Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra
In spite of chemical shifts (in photo-electron spectra) and interatomic relaxation by condensation of gaseous samples, the difference ΔI between the ionization energies of the monatomic entities and the compounds in the oxidation state z tends to be proportional to z. The new parameter (ΔI/z) seems...
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1976-11-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9327 |
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| Summary: | In spite of chemical shifts (in photo-electron spectra) and interatomic relaxation by condensation of gaseous samples, the difference ΔI between the ionization energies of the monatomic entities and the compounds in the oxidation state z tends to be proportional to z. The new parameter (ΔI/z) seems to indicate a superposition of electrostatic interatomic effects and the screening of the inner shell by external electrons. It is suggested to call the number of electrons in a Kossel isoelectronic series K.
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| ISSN: | 0009-4293 2673-2424 |