Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods

The influence of carbonation on the microstructure of normalised CEM II mortar was studied using nitrogen adsorption and porosity accessible to water. Samples were prepared and subjected to accelerated carbonation at 20°C, 65% relative humidity, and 20% CO2 concentration. Conflicts in results were o...

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Main Author: Son Tung Pham
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2013/672325
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author Son Tung Pham
author_facet Son Tung Pham
author_sort Son Tung Pham
collection DOAJ
description The influence of carbonation on the microstructure of normalised CEM II mortar was studied using nitrogen adsorption and porosity accessible to water. Samples were prepared and subjected to accelerated carbonation at 20°C, 65% relative humidity, and 20% CO2 concentration. Conflicts in results were observed because while the pore size distributions calculated by BJH method from nitrogen adsorption provided evolution of the micro- and mesopores during carbonation, the porosity accessible to water showed changes in all three porous domains: macro-, meso- and micropores. Furthermore, the porous domains explored by water and nitrogen molecules are not the same because of the difference in the molecular sizes. These two techniques are therefore different and help to complementarily evaluate the effects of carbonation. We also examined the evolution of macrophysical properties such as the solid phase volume using helium pycnometry, gas permeability, thermal conductivity, thermal diffusivity, and longitudinal and transverse ultrasonic velocities. This is a multiscale study where results on microstructural changes can help to explain the evolution of macro physical properties.
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spelling doaj-art-8505f4b1951d4eb7a234efc52038aac42025-02-03T01:23:17ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422013-01-01201310.1155/2013/672325672325Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental MethodsSon Tung Pham0Laboratory of Civil Engineering and Mechanical Engineering, Department of Civil Engineering, National Institute of Applied Sciences, 35000 Rennes, FranceThe influence of carbonation on the microstructure of normalised CEM II mortar was studied using nitrogen adsorption and porosity accessible to water. Samples were prepared and subjected to accelerated carbonation at 20°C, 65% relative humidity, and 20% CO2 concentration. Conflicts in results were observed because while the pore size distributions calculated by BJH method from nitrogen adsorption provided evolution of the micro- and mesopores during carbonation, the porosity accessible to water showed changes in all three porous domains: macro-, meso- and micropores. Furthermore, the porous domains explored by water and nitrogen molecules are not the same because of the difference in the molecular sizes. These two techniques are therefore different and help to complementarily evaluate the effects of carbonation. We also examined the evolution of macrophysical properties such as the solid phase volume using helium pycnometry, gas permeability, thermal conductivity, thermal diffusivity, and longitudinal and transverse ultrasonic velocities. This is a multiscale study where results on microstructural changes can help to explain the evolution of macro physical properties.http://dx.doi.org/10.1155/2013/672325
spellingShingle Son Tung Pham
Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods
Advances in Materials Science and Engineering
title Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods
title_full Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods
title_fullStr Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods
title_full_unstemmed Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods
title_short Modifications on Microporosity and Physical Properties of Cement Mortar Caused by Carbonation: Comparison of Experimental Methods
title_sort modifications on microporosity and physical properties of cement mortar caused by carbonation comparison of experimental methods
url http://dx.doi.org/10.1155/2013/672325
work_keys_str_mv AT sontungpham modificationsonmicroporosityandphysicalpropertiesofcementmortarcausedbycarbonationcomparisonofexperimentalmethods