Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin

This work aims to study the influence of submicron metakaolin (SMK) on the mechanical strength, pore structure, and microstructural properties of hardened cement-based slurry (HCS). Portland cement was replaced by SMK at a proportion of 1, 3, 5, and 7 wt%. The compressive strength and flexural stren...

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Main Authors: Yaoyu Wang, Jiye Li, Lihan Jiang, Lihua Zhao
Format: Article
Language:English
Published: Wiley 2020-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2020/8882385
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author Yaoyu Wang
Jiye Li
Lihan Jiang
Lihua Zhao
author_facet Yaoyu Wang
Jiye Li
Lihan Jiang
Lihua Zhao
author_sort Yaoyu Wang
collection DOAJ
description This work aims to study the influence of submicron metakaolin (SMK) on the mechanical strength, pore structure, and microstructural properties of hardened cement-based slurry (HCS). Portland cement was replaced by SMK at a proportion of 1, 3, 5, and 7 wt%. The compressive strength and flexural strength of the HCS samples were tested at a curing period of 3, 7, 14, and 28 days, and the pore structure of the specimens was analyzed by mercury intrusion porosimetry (MIP) at a curing period of 3 and 28 days. The microstructure characteristics of the hardened samples were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Thermogravimetric analysis (TGA) was also employed to analyze the change in the chemical composition of the HCS. The results showed that the SMK could accelerate the hydration rate of the cement and could improve the mechanical properties of the HCS; the compressive strength and flexural strength of the HCS samples were remarkably enhanced, compared to those of the plain cement, by 67 and 46%, respectively, at a curing period of 3 days and by 33 and 35%, respectively, at a curing period of 28 days. The SMK had a significant impact on the internal pore structure of the hardened samples, and the number of pores with a diameter of larger than 3000 nm significantly decreased. Because the hydration products filled the pores, the microstructure of the HCS was further refined and densified with the addition of SMK. Submicron metakaolin has a simple process and high activity, which can significantly improve the performance of the cement slurry. Therefore, submicron metakaolin has the potential for practical engineering applications.
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spelling doaj-art-86d2af6e807e4688948ae1bbc939ef022025-02-03T05:51:17ZengWileyAdvances in Civil Engineering1687-80861687-80942020-01-01202010.1155/2020/88823858882385Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron MetakaolinYaoyu Wang0Jiye Li1Lihan Jiang2Lihua Zhao3Institute of Road and Bridge Engineering, Dalian Maritime University, Dalian, Liaoning 116026, ChinaCollege of Civil Engineering, Dalian Minzu University, Dalian 116650, ChinaInstitute of City, Dalian University of Technology, Dalian, Liaoning 116600, ChinaInstitute of Civil Engineering, Dalian Jiaotong University, Dalian, Liaoning 116028, ChinaThis work aims to study the influence of submicron metakaolin (SMK) on the mechanical strength, pore structure, and microstructural properties of hardened cement-based slurry (HCS). Portland cement was replaced by SMK at a proportion of 1, 3, 5, and 7 wt%. The compressive strength and flexural strength of the HCS samples were tested at a curing period of 3, 7, 14, and 28 days, and the pore structure of the specimens was analyzed by mercury intrusion porosimetry (MIP) at a curing period of 3 and 28 days. The microstructure characteristics of the hardened samples were investigated by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). Thermogravimetric analysis (TGA) was also employed to analyze the change in the chemical composition of the HCS. The results showed that the SMK could accelerate the hydration rate of the cement and could improve the mechanical properties of the HCS; the compressive strength and flexural strength of the HCS samples were remarkably enhanced, compared to those of the plain cement, by 67 and 46%, respectively, at a curing period of 3 days and by 33 and 35%, respectively, at a curing period of 28 days. The SMK had a significant impact on the internal pore structure of the hardened samples, and the number of pores with a diameter of larger than 3000 nm significantly decreased. Because the hydration products filled the pores, the microstructure of the HCS was further refined and densified with the addition of SMK. Submicron metakaolin has a simple process and high activity, which can significantly improve the performance of the cement slurry. Therefore, submicron metakaolin has the potential for practical engineering applications.http://dx.doi.org/10.1155/2020/8882385
spellingShingle Yaoyu Wang
Jiye Li
Lihan Jiang
Lihua Zhao
Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin
Advances in Civil Engineering
title Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin
title_full Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin
title_fullStr Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin
title_full_unstemmed Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin
title_short Enhanced Mechanical and Microstructural Properties of Portland Cement Composites Modified with Submicron Metakaolin
title_sort enhanced mechanical and microstructural properties of portland cement composites modified with submicron metakaolin
url http://dx.doi.org/10.1155/2020/8882385
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AT jiyeli enhancedmechanicalandmicrostructuralpropertiesofportlandcementcompositesmodifiedwithsubmicronmetakaolin
AT lihanjiang enhancedmechanicalandmicrostructuralpropertiesofportlandcementcompositesmodifiedwithsubmicronmetakaolin
AT lihuazhao enhancedmechanicalandmicrostructuralpropertiesofportlandcementcompositesmodifiedwithsubmicronmetakaolin