Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes

One long-standing and crucial issue in the study of quasicrystals has been to identify the physical properties characteristic of quasicrystals. The large positive temperature coefficient of thermal conductivity at temperatures above room temperature, which has been observed in several quasicrystals,...

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Main Authors: Takashi Kurono, Jinjia Zhang, Yasushi Kamimura, Keiichi Edagawa
Format: Article
Language:English
Published: Taylor & Francis Group 2025-12-01
Series:Science and Technology of Advanced Materials: Methods
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Online Access:https://www.tandfonline.com/doi/10.1080/27660400.2024.2444866
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author Takashi Kurono
Jinjia Zhang
Yasushi Kamimura
Keiichi Edagawa
author_facet Takashi Kurono
Jinjia Zhang
Yasushi Kamimura
Keiichi Edagawa
author_sort Takashi Kurono
collection DOAJ
description One long-standing and crucial issue in the study of quasicrystals has been to identify the physical properties characteristic of quasicrystals. The large positive temperature coefficient of thermal conductivity at temperatures above room temperature, which has been observed in several quasicrystals, is one such characteristic property. Here, we show that this is indeed a very distinct property of quasicrystals through analysis using a large physical property database ‘Starrydata’. In fact, several quasicrystals ranked nearly first among more than 10,000 samples of various materials (metallic alloys, semiconductors, ceramics, etc.) in terms of the magnitude of the positive temperature coefficient of thermal conductivity. This unique property makes quasicrystals ideal for use in composite thermal diodes. We searched the database for the most suitable materials that can be combined with quasicrystals to create high-performance composite thermal diodes. Analytical calculations using a simple one-dimensional model showed that by selecting the optimal material, a thermal rectification ratio of 3.2 can be obtained. Heat transfer simulations based on the finite element method confirmed that this can be achieved under realistic conditions. This is the highest value of the thermal rectification ratio reported to date for a solid-state composite thermal diode.
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spelling doaj-art-8882feb7e8c2481887584d051ade1b562025-02-03T10:55:19ZengTaylor & Francis GroupScience and Technology of Advanced Materials: Methods2766-04002025-12-015110.1080/27660400.2024.2444866Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodesTakashi Kurono0Jinjia Zhang1Yasushi Kamimura2Keiichi Edagawa3Institute of Industrial Science, The University of Tokyo, Tokyo, JapanInstitute of Industrial Science, The University of Tokyo, Tokyo, JapanInstitute of Industrial Science, The University of Tokyo, Tokyo, JapanInstitute of Industrial Science, The University of Tokyo, Tokyo, JapanOne long-standing and crucial issue in the study of quasicrystals has been to identify the physical properties characteristic of quasicrystals. The large positive temperature coefficient of thermal conductivity at temperatures above room temperature, which has been observed in several quasicrystals, is one such characteristic property. Here, we show that this is indeed a very distinct property of quasicrystals through analysis using a large physical property database ‘Starrydata’. In fact, several quasicrystals ranked nearly first among more than 10,000 samples of various materials (metallic alloys, semiconductors, ceramics, etc.) in terms of the magnitude of the positive temperature coefficient of thermal conductivity. This unique property makes quasicrystals ideal for use in composite thermal diodes. We searched the database for the most suitable materials that can be combined with quasicrystals to create high-performance composite thermal diodes. Analytical calculations using a simple one-dimensional model showed that by selecting the optimal material, a thermal rectification ratio of 3.2 can be obtained. Heat transfer simulations based on the finite element method confirmed that this can be achieved under realistic conditions. This is the highest value of the thermal rectification ratio reported to date for a solid-state composite thermal diode.https://www.tandfonline.com/doi/10.1080/27660400.2024.2444866Quasicrystalsthermal conductivitythermal diodesStarrydataheat transfer simulations
spellingShingle Takashi Kurono
Jinjia Zhang
Yasushi Kamimura
Keiichi Edagawa
Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
Science and Technology of Advanced Materials: Methods
Quasicrystals
thermal conductivity
thermal diodes
Starrydata
heat transfer simulations
title Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
title_full Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
title_fullStr Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
title_full_unstemmed Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
title_short Large-scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
title_sort large scale database analysis of anomalous thermal conductivity of quasicrystals and its application to thermal diodes
topic Quasicrystals
thermal conductivity
thermal diodes
Starrydata
heat transfer simulations
url https://www.tandfonline.com/doi/10.1080/27660400.2024.2444866
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