In situ generated diphenylphosphine-chelated imidazo[1,5-a]pyridin-3-ylidene nickel(0) catalysts for highly efficient acrylate synthesis from ethylene and CO2
Diphenylphosphine-chelated imidazo[1,5-a]pyridin-3-ylidene (PPh₂-ImPy) nickel(0) catalysts were synthesized in-situ from imidazolium salts and various commercially available nickel(0) complexes using a base. These catalysts exhibited a highly planar and rigid structure, as confirmed by X-ray crystal...
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| Main Authors: | Changmuk Kang, Seyong Kim, Woosong Han, Huijeong Ryu, Wooyong Seong, Jiyun Kim, Da-Ae Park, Seongwook Park, Kyungho Park, Hyun Min Park, Hyun Tae Kim, Chang Hee Lee, Sukwon Hong |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-01-01
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| Series: | Journal of CO2 Utilization |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2212982024003391 |
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