Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic

LZSA (Li2O-ZrO2-SiO2-Al2O3) glass ceramic system has shown high potential to obtain LTCC laminate tapes at low sintering temperature (<1000°C) for several applications, such as screen-printed electronic components. Furthermore, LZSA glass ceramics offer interesting mechanical, chemical, and therm...

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Main Authors: Oscar Rubem Klegues Montedo, Dachamir Hotza, Antonio Pedro Novaes de Oliveira, Robert Meszaros, Nahum Travitzky, Peter Greil
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2012/525428
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author Oscar Rubem Klegues Montedo
Dachamir Hotza
Antonio Pedro Novaes de Oliveira
Robert Meszaros
Nahum Travitzky
Peter Greil
author_facet Oscar Rubem Klegues Montedo
Dachamir Hotza
Antonio Pedro Novaes de Oliveira
Robert Meszaros
Nahum Travitzky
Peter Greil
author_sort Oscar Rubem Klegues Montedo
collection DOAJ
description LZSA (Li2O-ZrO2-SiO2-Al2O3) glass ceramic system has shown high potential to obtain LTCC laminate tapes at low sintering temperature (<1000°C) for several applications, such as screen-printed electronic components. Furthermore, LZSA glass ceramics offer interesting mechanical, chemical, and thermal properties, which make LZSA also a potential candidate for fabricating multilayered structures processed by Laminated Objects Manufacturing (LOM) technology. The crystallization kinetics of an LZSA glass ceramic with a composition of 16.9Li2O⋅5.0ZrO2⋅65.1SiO2⋅8.6Al2O3 was investigated using nonisothermal methods by differential thermal analysis and scanning electronic microscopy. Apparent activation energy for crystallization was found to be in the 274–292 kJ⋅mol−1 range, and an Avrami parameter n of 1 was obtained that is compared very favorably with SEM observations.
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series Advances in Materials Science and Engineering
spelling doaj-art-8073f9d21eaa47598ab3e39e60e3b0792025-02-03T05:52:00ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422012-01-01201210.1155/2012/525428525428Crystallisation Kinetics of a β-Spodumene-Based Glass CeramicOscar Rubem Klegues Montedo0Dachamir Hotza1Antonio Pedro Novaes de Oliveira2Robert Meszaros3Nahum Travitzky4Peter Greil5Unidade Acadêmica de Ciências, Engenharias e Tecnologias (UNACET), Universidade do Extremo Sul Catarinense (UNESC), 88806-000 Criciúma, SC, BrazilGroup of Ceramic and Glass Materials (CERMAT), Department of Mechanical Engineering (EMC), Federal University of Santa Catarina (UFSC), 88040-900 Florianópolis, SC, BrazilGroup of Ceramic and Glass Materials (CERMAT), Department of Mechanical Engineering (EMC), Federal University of Santa Catarina (UFSC), 88040-900 Florianópolis, SC, BrazilDepartment of Materials Science, Institute of Glass and Ceramics, University of Erlangen-Nuremberg, 91058 Erlangen, GermanyDepartment of Materials Science, Institute of Glass and Ceramics, University of Erlangen-Nuremberg, 91058 Erlangen, GermanyDepartment of Materials Science, Institute of Glass and Ceramics, University of Erlangen-Nuremberg, 91058 Erlangen, GermanyLZSA (Li2O-ZrO2-SiO2-Al2O3) glass ceramic system has shown high potential to obtain LTCC laminate tapes at low sintering temperature (<1000°C) for several applications, such as screen-printed electronic components. Furthermore, LZSA glass ceramics offer interesting mechanical, chemical, and thermal properties, which make LZSA also a potential candidate for fabricating multilayered structures processed by Laminated Objects Manufacturing (LOM) technology. The crystallization kinetics of an LZSA glass ceramic with a composition of 16.9Li2O⋅5.0ZrO2⋅65.1SiO2⋅8.6Al2O3 was investigated using nonisothermal methods by differential thermal analysis and scanning electronic microscopy. Apparent activation energy for crystallization was found to be in the 274–292 kJ⋅mol−1 range, and an Avrami parameter n of 1 was obtained that is compared very favorably with SEM observations.http://dx.doi.org/10.1155/2012/525428
spellingShingle Oscar Rubem Klegues Montedo
Dachamir Hotza
Antonio Pedro Novaes de Oliveira
Robert Meszaros
Nahum Travitzky
Peter Greil
Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic
Advances in Materials Science and Engineering
title Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic
title_full Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic
title_fullStr Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic
title_full_unstemmed Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic
title_short Crystallisation Kinetics of a β-Spodumene-Based Glass Ceramic
title_sort crystallisation kinetics of a β spodumene based glass ceramic
url http://dx.doi.org/10.1155/2012/525428
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