Evaluation of a Local Clay as a Dehydration Catalyst

Since Egypt is rich in natural clays, they can be used as a cheap local catalyst for dehydration instead of importing synthetic catalysts. Samples from Wadi El Hai Helwan were studied for this purpose in the raw and activated forms. Activation included either thermal activation by calcination of the...

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Main Authors: Susan A. Ali, Maha K. El-Aiashy, Zita S. Ayad
Format: Article
Language:English
Published: SAGE Publishing 1996-12-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749601300604
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author Susan A. Ali
Maha K. El-Aiashy
Zita S. Ayad
author_facet Susan A. Ali
Maha K. El-Aiashy
Zita S. Ayad
author_sort Susan A. Ali
collection DOAJ
description Since Egypt is rich in natural clays, they can be used as a cheap local catalyst for dehydration instead of importing synthetic catalysts. Samples from Wadi El Hai Helwan were studied for this purpose in the raw and activated forms. Activation included either thermal activation by calcination of the clay in a stream of dry air at different temperatures or chemical activation by treatment with different concentrations of sulphuric acid solution. The dehydration activities of the prepared clay catalysts were studied using absolute ethyl alcohol. The optimum conditions for activation were obtained on treating Helwan raw clay with 20% sulphuric acid solution at 104°C at an acid solution/clay ratio of 1.5:1 by weight, followed by calcination at 500°C. The activation energy for this reaction on Helwan clay was estimated as equal to 17.5 kcal/mol.
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2048-4038
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publishDate 1996-12-01
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record_format Article
series Adsorption Science & Technology
spelling doaj-art-7ef07c02558a49d6a0230ab03e2545be2025-02-03T10:07:58ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381996-12-011310.1177/026361749601300604Evaluation of a Local Clay as a Dehydration CatalystSusan A. Ali0Maha K. El-Aiashy1Zita S. Ayad2 Faculty of Girls, Ain Shams University, Cairo, Egypt Faculty of Girls, Ain Shams University, Cairo, Egypt Egyptian Petroleum Research Institute, Nasr City, Cairo, EgyptSince Egypt is rich in natural clays, they can be used as a cheap local catalyst for dehydration instead of importing synthetic catalysts. Samples from Wadi El Hai Helwan were studied for this purpose in the raw and activated forms. Activation included either thermal activation by calcination of the clay in a stream of dry air at different temperatures or chemical activation by treatment with different concentrations of sulphuric acid solution. The dehydration activities of the prepared clay catalysts were studied using absolute ethyl alcohol. The optimum conditions for activation were obtained on treating Helwan raw clay with 20% sulphuric acid solution at 104°C at an acid solution/clay ratio of 1.5:1 by weight, followed by calcination at 500°C. The activation energy for this reaction on Helwan clay was estimated as equal to 17.5 kcal/mol.https://doi.org/10.1177/026361749601300604
spellingShingle Susan A. Ali
Maha K. El-Aiashy
Zita S. Ayad
Evaluation of a Local Clay as a Dehydration Catalyst
Adsorption Science & Technology
title Evaluation of a Local Clay as a Dehydration Catalyst
title_full Evaluation of a Local Clay as a Dehydration Catalyst
title_fullStr Evaluation of a Local Clay as a Dehydration Catalyst
title_full_unstemmed Evaluation of a Local Clay as a Dehydration Catalyst
title_short Evaluation of a Local Clay as a Dehydration Catalyst
title_sort evaluation of a local clay as a dehydration catalyst
url https://doi.org/10.1177/026361749601300604
work_keys_str_mv AT susanaali evaluationofalocalclayasadehydrationcatalyst
AT mahakelaiashy evaluationofalocalclayasadehydrationcatalyst
AT zitasayad evaluationofalocalclayasadehydrationcatalyst