Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel

The cleanliness of Ti-containing ferritic stainless steel (Ti-FSS) has been improved via vacuum-oxygen-decarburization (VOD) and ladle treatment (LT) processes. However, the reoxidation phenomena inevitably occur during melt transfer from ladle to continuous casting tundish, resulting in a loss of t...

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Main Authors: Yeongjin Jun, Yongsug Chung, Sungjin Park, Suchang Kang, Min-Kyu Paek, Joo Hyun Park
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425001103
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author Yeongjin Jun
Yongsug Chung
Sungjin Park
Suchang Kang
Min-Kyu Paek
Joo Hyun Park
author_facet Yeongjin Jun
Yongsug Chung
Sungjin Park
Suchang Kang
Min-Kyu Paek
Joo Hyun Park
author_sort Yeongjin Jun
collection DOAJ
description The cleanliness of Ti-containing ferritic stainless steel (Ti-FSS) has been improved via vacuum-oxygen-decarburization (VOD) and ladle treatment (LT) processes. However, the reoxidation phenomena inevitably occur during melt transfer from ladle to continuous casting tundish, resulting in a loss of titanium yield in conjunction with the formation of reoxidative inclusions. Hence, the present work aims to systematically investigate the combinational effect of different tundish fluxes on the reoxidation behavior of Al-killed Ti-FSS melt. Rice husk ash (RHA) and MgO (M) insulation powders, and calcium aluminate, CaO–Al2O3 (CA) based flux were used for the experiments. When the molten steel was covered by M + CA fluxes, the average size of inclusions decreased. On the other hand, when the RHA + CA fluxes were added, the average size of inclusion decreased, whereas total number of inclusions significantly increased due to a reoxidation reaction by SiO2 in RHA. When the M + RHA + CA combinative fluxes were added, the size of inclusion decreased, and the number of inclusions exhibited a value between the M + CA and RHA + CA conditions. Consequently, a decrease in total oxygen content in Ti-FSS was most effective in the M + CA flux combination.
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spelling doaj-art-8edda6e9ba074409b06dc89f07ca6aaa2025-01-20T04:17:31ZengElsevierJournal of Materials Research and Technology2238-78542025-03-013512501264Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steelYeongjin Jun0Yongsug Chung1Sungjin Park2Suchang Kang3Min-Kyu Paek4Joo Hyun Park5Department of Materials Science and Chemical Engineering, Hanyang University, Ansan, South KoreaDepartment of Materials Science and Engineering, Tech University of Korea (TU Korea), Siheung, South KoreaSteelmaking Research Group, Technical Research Laboratories, POSCO, Pohang, South KoreaSteelmaking Research Group, Technical Research Laboratories, POSCO, Pohang, South KoreaDepartment of Chemical and Metallurgical Engineering, Aalto University, Espoo, FinlandDepartment of Materials Science and Chemical Engineering, Hanyang University, Ansan, South Korea; Corresponding author.The cleanliness of Ti-containing ferritic stainless steel (Ti-FSS) has been improved via vacuum-oxygen-decarburization (VOD) and ladle treatment (LT) processes. However, the reoxidation phenomena inevitably occur during melt transfer from ladle to continuous casting tundish, resulting in a loss of titanium yield in conjunction with the formation of reoxidative inclusions. Hence, the present work aims to systematically investigate the combinational effect of different tundish fluxes on the reoxidation behavior of Al-killed Ti-FSS melt. Rice husk ash (RHA) and MgO (M) insulation powders, and calcium aluminate, CaO–Al2O3 (CA) based flux were used for the experiments. When the molten steel was covered by M + CA fluxes, the average size of inclusions decreased. On the other hand, when the RHA + CA fluxes were added, the average size of inclusion decreased, whereas total number of inclusions significantly increased due to a reoxidation reaction by SiO2 in RHA. When the M + RHA + CA combinative fluxes were added, the size of inclusion decreased, and the number of inclusions exhibited a value between the M + CA and RHA + CA conditions. Consequently, a decrease in total oxygen content in Ti-FSS was most effective in the M + CA flux combination.http://www.sciencedirect.com/science/article/pii/S2238785425001103ReoxidationTundishStainless steelInclusionRice husk ashCalcium aluminate flux
spellingShingle Yeongjin Jun
Yongsug Chung
Sungjin Park
Suchang Kang
Min-Kyu Paek
Joo Hyun Park
Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel
Journal of Materials Research and Technology
Reoxidation
Tundish
Stainless steel
Inclusion
Rice husk ash
Calcium aluminate flux
title Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel
title_full Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel
title_fullStr Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel
title_full_unstemmed Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel
title_short Influence of tundish flux on reoxidation behavior of Al-killed Ti-containing stainless steel
title_sort influence of tundish flux on reoxidation behavior of al killed ti containing stainless steel
topic Reoxidation
Tundish
Stainless steel
Inclusion
Rice husk ash
Calcium aluminate flux
url http://www.sciencedirect.com/science/article/pii/S2238785425001103
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