Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode
We investigated the electrochemical behavior of hemoglobin by glassy carbon electrode modified with Mn2O3-Ag nanofibers. The Mn2O3-Ag nanofibers were used as facilitator electron transfer between Hb and glassy-carbon-modified electrode. The Mn2O3-Ag nanofibers are studied by scanning electron micros...
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Format: | Article |
Language: | English |
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Wiley
2012-01-01
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Series: | International Journal of Analytical Chemistry |
Online Access: | http://dx.doi.org/10.1155/2012/375831 |
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author | Masoud Negahdary Gholamreza Mazaheri Somyyeh Rad Mohammadreza Hadi Roya Malekzadeh Mohammad Mahdi Saadatmand Saeed Rezaei-Zarchi Fariba Pishbin Mojdeh Khosravian-hemami |
author_facet | Masoud Negahdary Gholamreza Mazaheri Somyyeh Rad Mohammadreza Hadi Roya Malekzadeh Mohammad Mahdi Saadatmand Saeed Rezaei-Zarchi Fariba Pishbin Mojdeh Khosravian-hemami |
author_sort | Masoud Negahdary |
collection | DOAJ |
description | We investigated the electrochemical behavior of hemoglobin by glassy carbon electrode modified with Mn2O3-Ag nanofibers. The Mn2O3-Ag nanofibers were used as facilitator electron transfer between Hb and glassy-carbon-modified electrode. The Mn2O3-Ag nanofibers are studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The hemoglobin showed a quasireversible electrochemical redox behavior with a formal potential of −49 mV (versus Ag/AgCl) in 0.1 M potassium phosphate buffer solution at pH 7.0. The designed biosensor possesses good stability and reproducibility and achieves 95% of the steady-state current in less than five seconds. |
format | Article |
id | doaj-art-8c57a0f6c6f247e1a2fabe3c4cff3d8b |
institution | Kabale University |
issn | 1687-8760 1687-8779 |
language | English |
publishDate | 2012-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Analytical Chemistry |
spelling | doaj-art-8c57a0f6c6f247e1a2fabe3c4cff3d8b2025-02-03T01:29:57ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792012-01-01201210.1155/2012/375831375831Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon ElectrodeMasoud Negahdary0Gholamreza Mazaheri1Somyyeh Rad2Mohammadreza Hadi3Roya Malekzadeh4Mohammad Mahdi Saadatmand5Saeed Rezaei-Zarchi6Fariba Pishbin7Mojdeh Khosravian-hemami8Department of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Shahrekord University, Shahrekord, IranDepartment of Biology, Payam-e-Noor University, Taft, IranYoung Researchers Club, Islamic Azad University, Yazd Branch, Yazd, IranDepartment of Biology, Payam-e-Noor University, Taft, IranDepartment of Biology, Payam-e-Noor University, Tehran 7371719578, IranDepartment of Biology, Shahrekord University, Shahrekord, IranWe investigated the electrochemical behavior of hemoglobin by glassy carbon electrode modified with Mn2O3-Ag nanofibers. The Mn2O3-Ag nanofibers were used as facilitator electron transfer between Hb and glassy-carbon-modified electrode. The Mn2O3-Ag nanofibers are studied by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The hemoglobin showed a quasireversible electrochemical redox behavior with a formal potential of −49 mV (versus Ag/AgCl) in 0.1 M potassium phosphate buffer solution at pH 7.0. The designed biosensor possesses good stability and reproducibility and achieves 95% of the steady-state current in less than five seconds.http://dx.doi.org/10.1155/2012/375831 |
spellingShingle | Masoud Negahdary Gholamreza Mazaheri Somyyeh Rad Mohammadreza Hadi Roya Malekzadeh Mohammad Mahdi Saadatmand Saeed Rezaei-Zarchi Fariba Pishbin Mojdeh Khosravian-hemami Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode International Journal of Analytical Chemistry |
title | Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode |
title_full | Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode |
title_fullStr | Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode |
title_full_unstemmed | Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode |
title_short | Direct Electron Transfer of Hemoglobin on Manganese III Oxide-Ag Nanofibers Modified Glassy Carbon Electrode |
title_sort | direct electron transfer of hemoglobin on manganese iii oxide ag nanofibers modified glassy carbon electrode |
url | http://dx.doi.org/10.1155/2012/375831 |
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