Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils

In order to establish the differences in packaging containing various essential oils, polylactide (PLA)-based polymeric films incorporating poly(ethylene glycol) (PEG), clove (C), grapefruit (G), rosemary (R), and tea tree (T) essential oils were obtained and subsequently analyzed. In addition to ex...

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Main Authors: Ewa Olewnik-Kruszkowska, Astha Vishwakarma, Magdalena Wrona, Anis Bertella, Anna Rudawska, Magdalena Gierszewska, Beata Schmidt
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/14/2/204
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author Ewa Olewnik-Kruszkowska
Astha Vishwakarma
Magdalena Wrona
Anis Bertella
Anna Rudawska
Magdalena Gierszewska
Beata Schmidt
author_facet Ewa Olewnik-Kruszkowska
Astha Vishwakarma
Magdalena Wrona
Anis Bertella
Anna Rudawska
Magdalena Gierszewska
Beata Schmidt
author_sort Ewa Olewnik-Kruszkowska
collection DOAJ
description In order to establish the differences in packaging containing various essential oils, polylactide (PLA)-based polymeric films incorporating poly(ethylene glycol) (PEG), clove (C), grapefruit (G), rosemary (R), and tea tree (T) essential oils were obtained and subsequently analyzed. In addition to examining structure and morphology, the polymer films underwent analyses that are particularly important with regard to contact with food. Mechanical and antioxidant properties, water vapor transmission rate (WVTR), and analysis of barrier properties against ultraviolet (UV) radiation, as well as the migration of ingredients into food simulants such as 10% <i>v</i>/<i>v</i> solutions of ethanol, 3% <i>w</i>/<i>v</i> acetic acid solution, and isooctane, were among the critical studies conducted. A comparison of the properties of the obtained materials allowed us to establish that the incorporation of essential oils significantly increases elongation at break and enhances UV barrier properties. In the case of materials containing clove oil and tea tree oil, a reduction in WVTR of about 1 g/m<sup>2</sup>/h was observed. The migration of the ingredients present in the films filled with clove oil, grapefruit oil, and tea tree oil into the acetic acid solution did not exceed 10 mg/kg, which is an acceptable value according to the European Union restrictions. Taking into account all of the studied properties, it should be stressed that the most promising packaging material is the film filled with clove oil.
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spelling doaj-art-80099652346b45b89157d8acd3d7d5552025-01-24T13:32:51ZengMDPI AGFoods2304-81582025-01-0114220410.3390/foods14020204Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential OilsEwa Olewnik-Kruszkowska0Astha Vishwakarma1Magdalena Wrona2Anis Bertella3Anna Rudawska4Magdalena Gierszewska5Beata Schmidt6Chair of Physical Chemistry and Physicochemistry of Polymers, Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7 Street, 87-100 Toruń, PolandInstitut de Chimie et des Matériaux Paris-Est (ICMPE), Centre National de la Recherche Scientifique (CNRS), Universite Paris-Est Creteil, UMR 7182, 2 Rue Henri Dunant, 94320 Thiais, FranceForschungszentrum Jülich GmbH, Institute of Bio- and Geosciences 2, 52428 Jülich, GermanyDepartment of Molecular and Cellular Biology, Faculty of Life and Nature Sciences, Abbes Laghrour University Khenchela, BP 1252 Road of Batna, Khenchela 40004, AlgeriaFaculty of Mechanical Engineering, Lublin University of Technology, Nadbystrzycka 36 St., 20-618 Lublin, PolandChair of Physical Chemistry and Physicochemistry of Polymers, Faculty of Chemistry, Nicolaus Copernicus University in Toruń, Gagarina 7 Street, 87-100 Toruń, PolandDepartment of Chemical Organic Technology and Polymeric Materials, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology, Pułaskiego 10, 70-322 Szczecin, PolandIn order to establish the differences in packaging containing various essential oils, polylactide (PLA)-based polymeric films incorporating poly(ethylene glycol) (PEG), clove (C), grapefruit (G), rosemary (R), and tea tree (T) essential oils were obtained and subsequently analyzed. In addition to examining structure and morphology, the polymer films underwent analyses that are particularly important with regard to contact with food. Mechanical and antioxidant properties, water vapor transmission rate (WVTR), and analysis of barrier properties against ultraviolet (UV) radiation, as well as the migration of ingredients into food simulants such as 10% <i>v</i>/<i>v</i> solutions of ethanol, 3% <i>w</i>/<i>v</i> acetic acid solution, and isooctane, were among the critical studies conducted. A comparison of the properties of the obtained materials allowed us to establish that the incorporation of essential oils significantly increases elongation at break and enhances UV barrier properties. In the case of materials containing clove oil and tea tree oil, a reduction in WVTR of about 1 g/m<sup>2</sup>/h was observed. The migration of the ingredients present in the films filled with clove oil, grapefruit oil, and tea tree oil into the acetic acid solution did not exceed 10 mg/kg, which is an acceptable value according to the European Union restrictions. Taking into account all of the studied properties, it should be stressed that the most promising packaging material is the film filled with clove oil.https://www.mdpi.com/2304-8158/14/2/204polylactidepackaging materialsclove oiltea tree oilgrapefruit oilrosemary oil
spellingShingle Ewa Olewnik-Kruszkowska
Astha Vishwakarma
Magdalena Wrona
Anis Bertella
Anna Rudawska
Magdalena Gierszewska
Beata Schmidt
Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils
Foods
polylactide
packaging materials
clove oil
tea tree oil
grapefruit oil
rosemary oil
title Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils
title_full Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils
title_fullStr Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils
title_full_unstemmed Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils
title_short Comparative Study of Crucial Properties of Packaging Based on Polylactide and Selected Essential Oils
title_sort comparative study of crucial properties of packaging based on polylactide and selected essential oils
topic polylactide
packaging materials
clove oil
tea tree oil
grapefruit oil
rosemary oil
url https://www.mdpi.com/2304-8158/14/2/204
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AT magdalenawrona comparativestudyofcrucialpropertiesofpackagingbasedonpolylactideandselectedessentialoils
AT anisbertella comparativestudyofcrucialpropertiesofpackagingbasedonpolylactideandselectedessentialoils
AT annarudawska comparativestudyofcrucialpropertiesofpackagingbasedonpolylactideandselectedessentialoils
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