2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity
2,4-Dichlorophenoxyacetic acid derived Schiff base (HL) and its lanthanide [La(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Dy(III), Y(III)] complexes were synthesized and characterized by various spectroscopic (1H, 13C, DEPT and 2D HMQC NMR, FT-IR, UV-Vis, and mass) techniques and other analy...
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/810892 |
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| author | Ganesh N. Naik Raghavendra P. Bakale Aishakhanam H. Pathan Shashikala G. Ligade Shreenivas A. Desai Kalagouda B. Gudasi |
| author_facet | Ganesh N. Naik Raghavendra P. Bakale Aishakhanam H. Pathan Shashikala G. Ligade Shreenivas A. Desai Kalagouda B. Gudasi |
| author_sort | Ganesh N. Naik |
| collection | DOAJ |
| description | 2,4-Dichlorophenoxyacetic acid derived Schiff base (HL) and its lanthanide [La(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Dy(III), Y(III)] complexes were synthesized and characterized by various spectroscopic (1H, 13C, DEPT and 2D HMQC NMR, FT-IR, UV-Vis, and mass) techniques and other analytical methods. HL exhibits “E” and “Z” isomerism and was confirmed by variable temperature 1H NMR studies. The spectral and analytical data reveals the bidentate coordination of HL to lanthanide(III) ion, through carboxylic acid group via deprotonation. Fluorescence spectrum of europium complex shows bands at 578, 592, and 612 nm assignable to D05→F07, D05→F17, and D05→F27, respectively. Auxin activity of HL and lanthanum(III) complex on wheat seeds (Triticum durum) was measured at different concentrations. The percentage germination, root length, and shoot length were recorded. An enhancement in the plant growth activity of the ligand was observed on complexation and the best activity was observed at 10−6 M concentration. |
| format | Article |
| id | doaj-art-8882fd9f4e3c481b984d0c99afd69eaf |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-8882fd9f4e3c481b984d0c99afd69eaf2025-02-03T01:11:01ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/8108928108922,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth ActivityGanesh N. Naik0Raghavendra P. Bakale1Aishakhanam H. Pathan2Shashikala G. Ligade3Shreenivas A. Desai4Kalagouda B. Gudasi5Department of Chemistry, Karnatak University, Pavate Nagar, Karnataka, Dharwad 580003, IndiaDepartment of Chemistry, Karnatak University, Pavate Nagar, Karnataka, Dharwad 580003, IndiaDepartment of Chemistry, Karnatak University, Pavate Nagar, Karnataka, Dharwad 580003, IndiaDepartment of Botany, Karnatak Science College, Karnataka, Dharwad 580001, IndiaDepartment of Genetics and Plant Breeding, University of Agricultural Sciences, Karnataka Dharwad, 580005, IndiaDepartment of Chemistry, Karnatak University, Pavate Nagar, Karnataka, Dharwad 580003, India2,4-Dichlorophenoxyacetic acid derived Schiff base (HL) and its lanthanide [La(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Dy(III), Y(III)] complexes were synthesized and characterized by various spectroscopic (1H, 13C, DEPT and 2D HMQC NMR, FT-IR, UV-Vis, and mass) techniques and other analytical methods. HL exhibits “E” and “Z” isomerism and was confirmed by variable temperature 1H NMR studies. The spectral and analytical data reveals the bidentate coordination of HL to lanthanide(III) ion, through carboxylic acid group via deprotonation. Fluorescence spectrum of europium complex shows bands at 578, 592, and 612 nm assignable to D05→F07, D05→F17, and D05→F27, respectively. Auxin activity of HL and lanthanum(III) complex on wheat seeds (Triticum durum) was measured at different concentrations. The percentage germination, root length, and shoot length were recorded. An enhancement in the plant growth activity of the ligand was observed on complexation and the best activity was observed at 10−6 M concentration.http://dx.doi.org/10.1155/2013/810892 |
| spellingShingle | Ganesh N. Naik Raghavendra P. Bakale Aishakhanam H. Pathan Shashikala G. Ligade Shreenivas A. Desai Kalagouda B. Gudasi 2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity Journal of Chemistry |
| title | 2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity |
| title_full | 2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity |
| title_fullStr | 2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity |
| title_full_unstemmed | 2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity |
| title_short | 2,4-Dichlorophenoxyacetic Acid Derived Schiff Base and Its Lanthanide(III) Complexes: Synthesis, Characterization, Spectroscopic Studies, and Plant Growth Activity |
| title_sort | 2 4 dichlorophenoxyacetic acid derived schiff base and its lanthanide iii complexes synthesis characterization spectroscopic studies and plant growth activity |
| url | http://dx.doi.org/10.1155/2013/810892 |
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