Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum

Optical microscopic analysis of the stress induced (85% calculated stress) corrosion of brass in 1M ammonium sulfate [(NH4)2SO4] + 1M copper (II) sulfate (CuSO4) solution, and aluminium in 0.5M, 1M and 2M sulfuric (H2SO4) solution at 10% and 20% addition of Cedrus Atlantica and Ocimum basilicum Linn...

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Main Authors: Tolulope Loto Roland, Loto Cleophas, Usua Idorenyin
Format: Article
Language:English
Published: EDP Sciences 2025-01-01
Series:E3S Web of Conferences
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/03/e3sconf_isgst2024_02014.pdf
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author Tolulope Loto Roland
Loto Cleophas
Usua Idorenyin
author_facet Tolulope Loto Roland
Loto Cleophas
Usua Idorenyin
author_sort Tolulope Loto Roland
collection DOAJ
description Optical microscopic analysis of the stress induced (85% calculated stress) corrosion of brass in 1M ammonium sulfate [(NH4)2SO4] + 1M copper (II) sulfate (CuSO4) solution, and aluminium in 0.5M, 1M and 2M sulfuric (H2SO4) solution at 10% and 20% addition of Cedrus Atlantica and Ocimum basilicum Linn. essential oil extracts were documented. The optical images obtained showed the effect of both extracts on the alloys. Optical images of aluminium in the presence of Cedrus Atlantica showed increased susceptibility of the alloy to localized and general corrosion compared to Ocimum basilicum Linn which enhanced the corrosion resistance of aluminium. Cedrus Atlantica increased the susceptibility of alpha brass to corrosion compared to the solution without it. In the absence of Cedrus Atlantica, general surface deterioration was observed without any localized corrosion. However, at 10% Cedrus Atlantica concentration superficial crack was observed. The crack further increased to visible intergranular crack (fracture) at 20% Cedrus Atlantica concentration. Ocimum basilicum Linn performed effectively at 10% concentration, sustaining the corrosion resistance of brass in 1M (NH4)2SO4 + 1M CuSO4 solution. At 20% Ocimum basilicum Linn concentration superficial cracking appeared.
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series E3S Web of Conferences
spelling doaj-art-974cb2d0c22c479fbe3c57878bfd35672025-02-05T10:47:33ZengEDP SciencesE3S Web of Conferences2267-12422025-01-016030201410.1051/e3sconf/202560302014e3sconf_isgst2024_02014Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum BasilicumTolulope Loto Roland0Loto Cleophas1Usua Idorenyin2Department of Mechanical Engineering, Covenant UniversityDepartment of Mechanical Engineering, Covenant UniversityDepartment of Mechanical Engineering, Covenant UniversityOptical microscopic analysis of the stress induced (85% calculated stress) corrosion of brass in 1M ammonium sulfate [(NH4)2SO4] + 1M copper (II) sulfate (CuSO4) solution, and aluminium in 0.5M, 1M and 2M sulfuric (H2SO4) solution at 10% and 20% addition of Cedrus Atlantica and Ocimum basilicum Linn. essential oil extracts were documented. The optical images obtained showed the effect of both extracts on the alloys. Optical images of aluminium in the presence of Cedrus Atlantica showed increased susceptibility of the alloy to localized and general corrosion compared to Ocimum basilicum Linn which enhanced the corrosion resistance of aluminium. Cedrus Atlantica increased the susceptibility of alpha brass to corrosion compared to the solution without it. In the absence of Cedrus Atlantica, general surface deterioration was observed without any localized corrosion. However, at 10% Cedrus Atlantica concentration superficial crack was observed. The crack further increased to visible intergranular crack (fracture) at 20% Cedrus Atlantica concentration. Ocimum basilicum Linn performed effectively at 10% concentration, sustaining the corrosion resistance of brass in 1M (NH4)2SO4 + 1M CuSO4 solution. At 20% Ocimum basilicum Linn concentration superficial cracking appeared.https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/03/e3sconf_isgst2024_02014.pdf
spellingShingle Tolulope Loto Roland
Loto Cleophas
Usua Idorenyin
Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum
E3S Web of Conferences
title Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum
title_full Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum
title_fullStr Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum
title_full_unstemmed Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum
title_short Optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte, and the inhibition effect of Cedrus Atantica and Ocimum Basilicum
title_sort optical microscopic study of the stress induced corrosion of brass and aluminium in dilute electrolyte and the inhibition effect of cedrus atantica and ocimum basilicum
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2025/03/e3sconf_isgst2024_02014.pdf
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AT lotocleophas opticalmicroscopicstudyofthestressinducedcorrosionofbrassandaluminiumindiluteelectrolyteandtheinhibitioneffectofcedrusatanticaandocimumbasilicum
AT usuaidorenyin opticalmicroscopicstudyofthestressinducedcorrosionofbrassandaluminiumindiluteelectrolyteandtheinhibitioneffectofcedrusatanticaandocimumbasilicum