Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals

The apparent Henry’s Law constant (H′), which quantifies the concentration partition of a gas-liquid equilibrium of carbon dioxide (CO2), is used to optimize the absorption of carbon dioxide in algae liquors. The values of H′ were examined under various conditions: in water at different temperatures...

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Main Authors: Wen-Hsi Cheng, Ming-Shean Chou
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2016/2562638
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author Wen-Hsi Cheng
Ming-Shean Chou
author_facet Wen-Hsi Cheng
Ming-Shean Chou
author_sort Wen-Hsi Cheng
collection DOAJ
description The apparent Henry’s Law constant (H′), which quantifies the concentration partition of a gas-liquid equilibrium of carbon dioxide (CO2), is used to optimize the absorption of carbon dioxide in algae liquors. The values of H′ were examined under various conditions: in water at different temperatures (27 and 37°C), in alkaline buffering chemicals (sodium hydroxide (NaOH) and sodium carbonate (Na2CO3)), and in aquatic algae plants (Egeria densa and Anubias barteri nana). The optimal conditions for CO2 absorption can be obtained by controlling the aqueous pH values (around weak alkalinity with pH 9-10) using sodium carbonate as an alkaline buffering chemical at 27°C, yielding exact H′ values of around 16.3–21.3 atm/M, which were obtained from the mean gaseous CO2 concentration of 803 ppm and the total aqueous carbonate concentration of 4.085 mg/L. The experimental results reveal that an alkaline buffering compound, sodium carbonate, can be added to water to maintain a constant aqueous alkalinity enough for the fixation of carbon dioxide by the photosynthesis of green algae in a photobioreactor.
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spelling doaj-art-9965664be50848fe8b7bc5dc1c7449c82025-02-03T05:46:00ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2016-01-01201610.1155/2016/25626382562638Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering ChemicalsWen-Hsi Cheng0Ming-Shean Chou1Department of Occupational Safety and Hygiene, Fooyin University, Kaohsiung City 83102, TaiwanInstitute of Environmental Engineering, National Sun Yat-Sen University, Kaohsiung City 80424, TaiwanThe apparent Henry’s Law constant (H′), which quantifies the concentration partition of a gas-liquid equilibrium of carbon dioxide (CO2), is used to optimize the absorption of carbon dioxide in algae liquors. The values of H′ were examined under various conditions: in water at different temperatures (27 and 37°C), in alkaline buffering chemicals (sodium hydroxide (NaOH) and sodium carbonate (Na2CO3)), and in aquatic algae plants (Egeria densa and Anubias barteri nana). The optimal conditions for CO2 absorption can be obtained by controlling the aqueous pH values (around weak alkalinity with pH 9-10) using sodium carbonate as an alkaline buffering chemical at 27°C, yielding exact H′ values of around 16.3–21.3 atm/M, which were obtained from the mean gaseous CO2 concentration of 803 ppm and the total aqueous carbonate concentration of 4.085 mg/L. The experimental results reveal that an alkaline buffering compound, sodium carbonate, can be added to water to maintain a constant aqueous alkalinity enough for the fixation of carbon dioxide by the photosynthesis of green algae in a photobioreactor.http://dx.doi.org/10.1155/2016/2562638
spellingShingle Wen-Hsi Cheng
Ming-Shean Chou
Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals
International Journal of Photoenergy
title Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals
title_full Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals
title_fullStr Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals
title_full_unstemmed Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals
title_short Optimization of Gas-Water Absorption Equilibrium of Carbon Dioxide for Algae Liquors: Selection of Alkaline Buffering Chemicals
title_sort optimization of gas water absorption equilibrium of carbon dioxide for algae liquors selection of alkaline buffering chemicals
url http://dx.doi.org/10.1155/2016/2562638
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AT mingsheanchou optimizationofgaswaterabsorptionequilibriumofcarbondioxideforalgaeliquorsselectionofalkalinebufferingchemicals