UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications

Metal-organic frameworks (MOFs) have been recognized as promising materials for membrane-based separation technologies due to their exceptional porosity, structural tunability, and chemical stability. This review presents a comprehensive discussion of the advancements in structure engineering and de...

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Main Author: Yanwei Sun
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Membranes
Subjects:
Online Access:https://www.mdpi.com/2077-0375/15/1/8
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author Yanwei Sun
author_facet Yanwei Sun
author_sort Yanwei Sun
collection DOAJ
description Metal-organic frameworks (MOFs) have been recognized as promising materials for membrane-based separation technologies due to their exceptional porosity, structural tunability, and chemical stability. This review presents a comprehensive discussion of the advancements in structure engineering and design strategies that have been employed to optimize UiO-66 membranes for enhanced separation performance. Various synthesis methods for UiO-66 membranes are explored, with a focus on modulated approaches that incorporate different modulators to fine-tune nucleation rates and crystallization processes. The influence of preferred orientation, membrane thickness, pore size, pore surface chemistry, and hierarchical structures on the separation performance is concluded. By providing a consolidated overview of current research efforts and future directions in UiO-66 membrane development, this review aims to inspire further advancements in the field of separation technologies.
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institution Kabale University
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spelling doaj-art-8b683625982b4825a45d6c6c5a45005a2025-01-24T13:40:59ZengMDPI AGMembranes2077-03752025-01-01151810.3390/membranes15010008UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation ApplicationsYanwei Sun0Faculty of Arts and Sciences, Beijing Normal University, Zhuhai 519087, ChinaMetal-organic frameworks (MOFs) have been recognized as promising materials for membrane-based separation technologies due to their exceptional porosity, structural tunability, and chemical stability. This review presents a comprehensive discussion of the advancements in structure engineering and design strategies that have been employed to optimize UiO-66 membranes for enhanced separation performance. Various synthesis methods for UiO-66 membranes are explored, with a focus on modulated approaches that incorporate different modulators to fine-tune nucleation rates and crystallization processes. The influence of preferred orientation, membrane thickness, pore size, pore surface chemistry, and hierarchical structures on the separation performance is concluded. By providing a consolidated overview of current research efforts and future directions in UiO-66 membrane development, this review aims to inspire further advancements in the field of separation technologies.https://www.mdpi.com/2077-0375/15/1/8MOF membraneUiO-66structure manipulationsynthesis methodsseparation performance
spellingShingle Yanwei Sun
UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications
Membranes
MOF membrane
UiO-66
structure manipulation
synthesis methods
separation performance
title UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications
title_full UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications
title_fullStr UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications
title_full_unstemmed UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications
title_short UiO-66 Metal-Organic Framework Membranes: Structural Engineering for Separation Applications
title_sort uio 66 metal organic framework membranes structural engineering for separation applications
topic MOF membrane
UiO-66
structure manipulation
synthesis methods
separation performance
url https://www.mdpi.com/2077-0375/15/1/8
work_keys_str_mv AT yanweisun uio66metalorganicframeworkmembranesstructuralengineeringforseparationapplications