Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment

This paper investigates anticorrosion behaviour of the bark-extract from Rhizophora mangle L. on steel-rebar in concrete slabs in 3.5% NaCl medium of immersion (for simulating saline/marine environment). Corrosion-rate, corrosion-current, and corrosion-potential were measured from the NaCl-immersed...

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Main Authors: Joshua Olusegun Okeniyi, Jacob Olumuyiwa Ikotun, Esther Titilayo Akinlabi, Elizabeth Toyin Okeniyi
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1155/2019/6894714
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author Joshua Olusegun Okeniyi
Jacob Olumuyiwa Ikotun
Esther Titilayo Akinlabi
Elizabeth Toyin Okeniyi
author_facet Joshua Olusegun Okeniyi
Jacob Olumuyiwa Ikotun
Esther Titilayo Akinlabi
Elizabeth Toyin Okeniyi
author_sort Joshua Olusegun Okeniyi
collection DOAJ
description This paper investigates anticorrosion behaviour of the bark-extract from Rhizophora mangle L. on steel-rebar in concrete slabs in 3.5% NaCl medium of immersion (for simulating saline/marine environment). Corrosion-rate, corrosion-current, and corrosion-potential were measured from the NaCl-immersed steel-reinforced concrete cast with admixture of different plant-extract concentrations and from positive control concrete immersed in distilled water. Analyses indicate excellent mathematical-correlation between the corrosion-rate, concentration of the bark-extract admixture, and electrochemical noise-resistance (ratio of the corrosion-potential standard deviation to that of corrosion-current). The 0.4667% Rhizophora mangle L. bark-extract admixture exhibited optimal corrosion-inhibition performance, η = 99.08±0.11% (experimental) or η = 97.89±0.24% (correlation), which outperformed the positive control specimens, experimentally. Both experimental and correlated results followed Langmuir adsorption isotherm which suggests prevalent physisorption mechanism by the plant-extract on the reinforcing-steel corrosion-protection. These findings support Rhizophora mangle L. bark-extract suitability for corrosion-protection of steel-rebar in concrete structure designed for immersion in the saline/marine environmental medium.
format Article
id doaj-art-941d6135594b4e5da443dcb871453871
institution Kabale University
issn 2356-6140
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language English
publishDate 2019-01-01
publisher Wiley
record_format Article
series The Scientific World Journal
spelling doaj-art-941d6135594b4e5da443dcb8714538712025-02-03T01:24:27ZengWileyThe Scientific World Journal2356-61401537-744X2019-01-01201910.1155/2019/68947146894714Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-EnvironmentJoshua Olusegun Okeniyi0Jacob Olumuyiwa Ikotun1Esther Titilayo Akinlabi2Elizabeth Toyin Okeniyi3Mechanical Engineering Department, Covenant University, Ota 112001, NigeriaDepartment of Civil Engineering and Building, Vaal University of Technology, Vanderbijlpark 1911, South AfricaMechanical Engineering Department, Covenant University, Ota 112001, NigeriaPetroleum Engineering Department, Covenant University, Ota 112001, NigeriaThis paper investigates anticorrosion behaviour of the bark-extract from Rhizophora mangle L. on steel-rebar in concrete slabs in 3.5% NaCl medium of immersion (for simulating saline/marine environment). Corrosion-rate, corrosion-current, and corrosion-potential were measured from the NaCl-immersed steel-reinforced concrete cast with admixture of different plant-extract concentrations and from positive control concrete immersed in distilled water. Analyses indicate excellent mathematical-correlation between the corrosion-rate, concentration of the bark-extract admixture, and electrochemical noise-resistance (ratio of the corrosion-potential standard deviation to that of corrosion-current). The 0.4667% Rhizophora mangle L. bark-extract admixture exhibited optimal corrosion-inhibition performance, η = 99.08±0.11% (experimental) or η = 97.89±0.24% (correlation), which outperformed the positive control specimens, experimentally. Both experimental and correlated results followed Langmuir adsorption isotherm which suggests prevalent physisorption mechanism by the plant-extract on the reinforcing-steel corrosion-protection. These findings support Rhizophora mangle L. bark-extract suitability for corrosion-protection of steel-rebar in concrete structure designed for immersion in the saline/marine environmental medium.http://dx.doi.org/10.1155/2019/6894714
spellingShingle Joshua Olusegun Okeniyi
Jacob Olumuyiwa Ikotun
Esther Titilayo Akinlabi
Elizabeth Toyin Okeniyi
Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment
The Scientific World Journal
title Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment
title_full Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment
title_fullStr Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment
title_full_unstemmed Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment
title_short Anticorrosion Behaviour of Rhizophora mangle L. Bark-Extract on Concrete Steel-Rebar in Saline/Marine Simulating-Environment
title_sort anticorrosion behaviour of rhizophora mangle l bark extract on concrete steel rebar in saline marine simulating environment
url http://dx.doi.org/10.1155/2019/6894714
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