Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids
Novel carbonate-selective potentiometric sensors based on 5,10,15-tris(4-aminophenyl)-20-phenyl porphyrinates of Cu(II) and Co(II) have been developed. Ionophore functioning mechanism and possible source of carbonate sensitivity have been evolved. Potentiometric properties of Co(II)- and Cu(II)TATPP...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | International Journal of Electrochemistry |
| Online Access: | http://dx.doi.org/10.4061/2011/930203 |
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| author | Larisa Lvova Roberto Paolesse Corrado Di Natale Arnaldo D'Amico Alberto Bergamini |
| author_facet | Larisa Lvova Roberto Paolesse Corrado Di Natale Arnaldo D'Amico Alberto Bergamini |
| author_sort | Larisa Lvova |
| collection | DOAJ |
| description | Novel carbonate-selective potentiometric sensors based on 5,10,15-tris(4-aminophenyl)-20-phenyl porphyrinates of Cu(II) and Co(II) have been developed. Ionophore functioning mechanism and possible source of carbonate sensitivity have been evolved. Potentiometric properties of Co(II)- and Cu(II)TATPP-based sensors were compared with common carbonate-ISEs containing trifluoroacetophenone derivatives. The analytical utility of newly developed sensors has been demonstrated by measuring the bicarbonate content in human blood plasma. |
| format | Article |
| id | doaj-art-86c30304685d4d2a8a3871835661e252 |
| institution | Kabale University |
| issn | 2090-3537 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Electrochemistry |
| spelling | doaj-art-86c30304685d4d2a8a3871835661e2522025-02-03T01:31:39ZengWileyInternational Journal of Electrochemistry2090-35372011-01-01201110.4061/2011/930203930203Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological LiquidsLarisa Lvova0Roberto Paolesse1Corrado Di Natale2Arnaldo D'Amico3Alberto Bergamini4Department of Chemical Science and Technologies, University of Rome “Tor Vergata”, 00173 Rome, ItalyDepartment of Chemical Science and Technologies, University of Rome “Tor Vergata”, 00173 Rome, ItalyDepartment of Electronic Engineering, University of Rome “Tor Vergata”, 00173 Rome, ItalyDepartment of Electronic Engineering, University of Rome “Tor Vergata”, 00173 Rome, ItalyDepartment of Public Health and Cellular Biology, University of Rome “Tor Vergata”, 00173 Rome, ItalyNovel carbonate-selective potentiometric sensors based on 5,10,15-tris(4-aminophenyl)-20-phenyl porphyrinates of Cu(II) and Co(II) have been developed. Ionophore functioning mechanism and possible source of carbonate sensitivity have been evolved. Potentiometric properties of Co(II)- and Cu(II)TATPP-based sensors were compared with common carbonate-ISEs containing trifluoroacetophenone derivatives. The analytical utility of newly developed sensors has been demonstrated by measuring the bicarbonate content in human blood plasma.http://dx.doi.org/10.4061/2011/930203 |
| spellingShingle | Larisa Lvova Roberto Paolesse Corrado Di Natale Arnaldo D'Amico Alberto Bergamini Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids International Journal of Electrochemistry |
| title | Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids |
| title_full | Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids |
| title_fullStr | Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids |
| title_full_unstemmed | Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids |
| title_short | Potentiometric Polymeric Film Sensors Based on 5,10,15-tris(4-aminophenyl) Porphyrinates of Co(II) and Cu(II) for Analysis of Biological Liquids |
| title_sort | potentiometric polymeric film sensors based on 5 10 15 tris 4 aminophenyl porphyrinates of co ii and cu ii for analysis of biological liquids |
| url | http://dx.doi.org/10.4061/2011/930203 |
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