Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics

Utilizing the conventional approach, the positive temperature coefficient of resistivity (PTCR) performance of lead-free ceramics based on (1 − x%)(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 − x%(Bi0.5Na0.5)TiO3 (BBNTx) was examined. The BBNTx ceramics were prepared using the do...

Full description

Saved in:
Bibliographic Details
Main Authors: Chen Xiaoming, Li Yini, Zeng Sikang, Cheng Xuxin, Zhang Wei, Wang Yuxin
Format: Article
Language:English
Published: De Gruyter 2024-01-01
Series:High Temperature Materials and Processes
Subjects:
Online Access:https://doi.org/10.1515/htmp-2024-0064
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832570445687160832
author Chen Xiaoming
Li Yini
Zeng Sikang
Cheng Xuxin
Zhang Wei
Wang Yuxin
author_facet Chen Xiaoming
Li Yini
Zeng Sikang
Cheng Xuxin
Zhang Wei
Wang Yuxin
author_sort Chen Xiaoming
collection DOAJ
description Utilizing the conventional approach, the positive temperature coefficient of resistivity (PTCR) performance of lead-free ceramics based on (1 − x%)(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 − x%(Bi0.5Na0.5)TiO3 (BBNTx) was examined. The BBNTx ceramics were prepared using the double donor dopant under firing at 1,350°C for 120 min in the air. The findings exhibited that when the Y3+ concentration elevates, the room-temperature resistivity of 99%(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 – 1%(Bi0.5Na0.5)TiO3 (BBNT1) samples initially falls and subsequently elevates. Moreover, the critical content of the samples is 0.15 mol%. Furthermore, the samples’ resistance jumping ratio can be effectively improved by adding Mn2+. The manganese dioxide level of 0.05 mol% yields the greatest resistance-jumping ratio. Besides, the impact of (Bi0.5Na0.5)TiO3 (BNT) concentration on ceramics’ Curie temperature was examined in the work. Therefore, good free-lead PTCR thermistors were successfully prepared by doping 3% BNT, with a resistance jump of 4.1 magnitude.
format Article
id doaj-art-90929e49675c4a77acfd9ac2f35fd544
institution Kabale University
issn 2191-0324
language English
publishDate 2024-01-01
publisher De Gruyter
record_format Article
series High Temperature Materials and Processes
spelling doaj-art-90929e49675c4a77acfd9ac2f35fd5442025-02-02T15:45:43ZengDe GruyterHigh Temperature Materials and Processes2191-03242024-01-01431pp. 2088209210.1515/htmp-2024-0064Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramicsChen Xiaoming0Li Yini1Zeng Sikang2Cheng Xuxin3Zhang Wei4Wang Yuxin5School of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou, 510006, Guangdong, PR ChinaSchool of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu, PR ChinaUtilizing the conventional approach, the positive temperature coefficient of resistivity (PTCR) performance of lead-free ceramics based on (1 − x%)(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 − x%(Bi0.5Na0.5)TiO3 (BBNTx) was examined. The BBNTx ceramics were prepared using the double donor dopant under firing at 1,350°C for 120 min in the air. The findings exhibited that when the Y3+ concentration elevates, the room-temperature resistivity of 99%(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 – 1%(Bi0.5Na0.5)TiO3 (BBNT1) samples initially falls and subsequently elevates. Moreover, the critical content of the samples is 0.15 mol%. Furthermore, the samples’ resistance jumping ratio can be effectively improved by adding Mn2+. The manganese dioxide level of 0.05 mol% yields the greatest resistance-jumping ratio. Besides, the impact of (Bi0.5Na0.5)TiO3 (BNT) concentration on ceramics’ Curie temperature was examined in the work. Therefore, good free-lead PTCR thermistors were successfully prepared by doping 3% BNT, with a resistance jump of 4.1 magnitude.https://doi.org/10.1515/htmp-2024-0064batio3 y2o3-dopantptcr effectelectroceramics
spellingShingle Chen Xiaoming
Li Yini
Zeng Sikang
Cheng Xuxin
Zhang Wei
Wang Yuxin
Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
High Temperature Materials and Processes
batio3
y2o3-dopant
ptcr effect
electroceramics
title Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
title_full Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
title_fullStr Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
title_full_unstemmed Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
title_short Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
title_sort investigation of electrical properties and ptcr effect in double donor doping batio3 lead free ceramics
topic batio3
y2o3-dopant
ptcr effect
electroceramics
url https://doi.org/10.1515/htmp-2024-0064
work_keys_str_mv AT chenxiaoming investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics
AT liyini investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics
AT zengsikang investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics
AT chengxuxin investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics
AT zhangwei investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics
AT wangyuxin investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics