Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase

By means of CALPHAD approach, thermodynamic assessments of the Mg-Pb and Mg-Bi systems were carried out based on the available experimental data including thermodynamic properties and phase equilibrium data. The liquid phase was described with both the substitutional solution model and the...

Full description

Saved in:
Bibliographic Details
Main Authors: Zhang F., Tang Y., Hu B., Liu S., Du Y., Zhang Y.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2014-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2014/1450-53391400017Z.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832572218762067968
author Zhang F.
Tang Y.
Hu B.
Liu S.
Du Y.
Zhang Y.
author_facet Zhang F.
Tang Y.
Hu B.
Liu S.
Du Y.
Zhang Y.
author_sort Zhang F.
collection DOAJ
description By means of CALPHAD approach, thermodynamic assessments of the Mg-Pb and Mg-Bi systems were carried out based on the available experimental data including thermodynamic properties and phase equilibrium data. The liquid phase was described with both the substitutional solution model and the associate model, and two sets of self-consistent thermodynamic parameters for the Mg-Pb and Mg-Bi systems were obtained, respectively. It was found that the associate model can account for the experimental data more satisfactorily than the substitutional solution one, especially for the liquid phase with the short-range order behavior.
format Article
id doaj-art-94e704c00d69443eb62927518665eb96
institution Kabale University
issn 1450-5339
language English
publishDate 2014-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-94e704c00d69443eb62927518665eb962025-02-02T11:17:59ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392014-01-0150211512610.2298/JMMB130824017Z1450-53391400017ZThermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phaseZhang F.0Tang Y.1Hu B.2Liu S.3Du Y.4Zhang Y.5State Key Laboratory of Powder Metallurgy, Central South University, Changsha, PR ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, PR ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, PR ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, PR ChinaState Key Laboratory of Powder Metallurgy, Central South University, Changsha, PR ChinaPhosphorTech Inc, Kennesaw N Industrial Par Kennesaw, GA, United StatesBy means of CALPHAD approach, thermodynamic assessments of the Mg-Pb and Mg-Bi systems were carried out based on the available experimental data including thermodynamic properties and phase equilibrium data. The liquid phase was described with both the substitutional solution model and the associate model, and two sets of self-consistent thermodynamic parameters for the Mg-Pb and Mg-Bi systems were obtained, respectively. It was found that the associate model can account for the experimental data more satisfactorily than the substitutional solution one, especially for the liquid phase with the short-range order behavior.http://www.doiserbia.nb.rs/img/doi/1450-5339/2014/1450-53391400017Z.pdfassociativitysubstitutionphasesthermodynamics
spellingShingle Zhang F.
Tang Y.
Hu B.
Liu S.
Du Y.
Zhang Y.
Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase
Journal of Mining and Metallurgy. Section B: Metallurgy
associativity
substitution
phases
thermodynamics
title Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase
title_full Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase
title_fullStr Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase
title_full_unstemmed Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase
title_short Thermodynamic assessment of the Mg-Pb and Mg-Bi systems using substitutional solution and associate models for the liquid phase
title_sort thermodynamic assessment of the mg pb and mg bi systems using substitutional solution and associate models for the liquid phase
topic associativity
substitution
phases
thermodynamics
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2014/1450-53391400017Z.pdf
work_keys_str_mv AT zhangf thermodynamicassessmentofthemgpbandmgbisystemsusingsubstitutionalsolutionandassociatemodelsfortheliquidphase
AT tangy thermodynamicassessmentofthemgpbandmgbisystemsusingsubstitutionalsolutionandassociatemodelsfortheliquidphase
AT hub thermodynamicassessmentofthemgpbandmgbisystemsusingsubstitutionalsolutionandassociatemodelsfortheliquidphase
AT lius thermodynamicassessmentofthemgpbandmgbisystemsusingsubstitutionalsolutionandassociatemodelsfortheliquidphase
AT duy thermodynamicassessmentofthemgpbandmgbisystemsusingsubstitutionalsolutionandassociatemodelsfortheliquidphase
AT zhangy thermodynamicassessmentofthemgpbandmgbisystemsusingsubstitutionalsolutionandassociatemodelsfortheliquidphase