Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae)
In the family Zygaenidae (Lepidoptera) with more than 1000 species a complete chemical analysis of the structure of female sex pheromones has been carried out for only three species of the subfamily Procridinae while sex attractants have been found for males of more than 60 species of two subfamili...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Sociedad Hispano-Luso-Americana de Lepidopterología
2023-06-01
|
| Series: | SHILAP |
| Subjects: | |
| Online Access: | https://shilap.org/revista/article/view/474 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850067901063626752 |
|---|---|
| author | Konstantin A. Efetov Elena E. Kucherenko |
| author_facet | Konstantin A. Efetov Elena E. Kucherenko |
| author_sort | Konstantin A. Efetov |
| collection | DOAJ |
| description |
In the family Zygaenidae (Lepidoptera) with more than 1000 species a complete chemical analysis of the structure of female sex pheromones has been carried out for only three species of the subfamily Procridinae while sex attractants have been found for males of more than 60 species of two subfamilies: Procridinae and Zygaeninae. The synthesis of new sex attractants was performed from (Z)-dodec-5-enoic acid and R- and S-enantiomers of butan-2-ol at the Crimean Federal University in 2021. The biological activity of received esters was tested during fieldwork in the Crimean Peninsula. It has been proved that (2R)-butan-2-yl (Z)-dodec-5-enoate (named EFETOV-S-5) and (2S)-butan-2-yl (Z)-dodec-5-enoate (named EFETOV-S-S-5) are sex attractants for the males of Jordanita (Tremewania) notata (Zeller, 1847), while (2S)-butan-2-yl (Z)-dodec-5-enoate (EFETOV-S-S-5) is a sex attractant for Adscita (Adscita) geryon (Hübner, 1813). In addition, (2R)-butan-2-yl (Z)-hexadec-9-enoate and (2S)-butan-2-yl (Z)-hexadec-9-enoate were synthesised in 2022. However, these esters did not attract any of the Zygaenidae species which are common in the Crimea.
|
| format | Article |
| id | doaj-art-9aec64bd7fe842e0bc8ddf078b787dc1 |
| institution | DOAJ |
| issn | 2340-4078 |
| language | English |
| publishDate | 2023-06-01 |
| publisher | Sociedad Hispano-Luso-Americana de Lepidopterología |
| record_format | Article |
| series | SHILAP |
| spelling | doaj-art-9aec64bd7fe842e0bc8ddf078b787dc12025-08-20T02:48:12ZengSociedad Hispano-Luso-Americana de LepidopterologíaSHILAP2340-40782023-06-015120210.57065/shilap.474Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae)Konstantin A. Efetov0Elena E. Kucherenko1V. I. Vernadsky Crimean Federal UniversityV. I. Vernadsky Crimean Federal University In the family Zygaenidae (Lepidoptera) with more than 1000 species a complete chemical analysis of the structure of female sex pheromones has been carried out for only three species of the subfamily Procridinae while sex attractants have been found for males of more than 60 species of two subfamilies: Procridinae and Zygaeninae. The synthesis of new sex attractants was performed from (Z)-dodec-5-enoic acid and R- and S-enantiomers of butan-2-ol at the Crimean Federal University in 2021. The biological activity of received esters was tested during fieldwork in the Crimean Peninsula. It has been proved that (2R)-butan-2-yl (Z)-dodec-5-enoate (named EFETOV-S-5) and (2S)-butan-2-yl (Z)-dodec-5-enoate (named EFETOV-S-S-5) are sex attractants for the males of Jordanita (Tremewania) notata (Zeller, 1847), while (2S)-butan-2-yl (Z)-dodec-5-enoate (EFETOV-S-S-5) is a sex attractant for Adscita (Adscita) geryon (Hübner, 1813). In addition, (2R)-butan-2-yl (Z)-hexadec-9-enoate and (2S)-butan-2-yl (Z)-hexadec-9-enoate were synthesised in 2022. However, these esters did not attract any of the Zygaenidae species which are common in the Crimea. https://shilap.org/revista/article/view/474LepidopteraZygaenidaeProcridinaeAdscita geryonJordanita notataEFETOV-S-5 |
| spellingShingle | Konstantin A. Efetov Elena E. Kucherenko Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae) SHILAP Lepidoptera Zygaenidae Procridinae Adscita geryon Jordanita notata EFETOV-S-5 |
| title | Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae) |
| title_full | Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae) |
| title_fullStr | Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae) |
| title_full_unstemmed | Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae) |
| title_short | Synthesis and field testing of esters of (2R)-butan-2-ol and (2S)-butan-2-ol and monounsaturated fatty acids as sex attractants for the males of Procridinae species (Lepidoptera: Zygaenidae) |
| title_sort | synthesis and field testing of esters of 2r butan 2 ol and 2s butan 2 ol and monounsaturated fatty acids as sex attractants for the males of procridinae species lepidoptera zygaenidae |
| topic | Lepidoptera Zygaenidae Procridinae Adscita geryon Jordanita notata EFETOV-S-5 |
| url | https://shilap.org/revista/article/view/474 |
| work_keys_str_mv | AT konstantinaefetov synthesisandfieldtestingofestersof2rbutan2oland2sbutan2olandmonounsaturatedfattyacidsassexattractantsforthemalesofprocridinaespecieslepidopterazygaenidae AT elenaekucherenko synthesisandfieldtestingofestersof2rbutan2oland2sbutan2olandmonounsaturatedfattyacidsassexattractantsforthemalesofprocridinaespecieslepidopterazygaenidae |