Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer
Polyacrylamides constitute a class of polymers that can entirely dissolve or swell in water to form a solution or hydrogel, respectively. Free radical polymerization of acrylamide monomer, using both solution and inverse emulsion polymerization, was applied to produce polyacrylamide with various mol...
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| Format: | Article |
| Language: | English |
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Wiley
2015-01-01
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| Series: | International Journal of Polymer Science |
| Online Access: | http://dx.doi.org/10.1155/2015/436583 |
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| author | Mahmoud A. Mohsin Nuha F. Attia |
| author_facet | Mahmoud A. Mohsin Nuha F. Attia |
| author_sort | Mahmoud A. Mohsin |
| collection | DOAJ |
| description | Polyacrylamides constitute a class of polymers that can entirely dissolve or swell in water to form a solution or hydrogel, respectively. Free radical polymerization of acrylamide monomer, using both solution and inverse emulsion polymerization, was applied to produce polyacrylamide with various molecular weights. This investigation was focused on the production of polymers with varying molecular weight, depending on monomer to initiator ratio. Experimental conditions were designed to produce high molecular weight polymers that can be used in stabilization of sand dunes in the arid regions. Synthesized polyacrylamide samples were characterized using Gel Permeation Chromatography and solution viscosity in order to determine the molecular weights and molecular weights distribution. The rheological behavior was also investigated in different polymer concentrations and at various temperatures using Brookfield Rheometer. Lab-scale wind tunnel was used to determine the stability of the sand before and after treatment with the polymer. Compressive stress-strain test was also used to establish the mechanical behavior of the polymer-sand composite under controlled compressive load up to failure. The results showed that the use of high molecular weight polymer gave excellent mechanical and thermal stability. |
| format | Article |
| id | doaj-art-7e1b6e39e7aa4ece9f32cc1ce97fae9e |
| institution | Kabale University |
| issn | 1687-9422 1687-9430 |
| language | English |
| publishDate | 2015-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Polymer Science |
| spelling | doaj-art-7e1b6e39e7aa4ece9f32cc1ce97fae9e2025-02-03T01:21:43ZengWileyInternational Journal of Polymer Science1687-94221687-94302015-01-01201510.1155/2015/436583436583Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand StabilizerMahmoud A. Mohsin0Nuha F. Attia1Department of Chemistry, University of Sharjah, P.O. Box 27272, Sharjah, UAEAbu Dhabi Polytechnic, P.O. Box 111499, Abu Dhabi, UAEPolyacrylamides constitute a class of polymers that can entirely dissolve or swell in water to form a solution or hydrogel, respectively. Free radical polymerization of acrylamide monomer, using both solution and inverse emulsion polymerization, was applied to produce polyacrylamide with various molecular weights. This investigation was focused on the production of polymers with varying molecular weight, depending on monomer to initiator ratio. Experimental conditions were designed to produce high molecular weight polymers that can be used in stabilization of sand dunes in the arid regions. Synthesized polyacrylamide samples were characterized using Gel Permeation Chromatography and solution viscosity in order to determine the molecular weights and molecular weights distribution. The rheological behavior was also investigated in different polymer concentrations and at various temperatures using Brookfield Rheometer. Lab-scale wind tunnel was used to determine the stability of the sand before and after treatment with the polymer. Compressive stress-strain test was also used to establish the mechanical behavior of the polymer-sand composite under controlled compressive load up to failure. The results showed that the use of high molecular weight polymer gave excellent mechanical and thermal stability.http://dx.doi.org/10.1155/2015/436583 |
| spellingShingle | Mahmoud A. Mohsin Nuha F. Attia Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer International Journal of Polymer Science |
| title | Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer |
| title_full | Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer |
| title_fullStr | Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer |
| title_full_unstemmed | Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer |
| title_short | Inverse Emulsion Polymerization for the Synthesis of High Molecular Weight Polyacrylamide and Its Application as Sand Stabilizer |
| title_sort | inverse emulsion polymerization for the synthesis of high molecular weight polyacrylamide and its application as sand stabilizer |
| url | http://dx.doi.org/10.1155/2015/436583 |
| work_keys_str_mv | AT mahmoudamohsin inverseemulsionpolymerizationforthesynthesisofhighmolecularweightpolyacrylamideanditsapplicationassandstabilizer AT nuhafattia inverseemulsionpolymerizationforthesynthesisofhighmolecularweightpolyacrylamideanditsapplicationassandstabilizer |