Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite

Metakaolin (MK) is an aluminosilicate pozzolan material and can contribute to property development of concrete due to the pozzolanic reaction. Limestone (LS) powder presents the dilution effect, nucleation effect, and chemical effect on hydration of cement. When metakaolin and limestone are used tog...

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Main Author: Xiao-Yong Wang
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2019/8361810
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author Xiao-Yong Wang
author_facet Xiao-Yong Wang
author_sort Xiao-Yong Wang
collection DOAJ
description Metakaolin (MK) is an aluminosilicate pozzolan material and can contribute to property development of concrete due to the pozzolanic reaction. Limestone (LS) powder presents the dilution effect, nucleation effect, and chemical effect on hydration of cement. When metakaolin and limestone are used together, due to the additional chemical reaction between the aluminum phase in MK and limestone, the synergetic benefit can be achieved. This study presents a hydration model for cement-limestone-metakaolin ternary blends. Individual reactions of cement, metakaolin, and limestone are simulated separately, and the interactions among cement hydration, limestone reaction, and metakaolin reaction are considered through the contents of calcium hydroxide and capillary water. The hydration model considers the pozzolanic reaction of metakaolin, chemical and physics effects of limestone, and synergetic effect between metakaolin and limestone. Furthermore, the gel-space ratio of hydrating concrete is calculated using reaction degrees of binders and concrete mixtures. The strength development of ternary blends is evaluated using the gel-space ratio. Based on parameter analysis, the synergetic effect on strength development is shown and the optimal combinations of cement-limestone-metakaolin ternary blends are determined.
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spelling doaj-art-91c8d38a081a4059b07c8cbdccaf65fd2025-02-03T01:30:06ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422019-01-01201910.1155/2019/83618108361810Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary CompositeXiao-Yong Wang0Department of Architectural Engineering, Kangwon National University, Chuncheon-Si, Republic of KoreaMetakaolin (MK) is an aluminosilicate pozzolan material and can contribute to property development of concrete due to the pozzolanic reaction. Limestone (LS) powder presents the dilution effect, nucleation effect, and chemical effect on hydration of cement. When metakaolin and limestone are used together, due to the additional chemical reaction between the aluminum phase in MK and limestone, the synergetic benefit can be achieved. This study presents a hydration model for cement-limestone-metakaolin ternary blends. Individual reactions of cement, metakaolin, and limestone are simulated separately, and the interactions among cement hydration, limestone reaction, and metakaolin reaction are considered through the contents of calcium hydroxide and capillary water. The hydration model considers the pozzolanic reaction of metakaolin, chemical and physics effects of limestone, and synergetic effect between metakaolin and limestone. Furthermore, the gel-space ratio of hydrating concrete is calculated using reaction degrees of binders and concrete mixtures. The strength development of ternary blends is evaluated using the gel-space ratio. Based on parameter analysis, the synergetic effect on strength development is shown and the optimal combinations of cement-limestone-metakaolin ternary blends are determined.http://dx.doi.org/10.1155/2019/8361810
spellingShingle Xiao-Yong Wang
Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite
Advances in Materials Science and Engineering
title Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite
title_full Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite
title_fullStr Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite
title_full_unstemmed Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite
title_short Analysis of Hydration and Optimal Strength Combinations of Cement-Limestone-Metakaolin Ternary Composite
title_sort analysis of hydration and optimal strength combinations of cement limestone metakaolin ternary composite
url http://dx.doi.org/10.1155/2019/8361810
work_keys_str_mv AT xiaoyongwang analysisofhydrationandoptimalstrengthcombinationsofcementlimestonemetakaolinternarycomposite