Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples

The fractal theory has been widely applied to the analysis of gas adsorption isotherms, which are used for the pore structure characterization in unconventional reservoirs. Fractal dimension is a key parameter that can indicate the complexity of the pore structures. So far, most fractal models for g...

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Main Authors: Hongyan Qi, Zhenlin Wang, Jianglong Yu, Peirong Yu, Guoqing Zheng
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Geofluids
Online Access:http://dx.doi.org/10.1155/2022/2206989
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author Hongyan Qi
Zhenlin Wang
Jianglong Yu
Peirong Yu
Guoqing Zheng
author_facet Hongyan Qi
Zhenlin Wang
Jianglong Yu
Peirong Yu
Guoqing Zheng
author_sort Hongyan Qi
collection DOAJ
description The fractal theory has been widely applied to the analysis of gas adsorption isotherms, which are used for the pore structure characterization in unconventional reservoirs. Fractal dimension is a key parameter that can indicate the complexity of the pore structures. So far, most fractal models for gas adsorption are for N2 adsorption, while fractal models for CO2 adsorption are rarely reported. In this paper, we built a fractal model for CO2 adsorption by combining a thermodynamic model and the Dubinin–Astakhov model. We then applied the new model to three CO2 adsorption isotherms measured on shale samples. The results show that the fractal dimension from the new model lies between 2 and 3, which agrees with the fractal geometry. The new model presented in this paper can be used for the CO2 adsorption analysis, which allows characterizing micropore structures in shales.
format Article
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institution Kabale University
issn 1468-8123
language English
publishDate 2022-01-01
publisher Wiley
record_format Article
series Geofluids
spelling doaj-art-960c7be16b4042f789a32ffecb03d8492025-02-03T06:06:47ZengWileyGeofluids1468-81232022-01-01202210.1155/2022/2206989Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale SamplesHongyan Qi0Zhenlin Wang1Jianglong Yu2Peirong Yu3Guoqing Zheng4Petro China Xinjiang Oilfield CompanyPetro China Xinjiang Oilfield CompanyPetro China Xinjiang Oilfield CompanyPetro China Xinjiang Oilfield CompanyPetro China Xinjiang Oilfield CompanyThe fractal theory has been widely applied to the analysis of gas adsorption isotherms, which are used for the pore structure characterization in unconventional reservoirs. Fractal dimension is a key parameter that can indicate the complexity of the pore structures. So far, most fractal models for gas adsorption are for N2 adsorption, while fractal models for CO2 adsorption are rarely reported. In this paper, we built a fractal model for CO2 adsorption by combining a thermodynamic model and the Dubinin–Astakhov model. We then applied the new model to three CO2 adsorption isotherms measured on shale samples. The results show that the fractal dimension from the new model lies between 2 and 3, which agrees with the fractal geometry. The new model presented in this paper can be used for the CO2 adsorption analysis, which allows characterizing micropore structures in shales.http://dx.doi.org/10.1155/2022/2206989
spellingShingle Hongyan Qi
Zhenlin Wang
Jianglong Yu
Peirong Yu
Guoqing Zheng
Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples
Geofluids
title Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples
title_full Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples
title_fullStr Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples
title_full_unstemmed Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples
title_short Determination of the Fractal Dimension of CO2 Adsorption Isotherms on Shale Samples
title_sort determination of the fractal dimension of co2 adsorption isotherms on shale samples
url http://dx.doi.org/10.1155/2022/2206989
work_keys_str_mv AT hongyanqi determinationofthefractaldimensionofco2adsorptionisothermsonshalesamples
AT zhenlinwang determinationofthefractaldimensionofco2adsorptionisothermsonshalesamples
AT jianglongyu determinationofthefractaldimensionofco2adsorptionisothermsonshalesamples
AT peirongyu determinationofthefractaldimensionofco2adsorptionisothermsonshalesamples
AT guoqingzheng determinationofthefractaldimensionofco2adsorptionisothermsonshalesamples