Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution

A novel method for the recovery of sodium from alumina-extracted fly ash (AEFA) using concentrated Na2CO3 solution is presented. Sodium was efficiently extracted from AEFA, which was mainly composed of NaCaHSiO4. The factors influencing the process were systematically investigated, and the optimal c...

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Main Authors: Wang Z., Zheng S., Ma S., Ding J., Wang X.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2018-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391800010W.pdf
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author Wang Z.
Zheng S.
Ma S.
Ding J.
Wang X.
author_facet Wang Z.
Zheng S.
Ma S.
Ding J.
Wang X.
author_sort Wang Z.
collection DOAJ
description A novel method for the recovery of sodium from alumina-extracted fly ash (AEFA) using concentrated Na2CO3 solution is presented. Sodium was efficiently extracted from AEFA, which was mainly composed of NaCaHSiO4. The factors influencing the process were systematically investigated, and the optimal conditions were determined to be: reaction temperature = 180°C, Na2CO3 concentration = 170 g/L, liquid-to-solid ratio = 10 mL/g, and reaction time = 2 h. Under optimal conditions, a low Na2O content of 1.02 wt% of the products, with Na2O extraction rate of 93.79% was achieved. The results indicated that this process was more effective than the recovery of sodium from AEFA using a dilute NaOH solution. Furthermore, this process avoided the production of a dilute NaOH solution, therefore lowering the energy consumption during the concentration and recycling of sodium, when compared with the NaOH-based route. Therefore, the recovery of sodium from AEFA using concentrated Na2CO3 solution is more suitable for use in industrial applications.
format Article
id doaj-art-99beca703c6d4f99b1dd456e10ddc029
institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2018-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-99beca703c6d4f99b1dd456e10ddc0292025-02-02T08:28:53ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752018-01-0154222523210.2298/JMMB180309010W1450-53391800010WRecovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solutionWang Z.0Zheng S.1Ma S.2Ding J.3Wang X.4National Engineering Laboratory for Hydrometallurgy Cleaner Production Technology, Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing, PR China + University of Chinese Academy of ScienceInstitute of Process Engineering, Chinese Academy of Sciences, Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgy Cleaner Production Technology, Beijing, PR ChinaInstitute of Process Engineering, Chinese Academy of Sciences, Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgy Cleaner Production Technology, Beijing, PR ChinaInstitute of Process Engineering, Chinese Academy of Sciences, Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgy Cleaner Production Technology, Beijing, PR ChinaInstitute of Process Engineering, Chinese Academy of Sciences, Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgy Cleaner Production Technology, Beijing, PR ChinaA novel method for the recovery of sodium from alumina-extracted fly ash (AEFA) using concentrated Na2CO3 solution is presented. Sodium was efficiently extracted from AEFA, which was mainly composed of NaCaHSiO4. The factors influencing the process were systematically investigated, and the optimal conditions were determined to be: reaction temperature = 180°C, Na2CO3 concentration = 170 g/L, liquid-to-solid ratio = 10 mL/g, and reaction time = 2 h. Under optimal conditions, a low Na2O content of 1.02 wt% of the products, with Na2O extraction rate of 93.79% was achieved. The results indicated that this process was more effective than the recovery of sodium from AEFA using a dilute NaOH solution. Furthermore, this process avoided the production of a dilute NaOH solution, therefore lowering the energy consumption during the concentration and recycling of sodium, when compared with the NaOH-based route. Therefore, the recovery of sodium from AEFA using concentrated Na2CO3 solution is more suitable for use in industrial applications.http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391800010W.pdfFly ashNaCaHSiO4Sodium carbonateSodium extraction
spellingShingle Wang Z.
Zheng S.
Ma S.
Ding J.
Wang X.
Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution
Journal of Mining and Metallurgy. Section B: Metallurgy
Fly ash
NaCaHSiO4
Sodium carbonate
Sodium extraction
title Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution
title_full Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution
title_fullStr Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution
title_full_unstemmed Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution
title_short Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution
title_sort recovery of sodium from alumina extracted fly ash using concentrated sodium carbonate solution
topic Fly ash
NaCaHSiO4
Sodium carbonate
Sodium extraction
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391800010W.pdf
work_keys_str_mv AT wangz recoveryofsodiumfromaluminaextractedflyashusingconcentratedsodiumcarbonatesolution
AT zhengs recoveryofsodiumfromaluminaextractedflyashusingconcentratedsodiumcarbonatesolution
AT mas recoveryofsodiumfromaluminaextractedflyashusingconcentratedsodiumcarbonatesolution
AT dingj recoveryofsodiumfromaluminaextractedflyashusingconcentratedsodiumcarbonatesolution
AT wangx recoveryofsodiumfromaluminaextractedflyashusingconcentratedsodiumcarbonatesolution