Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials

Alkali-activated materials prepared from industrial solid wastes have excellent performance, advancing the cement industry towards achieving the Net-zero emissions goal. However, the diverse synergistic effects of various solid waste types necessitate further investigation. In this study, the effect...

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Main Authors: Xingyi Wang, Jinzhuang Lv, Jingchao Yang, Jiamin Zhu, Bin He, Xiaoyuan Wang, Pengju Han, Xiaohong Bai
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Case Studies in Construction Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2214509525000580
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author Xingyi Wang
Jinzhuang Lv
Jingchao Yang
Jiamin Zhu
Bin He
Xiaoyuan Wang
Pengju Han
Xiaohong Bai
author_facet Xingyi Wang
Jinzhuang Lv
Jingchao Yang
Jiamin Zhu
Bin He
Xiaoyuan Wang
Pengju Han
Xiaohong Bai
author_sort Xingyi Wang
collection DOAJ
description Alkali-activated materials prepared from industrial solid wastes have excellent performance, advancing the cement industry towards achieving the Net-zero emissions goal. However, the diverse synergistic effects of various solid waste types necessitate further investigation. In this study, the effect of different content (20 %, 30 %, 40 %, and 50 %) of ground granulated blast furnace slag (GGBFS) on the mechanical performance of circulating fluidized bed fly ash (CFBFA)-GGBFS-lime ternary cementitious materials (CGL) was investigated. The synergistic mechanism of GGBFS and CFBFA was elucidated through analyses of hydration heat, XRD, FT-IR, and SEM-EDS tests. The results indicated that GGBFS facilitated sulfate consumption during the early hydration stage, promoting the dissolution of CFBFA. This, in turn, enhanced the availability of sulfate, calcium, and active silicon-aluminum phases for CGL hydration, ultimately leading to an improvement in their overall hydration degree. Conclusively, the optimal synergistic effect between CFBFA and GGBFS was observed at a GGBFS content of 40 %, with a compressive strength of 32.84 MPa at 28 days. However, excessive GGBFS content (50 %) could lead to the premature formation of a “hydration barrier membrane”, negatively affecting the sustained hydration of CGL. This work presented an eco-friendly approach to the resource utilization of CFBFA, particularly in terms of mineral resource consumption, and held promising prospects for applications in projects.
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spelling doaj-art-950a388f6d4b4c6caadd6eca077e6f152025-01-18T05:04:41ZengElsevierCase Studies in Construction Materials2214-50952025-07-0122e04259Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materialsXingyi Wang0Jinzhuang Lv1Jingchao Yang2Jiamin Zhu3Bin He4Xiaoyuan Wang5Pengju Han6Xiaohong Bai7College of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCollege of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCollege of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCollege of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCollege of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCorresponding authors.; College of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCorresponding authors.; College of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaCollege of Civil Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, ChinaAlkali-activated materials prepared from industrial solid wastes have excellent performance, advancing the cement industry towards achieving the Net-zero emissions goal. However, the diverse synergistic effects of various solid waste types necessitate further investigation. In this study, the effect of different content (20 %, 30 %, 40 %, and 50 %) of ground granulated blast furnace slag (GGBFS) on the mechanical performance of circulating fluidized bed fly ash (CFBFA)-GGBFS-lime ternary cementitious materials (CGL) was investigated. The synergistic mechanism of GGBFS and CFBFA was elucidated through analyses of hydration heat, XRD, FT-IR, and SEM-EDS tests. The results indicated that GGBFS facilitated sulfate consumption during the early hydration stage, promoting the dissolution of CFBFA. This, in turn, enhanced the availability of sulfate, calcium, and active silicon-aluminum phases for CGL hydration, ultimately leading to an improvement in their overall hydration degree. Conclusively, the optimal synergistic effect between CFBFA and GGBFS was observed at a GGBFS content of 40 %, with a compressive strength of 32.84 MPa at 28 days. However, excessive GGBFS content (50 %) could lead to the premature formation of a “hydration barrier membrane”, negatively affecting the sustained hydration of CGL. This work presented an eco-friendly approach to the resource utilization of CFBFA, particularly in terms of mineral resource consumption, and held promising prospects for applications in projects.http://www.sciencedirect.com/science/article/pii/S2214509525000580Circulating fluidized bed fly ashGround granulated blast furnace slagSynergistic effectHydration processMicroscopic analysis
spellingShingle Xingyi Wang
Jinzhuang Lv
Jingchao Yang
Jiamin Zhu
Bin He
Xiaoyuan Wang
Pengju Han
Xiaohong Bai
Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials
Case Studies in Construction Materials
Circulating fluidized bed fly ash
Ground granulated blast furnace slag
Synergistic effect
Hydration process
Microscopic analysis
title Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials
title_full Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials
title_fullStr Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials
title_full_unstemmed Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials
title_short Synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime-activated cementitious materials
title_sort synergistic effects of ground granulated blast furnace slag and circulating fluidized bed fly ash in lime activated cementitious materials
topic Circulating fluidized bed fly ash
Ground granulated blast furnace slag
Synergistic effect
Hydration process
Microscopic analysis
url http://www.sciencedirect.com/science/article/pii/S2214509525000580
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