Syntheses and crystal structures of the cerium-based coordination polymers poly[(acetic acid)bis(μ-5-carboxythiophene-2-carboxylato)bis(μ-thiophene-2,5-dicarboxylato)dicerium(III)] and poly[(μ-acetato)aqua(μ4-thiophene-2,5-dicarboxylato)cerium(III)]

Syntheses and crystal structures of the cerium-based coordination polymers poly[(acetic acid)bis(μ-5-carboxythiophene-2-carboxylato)bis(μ-thiophene-2,5-dicarboxylato)dicerium(III)] and poly[(μ-acetato)aqua(μ4-thiophene-2,5-dicarboxylato)cerium(III)]

The title compounds, [Ce2(C6H3SO4)2(C6H2SO4)2(CH3COOH)]n (1) and [Ce(CH3COO)(C6H2SO4)(H2O)]n (2) were synthesized by solvothermal reaction of Ce(NO3)3·6H2O with 2,5-thiophenedicarboxylic acid (H2TDC, C6H4SO4) and acetic acid in acetonitrile or ethanol/water, respectively. These compounds were obtain...

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Bibliographic Details
Main Authors: Niklas Ruser, Christian Näther, Norbert Stock
Format: Article
Language:English
Published: International Union of Crystallography 2025-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
synthesis
crystal structure
solvothermal reaction
coordination polymer
Online Access:https://journals.iucr.org/paper?S2056989025000210
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