Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst

Polyaniline salt form (PANI-ES) was synthesized by oxidative polymerization of aniline using potassium persulfate as an oxidant and an acid-exchanged montmorillonite clay called Maghnite-H+ as an effective catalyst. The clay, which was used as a catalyst, was supplied by a local company known as ENO...

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Main Authors: Rahmouni Abdelkader, Harrane Amine, Belbachir Mohammed
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2012/846710
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author Rahmouni Abdelkader
Harrane Amine
Belbachir Mohammed
author_facet Rahmouni Abdelkader
Harrane Amine
Belbachir Mohammed
author_sort Rahmouni Abdelkader
collection DOAJ
description Polyaniline salt form (PANI-ES) was synthesized by oxidative polymerization of aniline using potassium persulfate as an oxidant and an acid-exchanged montmorillonite clay called Maghnite-H+ as an effective catalyst. The clay, which was used as a catalyst, was supplied by a local company known as ENOF Maghnia (Western Algeria). The chemical stability of PANI has been investigated by thermogravimetry and differential scanning calorimetry, that a good thermal stability of PANI could be improved by combining PANI with montmorillonite. TGA results illustrated that there were two major stages for weight loss of the ES-form PANI powder sample. The different forms of PANI were characterized by infrared spectroscopy, thermal analysis, and H-NMR spectroscopy and conductivity measurements.
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institution Kabale University
issn 1687-9422
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language English
publishDate 2012-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-8b838527aea24a0bae169a088f8e05832025-02-03T01:03:00ZengWileyInternational Journal of Polymer Science1687-94221687-94302012-01-01201210.1155/2012/846710846710Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective CatalystRahmouni Abdelkader0Harrane Amine1Belbachir Mohammed2Département de Chimie, Faculté des Sciences, Université d’Oran, BP 1524, El M'nouar, 31000 Oran, AlgeriaDépartement de Chimie, Faculté des Sciences, Université d’Oran, BP 1524, El M'nouar, 31000 Oran, AlgeriaDépartement de Chimie, Faculté des Sciences, Université d’Oran, BP 1524, El M'nouar, 31000 Oran, AlgeriaPolyaniline salt form (PANI-ES) was synthesized by oxidative polymerization of aniline using potassium persulfate as an oxidant and an acid-exchanged montmorillonite clay called Maghnite-H+ as an effective catalyst. The clay, which was used as a catalyst, was supplied by a local company known as ENOF Maghnia (Western Algeria). The chemical stability of PANI has been investigated by thermogravimetry and differential scanning calorimetry, that a good thermal stability of PANI could be improved by combining PANI with montmorillonite. TGA results illustrated that there were two major stages for weight loss of the ES-form PANI powder sample. The different forms of PANI were characterized by infrared spectroscopy, thermal analysis, and H-NMR spectroscopy and conductivity measurements.http://dx.doi.org/10.1155/2012/846710
spellingShingle Rahmouni Abdelkader
Harrane Amine
Belbachir Mohammed
Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst
International Journal of Polymer Science
title Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst
title_full Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst
title_fullStr Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst
title_full_unstemmed Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst
title_short Thermally Stable Forms of Pure Polyaniline Catalyzed by an Acid-Exchanged Montmorillonite Clay Called Maghnite-H+ as an Effective Catalyst
title_sort thermally stable forms of pure polyaniline catalyzed by an acid exchanged montmorillonite clay called maghnite h as an effective catalyst
url http://dx.doi.org/10.1155/2012/846710
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AT harraneamine thermallystableformsofpurepolyanilinecatalyzedbyanacidexchangedmontmorilloniteclaycalledmaghnitehasaneffectivecatalyst
AT belbachirmohammed thermallystableformsofpurepolyanilinecatalyzedbyanacidexchangedmontmorilloniteclaycalledmaghnitehasaneffectivecatalyst