Tetracarbonyl (η5-cyclopentadienyl) vanadium Complexes with R3E Substituents (E = Si, Ge, Sn) at the Cp-Ring
The preparation and spectral properties (IR, 1H- and 51V-NMR, MS) of the complexes [(η5-R3EC5H4)V(CO)4], R3E = Me3Si, Et3Ge, Et3Sn and n-Bu3Sn, are described. These compounds are obtained by direct reaction from V(CO)6 and R3EC5H5. The complexes [R3EV(CO)6] are formed as by-products in the case of...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1988-05-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9850 |
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| Summary: | The preparation and spectral properties (IR, 1H- and 51V-NMR, MS) of the complexes [(η5-R3EC5H4)V(CO)4], R3E = Me3Si, Et3Ge, Et3Sn and n-Bu3Sn, are described. These compounds are obtained by direct reaction from V(CO)6 and R3EC5H5. The complexes [R3EV(CO)6] are formed as by-products in the case of E = Sn and Ge. With Ph3PbC5H5, the only metalated complex is [Ph3PbV(CO)6].
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| ISSN: | 0009-4293 2673-2424 |