Synthesis and Characterization of Salicylate Derivatives of Dibutyl Sn(IV)-Ti(IV)-μ-Oxoisopropoxide

New Salicylate derivatives of organoheterobimetallic-μ-oxoisopropoxide [Bu2SnO2Ti2(OPri)6] have been synthesized by the thermal condensation of μ-oxoisopropoxide compound with different salicylates in different molar ratios (1:1-1:4) yielded the compounds of the type [Bu2SnO2Ti2(OPri)6-n(RSal)n] (wh...

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Bibliographic Details
Main Author: Rajesh Kumar
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2012/450821
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Summary:New Salicylate derivatives of organoheterobimetallic-μ-oxoisopropoxide [Bu2SnO2Ti2(OPri)6] have been synthesized by the thermal condensation of μ-oxoisopropoxide compound with different salicylates in different molar ratios (1:1-1:4) yielded the compounds of the type [Bu2SnO2Ti2(OPri)6-n(RSal)n] (where n is 1-4 and RSal = Salicylate anion) respectively. The μ-oxoisopropoxide derivative has been characterized by elemental, liberated isopropanol, and spectral analysis (IR, 1H, 13C, and 119Sn NMR).
ISSN:0973-4945
2090-9810