Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics
Utilizing the conventional approach, the positive temperature coefficient of resistivity (PTCR) performance of lead-free ceramics based on (1 − x%)(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 − x%(Bi0.5Na0.5)TiO3 (BBNTx) was examined. The BBNTx ceramics were prepared using the do...
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De Gruyter
2024-01-01
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Series: | High Temperature Materials and Processes |
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Online Access: | https://doi.org/10.1515/htmp-2024-0064 |
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author | Chen Xiaoming Li Yini Zeng Sikang Cheng Xuxin Zhang Wei Wang Yuxin |
author_facet | Chen Xiaoming Li Yini Zeng Sikang Cheng Xuxin Zhang Wei Wang Yuxin |
author_sort | Chen Xiaoming |
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description | Utilizing the conventional approach, the positive temperature coefficient of resistivity (PTCR) performance of lead-free ceramics based on (1 − x%)(Ba1−y
Yy)(Ti1.011−z
Nb0.001Mnz)O3 − x%(Bi0.5Na0.5)TiO3 (BBNTx) was examined. The BBNTx ceramics were prepared using the double donor dopant under firing at 1,350°C for 120 min in the air. The findings exhibited that when the Y3+ concentration elevates, the room-temperature resistivity of 99%(Ba1−y
Yy)(Ti1.011−z
Nb0.001Mnz)O3 – 1%(Bi0.5Na0.5)TiO3 (BBNT1) samples initially falls and subsequently elevates. Moreover, the critical content of the samples is 0.15 mol%. Furthermore, the samples’ resistance jumping ratio can be effectively improved by adding Mn2+. The manganese dioxide level of 0.05 mol% yields the greatest resistance-jumping ratio. Besides, the impact of (Bi0.5Na0.5)TiO3 (BNT) concentration on ceramics’ Curie temperature was examined in the work. Therefore, good free-lead PTCR thermistors were successfully prepared by doping 3% BNT, with a resistance jump of 4.1 magnitude. |
format | Article |
id | doaj-art-90929e49675c4a77acfd9ac2f35fd544 |
institution | Kabale University |
issn | 2191-0324 |
language | English |
publishDate | 2024-01-01 |
publisher | De Gruyter |
record_format | Article |
series | High Temperature Materials and Processes |
spelling | doaj-art-90929e49675c4a77acfd9ac2f35fd5442025-02-02T15:45:43ZengDe GruyterHigh Temperature Materials and Processes2191-03242024-01-01431pp. 2088209210.1515/htmp-2024-0064Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramicsChen Xiaoming0Li Yini1Zeng Sikang2Cheng Xuxin3Zhang Wei4Wang Yuxin5School of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Electronic and Electrical Engineering, Zhaoqing University, Zhaoqing Road, Duanzhou District, Zhaoqing, 526061, Guangdong, PR ChinaSchool of Physics and Optoelectronic Engineering, Guangdong University of Technology, Guangzhou, 510006, Guangdong, PR ChinaSchool of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu, PR ChinaUtilizing the conventional approach, the positive temperature coefficient of resistivity (PTCR) performance of lead-free ceramics based on (1 − x%)(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 − x%(Bi0.5Na0.5)TiO3 (BBNTx) was examined. The BBNTx ceramics were prepared using the double donor dopant under firing at 1,350°C for 120 min in the air. The findings exhibited that when the Y3+ concentration elevates, the room-temperature resistivity of 99%(Ba1−y Yy)(Ti1.011−z Nb0.001Mnz)O3 – 1%(Bi0.5Na0.5)TiO3 (BBNT1) samples initially falls and subsequently elevates. Moreover, the critical content of the samples is 0.15 mol%. Furthermore, the samples’ resistance jumping ratio can be effectively improved by adding Mn2+. The manganese dioxide level of 0.05 mol% yields the greatest resistance-jumping ratio. Besides, the impact of (Bi0.5Na0.5)TiO3 (BNT) concentration on ceramics’ Curie temperature was examined in the work. Therefore, good free-lead PTCR thermistors were successfully prepared by doping 3% BNT, with a resistance jump of 4.1 magnitude.https://doi.org/10.1515/htmp-2024-0064batio3 y2o3-dopantptcr effectelectroceramics |
spellingShingle | Chen Xiaoming Li Yini Zeng Sikang Cheng Xuxin Zhang Wei Wang Yuxin Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics High Temperature Materials and Processes batio3 y2o3-dopant ptcr effect electroceramics |
title | Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics |
title_full | Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics |
title_fullStr | Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics |
title_full_unstemmed | Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics |
title_short | Investigation of electrical properties and PTCR effect in double-donor doping BaTiO3 lead-free ceramics |
title_sort | investigation of electrical properties and ptcr effect in double donor doping batio3 lead free ceramics |
topic | batio3 y2o3-dopant ptcr effect electroceramics |
url | https://doi.org/10.1515/htmp-2024-0064 |
work_keys_str_mv | AT chenxiaoming investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics AT liyini investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics AT zengsikang investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics AT chengxuxin investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics AT zhangwei investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics AT wangyuxin investigationofelectricalpropertiesandptcreffectindoubledonordopingbatio3leadfreeceramics |