Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography

Chitosan (CS)-based nanocomposites have been studied in various fields, requiring a more facile and efficient technique to fabricate nanoparticles with customized structures. In this study, Ag@methacrylamide CS/poly(ethylene glycol) diacrylate (Ag@MP) micropatterns are successfully fabricated by fem...

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Main Authors: Fan-Chun Bin, Xin-Yi Wu, Jie Liu, Xian-Zi Dong, Teng Li, Qi Duan, Jian-Miao Zhang, Katsumasa Fujita, Mei-Ling Zheng
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:International Journal of Extreme Manufacturing
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Online Access:https://doi.org/10.1088/2631-7990/ada83a
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author Fan-Chun Bin
Xin-Yi Wu
Jie Liu
Xian-Zi Dong
Teng Li
Qi Duan
Jian-Miao Zhang
Katsumasa Fujita
Mei-Ling Zheng
author_facet Fan-Chun Bin
Xin-Yi Wu
Jie Liu
Xian-Zi Dong
Teng Li
Qi Duan
Jian-Miao Zhang
Katsumasa Fujita
Mei-Ling Zheng
author_sort Fan-Chun Bin
collection DOAJ
description Chitosan (CS)-based nanocomposites have been studied in various fields, requiring a more facile and efficient technique to fabricate nanoparticles with customized structures. In this study, Ag@methacrylamide CS/poly(ethylene glycol) diacrylate (Ag@MP) micropatterns are successfully fabricated by femtosecond laser maskless optical projection lithography (Fs-MOPL) for the first time. The formation mechanism of core-shell nanomaterial is demonstrated by the local surface plasmon resonances and the nucleation and growth theory. Amino and hydroxyl groups greatly affect the number of Ag@MP nanocomposites, which is further verified by replacing MCS with methacrylated bovine serum albumin and hyaluronic acid methacryloyl, respectively. Besides, the performance of the surface-enhanced Raman scattering, cytotoxicity, cell proliferation, and antibacterial was investigated on Ag@MP micropatterns. Therefore, the proposed protocol to prepare hydrogel core-shell micropattern by the home-built Fs-MOPL technique is prospective for potential applications in the biomedical and biotechnological fields, such as biosensors, cell imaging, and antimicrobial.
format Article
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institution Kabale University
issn 2631-7990
language English
publishDate 2025-01-01
publisher IOP Publishing
record_format Article
series International Journal of Extreme Manufacturing
spelling doaj-art-8ca7ceca5e7d41cf989eb708af9009452025-01-23T12:56:46ZengIOP PublishingInternational Journal of Extreme Manufacturing2631-79902025-01-017303500110.1088/2631-7990/ada83aMicropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithographyFan-Chun Bin0Xin-Yi Wu1Jie Liu2Xian-Zi Dong3Teng Li4Qi Duan5Jian-Miao Zhang6Katsumasa Fujita7Mei-Ling Zheng8https://orcid.org/0000-0002-9459-799XLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China; School of Future Technology, University of Chinese Academy of Sciences , Yanqihu Campus, Beijing 101407, People’s Republic of ChinaLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China; School of Future Technology, University of Chinese Academy of Sciences , Yanqihu Campus, Beijing 101407, People’s Republic of ChinaLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China; School of Future Technology, University of Chinese Academy of Sciences , Yanqihu Campus, Beijing 101407, People’s Republic of ChinaLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China; School of Future Technology, University of Chinese Academy of Sciences , Yanqihu Campus, Beijing 101407, People’s Republic of ChinaLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of China; School of Future Technology, University of Chinese Academy of Sciences , Yanqihu Campus, Beijing 101407, People’s Republic of ChinaDepartment of Applied Physics, Osaka University , 2-1 Yamadaoka, Suita, Osaka 565-0871, JapanLaboratory of Organic NanoPhotonics and CAS Key Laboratory of Bio-Inspired Materials and Interfacial Science , Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People’s Republic of ChinaChitosan (CS)-based nanocomposites have been studied in various fields, requiring a more facile and efficient technique to fabricate nanoparticles with customized structures. In this study, Ag@methacrylamide CS/poly(ethylene glycol) diacrylate (Ag@MP) micropatterns are successfully fabricated by femtosecond laser maskless optical projection lithography (Fs-MOPL) for the first time. The formation mechanism of core-shell nanomaterial is demonstrated by the local surface plasmon resonances and the nucleation and growth theory. Amino and hydroxyl groups greatly affect the number of Ag@MP nanocomposites, which is further verified by replacing MCS with methacrylated bovine serum albumin and hyaluronic acid methacryloyl, respectively. Besides, the performance of the surface-enhanced Raman scattering, cytotoxicity, cell proliferation, and antibacterial was investigated on Ag@MP micropatterns. Therefore, the proposed protocol to prepare hydrogel core-shell micropattern by the home-built Fs-MOPL technique is prospective for potential applications in the biomedical and biotechnological fields, such as biosensors, cell imaging, and antimicrobial.https://doi.org/10.1088/2631-7990/ada83afemtosecond laser maskless optical projection lithographymicropatternsAg@MCS/PEGDA nanoparticlescore-shell nanomaterials
spellingShingle Fan-Chun Bin
Xin-Yi Wu
Jie Liu
Xian-Zi Dong
Teng Li
Qi Duan
Jian-Miao Zhang
Katsumasa Fujita
Mei-Ling Zheng
Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography
International Journal of Extreme Manufacturing
femtosecond laser maskless optical projection lithography
micropatterns
Ag@MCS/PEGDA nanoparticles
core-shell nanomaterials
title Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography
title_full Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography
title_fullStr Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography
title_full_unstemmed Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography
title_short Micropattern of core-shell Ag@MCS/PEGDA nanoparticles fabricated by femtosecond laser maskless optical projection lithography
title_sort micropattern of core shell ag mcs pegda nanoparticles fabricated by femtosecond laser maskless optical projection lithography
topic femtosecond laser maskless optical projection lithography
micropatterns
Ag@MCS/PEGDA nanoparticles
core-shell nanomaterials
url https://doi.org/10.1088/2631-7990/ada83a
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