Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode

We investigated the electrochemical behavior of hemoglobin by glassy carbon electrode modified with Mn2O3-Ag nanofibers. The Mn2O3-Ag nanofibers were used as facilitator electron transfer between Hb and glassy-carbon-modified electrode. The Mn2O3-Ag nanofibers are studied by scanning electron micros...

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Main Authors: Masoud Negahdary, Gholamreza Mazaheri, Somyyeh Rad, Mohammadreza Hadi, Roya Malekzadeh, Mohammad Mahdi Saadatmand, Saeed Rezaei-Zarchi, Fariba Pishbin, Mojdeh Khosravian-hemami
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Analytical Chemistry
Online Access:http://dx.doi.org/10.1155/2012/375831
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author Masoud Negahdary
Gholamreza Mazaheri
Somyyeh Rad
Mohammadreza Hadi
Roya Malekzadeh
Mohammad Mahdi Saadatmand
Saeed Rezaei-Zarchi
Fariba Pishbin
Mojdeh Khosravian-hemami
author_facet Masoud Negahdary
Gholamreza Mazaheri
Somyyeh Rad
Mohammadreza Hadi
Roya Malekzadeh
Mohammad Mahdi Saadatmand
Saeed Rezaei-Zarchi
Fariba Pishbin
Mojdeh Khosravian-hemami
author_sort Masoud Negahdary
collection DOAJ
description We investigated the electrochemical behavior of hemoglobin by glassy carbon electrode modified with Mn2O3-Ag nanofibers. The Mn2O3-Ag nanofibers were used as facilitator electron transfer between Hb and glassy-carbon-modified electrode. The Mn2O3-Ag nanofibers are studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The hemoglobin showed a quasireversible electrochemical redox behavior with a formal potential of −49 mV (versus Ag/AgCl) in 0.1 M potassium phosphate buffer solution at pH 7.0. The designed biosensor possesses good stability and reproducibility and achieves 95% of the steady-state current in less than five seconds.
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institution Kabale University
issn 1687-8760
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language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series International Journal of Analytical Chemistry
spelling doaj-art-8c57a0f6c6f247e1a2fabe3c4cff3d8b2025-02-03T01:29:57ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792012-01-01201210.1155/2012/375831375831Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon ElectrodeMasoud Negahdary0Gholamreza Mazaheri1Somyyeh Rad2Mohammadreza Hadi3Roya Malekzadeh4Mohammad Mahdi Saadatmand5Saeed Rezaei-Zarchi6Fariba Pishbin7Mojdeh Khosravian-hemami8Department of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Shahrekord University, Shahrekord, IranDepartment of Biology, Payam-e-Noor University, Taft, IranYoung Researchers Club, Islamic Azad University, Yazd Branch, Yazd, IranDepartment of Biology, Payam-e-Noor University, Taft, IranDepartment of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Shahrekord University, Shahrekord, IranWe investigated the electrochemical behavior of hemoglobin by glassy carbon electrode modified with Mn2O3-Ag nanofibers. The Mn2O3-Ag nanofibers were used as facilitator electron transfer between Hb and glassy-carbon-modified electrode. The Mn2O3-Ag nanofibers are studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The hemoglobin showed a quasireversible electrochemical redox behavior with a formal potential of −49 mV (versus Ag/AgCl) in 0.1 M potassium phosphate buffer solution at pH 7.0. The designed biosensor possesses good stability and reproducibility and achieves 95% of the steady-state current in less than five seconds.http://dx.doi.org/10.1155/2012/375831
spellingShingle Masoud Negahdary
Gholamreza Mazaheri
Somyyeh Rad
Mohammadreza Hadi
Roya Malekzadeh
Mohammad Mahdi Saadatmand
Saeed Rezaei-Zarchi
Fariba Pishbin
Mojdeh Khosravian-hemami
Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
International Journal of Analytical Chemistry
title Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
title_full Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
title_fullStr Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
title_full_unstemmed Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
title_short Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
title_sort direct electron transfer of hemoglobin on manganese iii oxide ag nanofibers modified glassy carbon electrode
url http://dx.doi.org/10.1155/2012/375831
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