Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals
Liquid crystals are compounds that display order in the liquid state above the melting temperature and below the mesogenic isotropic temperature. Polymer-dispersed liquid crystals (PDLCs) are composite materials in which liquid crystalline material is dispersed within a polymer matrix to form micron...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2012/767581 |
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| author | Robert A. Shanks Daniel Staszczyk |
| author_facet | Robert A. Shanks Daniel Staszczyk |
| author_sort | Robert A. Shanks |
| collection | DOAJ |
| description | Liquid crystals are compounds that display order in the liquid state above the melting temperature and below the mesogenic isotropic temperature. Polymer-dispersed liquid crystals (PDLCs) are composite materials in which liquid crystalline material is dispersed within a polymer matrix to form micron-sized droplets. The aim was to prepare several cholesteryl esters or alkoxybenzoic acid PDLCs and characterise thermal and optical properties. Differential scanning calorimetry and polarized optical microscopy were employed. The matrix polymer was a one-component UV-curable epoxy-acrylate resin. PDLCs were formed through entropy controlled phase separation resulting from UV-initiated crosslinking. The liquid crystals, both as mesogenic moieties and as dispersed droplets, exhibited various textures according to their molecular order and orientation. These textures formed in constrained regions separated by phase boundaries that occurred at temperatures characteristic of each liquid crystal used. The PDLC phase transitions occurred at temperatures lower than those exhibited by the mesogenic components in the neat state. |
| format | Article |
| id | doaj-art-9248a9c0b5e44e45afdd251f09c42826 |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-9248a9c0b5e44e45afdd251f09c428262025-02-03T06:48:29ZengWileyInternational Journal of Polymer Science1687-94221687-94302012-01-01201210.1155/2012/767581767581Thermal and Optical Characterization of Polymer-Dispersed Liquid CrystalsRobert A. Shanks0Daniel Staszczyk1School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, VIC 3001, AustraliaSchool of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, VIC 3001, AustraliaLiquid crystals are compounds that display order in the liquid state above the melting temperature and below the mesogenic isotropic temperature. Polymer-dispersed liquid crystals (PDLCs) are composite materials in which liquid crystalline material is dispersed within a polymer matrix to form micron-sized droplets. The aim was to prepare several cholesteryl esters or alkoxybenzoic acid PDLCs and characterise thermal and optical properties. Differential scanning calorimetry and polarized optical microscopy were employed. The matrix polymer was a one-component UV-curable epoxy-acrylate resin. PDLCs were formed through entropy controlled phase separation resulting from UV-initiated crosslinking. The liquid crystals, both as mesogenic moieties and as dispersed droplets, exhibited various textures according to their molecular order and orientation. These textures formed in constrained regions separated by phase boundaries that occurred at temperatures characteristic of each liquid crystal used. The PDLC phase transitions occurred at temperatures lower than those exhibited by the mesogenic components in the neat state.http://dx.doi.org/10.1155/2012/767581 |
| spellingShingle | Robert A. Shanks Daniel Staszczyk Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals International Journal of Polymer Science |
| title | Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals |
| title_full | Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals |
| title_fullStr | Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals |
| title_full_unstemmed | Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals |
| title_short | Thermal and Optical Characterization of Polymer-Dispersed Liquid Crystals |
| title_sort | thermal and optical characterization of polymer dispersed liquid crystals |
| url | http://dx.doi.org/10.1155/2012/767581 |
| work_keys_str_mv | AT robertashanks thermalandopticalcharacterizationofpolymerdispersedliquidcrystals AT danielstaszczyk thermalandopticalcharacterizationofpolymerdispersedliquidcrystals |