SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive
SO2 removal has drawn extensive attentions for air pollution treatment. In this paper, the pulse streamer discharge technique is investigated. Emission spectra diagnosis experimentally indicates that the SO2 molecule has been physically dissociated into SO and O radicals by electron collision and ca...
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2015/872964 |
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| author | Xiaojun Wang Lianshui Zhang |
| author_facet | Xiaojun Wang Lianshui Zhang |
| author_sort | Xiaojun Wang |
| collection | DOAJ |
| description | SO2 removal has drawn extensive attentions for air pollution treatment. In this paper, the pulse streamer discharge technique is investigated. Emission spectra diagnosis experimentally indicates that the SO2 molecule has been physically dissociated into SO and O radicals by electron collision and can be remediated through further chemical reactions during and after discharge. In order to quantitatively analyze the removal physical chemistry kinetics, a zero-dimensional physicochemical reaction model is established. Without H2O vapor additive, the SO2 removal efficiency is leanly low and only 0.296% has been achieved under pulse discharge duration of 0.5 μs. Through increasing the electrical concentration six times, the removal efficiency has been slightly heightened to 1.796% at pulse duration of 3 μs. Contrarily, vapor additive can effectively improve the removal kinetics, and removal efficiency has been remarkably heightened to 13.0195% at pulse duration of 0.5 μs with H2O/SO2 initial concentration ratio of 0.1 : 1. OH radicals decomposed from H2O through electron collision are the essential factor to achieve such improvement, which have effectively adjusted the chemical removal process to the favorite directions. The major productions have been transformed from HSO3 and HOSO2 to H2SO4 when vapor ratio increased above 1.27 : 1. |
| format | Article |
| id | doaj-art-87488232e05f48a186ed60f7c56c3f70 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-87488232e05f48a186ed60f7c56c3f702025-02-03T01:25:23ZengWileyJournal of Chemistry2090-90632090-90712015-01-01201510.1155/2015/872964872964SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor AdditiveXiaojun Wang0Lianshui Zhang1Science and Technology College, North China Electric Power University, Baoding, Hebei 071051, ChinaCollege of Physics Science and Technology, Hebei University, Baoding, Hebei 071000, ChinaSO2 removal has drawn extensive attentions for air pollution treatment. In this paper, the pulse streamer discharge technique is investigated. Emission spectra diagnosis experimentally indicates that the SO2 molecule has been physically dissociated into SO and O radicals by electron collision and can be remediated through further chemical reactions during and after discharge. In order to quantitatively analyze the removal physical chemistry kinetics, a zero-dimensional physicochemical reaction model is established. Without H2O vapor additive, the SO2 removal efficiency is leanly low and only 0.296% has been achieved under pulse discharge duration of 0.5 μs. Through increasing the electrical concentration six times, the removal efficiency has been slightly heightened to 1.796% at pulse duration of 3 μs. Contrarily, vapor additive can effectively improve the removal kinetics, and removal efficiency has been remarkably heightened to 13.0195% at pulse duration of 0.5 μs with H2O/SO2 initial concentration ratio of 0.1 : 1. OH radicals decomposed from H2O through electron collision are the essential factor to achieve such improvement, which have effectively adjusted the chemical removal process to the favorite directions. The major productions have been transformed from HSO3 and HOSO2 to H2SO4 when vapor ratio increased above 1.27 : 1.http://dx.doi.org/10.1155/2015/872964 |
| spellingShingle | Xiaojun Wang Lianshui Zhang SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive Journal of Chemistry |
| title | SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive |
| title_full | SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive |
| title_fullStr | SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive |
| title_full_unstemmed | SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive |
| title_short | SO2 Gas Physicochemical Removal through Pulse Streamer Discharge Technique Assisted by Vapor Additive |
| title_sort | so2 gas physicochemical removal through pulse streamer discharge technique assisted by vapor additive |
| url | http://dx.doi.org/10.1155/2015/872964 |
| work_keys_str_mv | AT xiaojunwang so2gasphysicochemicalremovalthroughpulsestreamerdischargetechniqueassistedbyvaporadditive AT lianshuizhang so2gasphysicochemicalremovalthroughpulsestreamerdischargetechniqueassistedbyvaporadditive |