Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies

Adsorption of rhodamine B from aqueous solution on the surface of Moringa oliefera bark carbon was accomplished under the optimize conditions of temperature, concentration, pH, contact time and quantity of adsorbent. Spectrometric technique was used for the measurements of concentration of dye befor...

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Main Authors: S. Ramuthai, V. Nandhakumar, M. Thiruchelvi, S. Arivoli, V. Vijayakumaran
Format: Article
Language:English
Published: Wiley 2009-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2009/470704
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author S. Ramuthai
V. Nandhakumar
M. Thiruchelvi
S. Arivoli
V. Vijayakumaran
author_facet S. Ramuthai
V. Nandhakumar
M. Thiruchelvi
S. Arivoli
V. Vijayakumaran
author_sort S. Ramuthai
collection DOAJ
description Adsorption of rhodamine B from aqueous solution on the surface of Moringa oliefera bark carbon was accomplished under the optimize conditions of temperature, concentration, pH, contact time and quantity of adsorbent. Spectrometric technique was used for the measurements of concentration of dye before and after adsorption. The percentage removal of rhodamine B was calculated. The values of % adsorption data for Moringa oliefera bark carbon system show better adsorption capacity. The experimental data are fitted to the Langmuir and Freundlich isotherm equations. The values of their corresponding constant were determined from the slope and intercepts of their respective plots. Thermodynamic parameters like ΔG0, ΔH0 and ΔS0 were calculated. Rhodamine B-Moringa oliefera bark carbon system shows spontaneous and endothermic behaviour. The results of these investigations suggested that natural adsorbents can be utilized as adsorbent materials, because of their selectivity's for the removal of dyes.
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institution Kabale University
issn 0973-4945
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series E-Journal of Chemistry
spelling doaj-art-98c250cf5aaf4149bdcc23a6b3f4366c2025-02-03T07:25:32ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-016S1S363S37310.1155/2009/470704Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic StudiesS. Ramuthai0V. Nandhakumar1M. Thiruchelvi2S. Arivoli3V. Vijayakumaran4Department of Chemistry, Seethalakshmi Achi College for Women, Pallathur-630 107, IndiaDepartment of Chemistry, A.V.V.M. Sri Pushpam College, Poondi-613 503, IndiaDepartment of Chemistry, H H the Rajah's Government College, Pudukkottai-622 001, IndiaDepartment of Chemistry, H H the Rajah's Government College, Pudukkottai-622 001, IndiaDepartment of Chemistry, H H the Rajah's Government College, Pudukkottai-622 001, IndiaAdsorption of rhodamine B from aqueous solution on the surface of Moringa oliefera bark carbon was accomplished under the optimize conditions of temperature, concentration, pH, contact time and quantity of adsorbent. Spectrometric technique was used for the measurements of concentration of dye before and after adsorption. The percentage removal of rhodamine B was calculated. The values of % adsorption data for Moringa oliefera bark carbon system show better adsorption capacity. The experimental data are fitted to the Langmuir and Freundlich isotherm equations. The values of their corresponding constant were determined from the slope and intercepts of their respective plots. Thermodynamic parameters like ΔG0, ΔH0 and ΔS0 were calculated. Rhodamine B-Moringa oliefera bark carbon system shows spontaneous and endothermic behaviour. The results of these investigations suggested that natural adsorbents can be utilized as adsorbent materials, because of their selectivity's for the removal of dyes.http://dx.doi.org/10.1155/2009/470704
spellingShingle S. Ramuthai
V. Nandhakumar
M. Thiruchelvi
S. Arivoli
V. Vijayakumaran
Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies
E-Journal of Chemistry
title Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies
title_full Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies
title_fullStr Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies
title_full_unstemmed Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies
title_short Rhodamine B Adsorption- Kinetic, Mechanistic and Thermodynamic Studies
title_sort rhodamine b adsorption kinetic mechanistic and thermodynamic studies
url http://dx.doi.org/10.1155/2009/470704
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AT mthiruchelvi rhodaminebadsorptionkineticmechanisticandthermodynamicstudies
AT sarivoli rhodaminebadsorptionkineticmechanisticandthermodynamicstudies
AT vvijayakumaran rhodaminebadsorptionkineticmechanisticandthermodynamicstudies