(3a,8b)-5-Acetyl-3a-fluoro-6,8-dihydroxy-7,8b-dimethyl-3,3a-dihydrofuro[3,2-b]benzofuran-2(8bH)-one

Usnetic acid is a dibenzofuran-2-ylacetic acid that can be obtained by alkaline degradation of a secondary lichen metabolite—usnic acid. In the present paper, the product of the reaction of usnetic acid with a mild fluorinating agent, Selectfluor<sup>®</sup>, was obtained. The structure...

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Bibliographic Details
Main Authors: Aleksandr S. Filimonov, Stepan P. Zernov, Olga A. Luzina, Nariman F. Salakhutdinov
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Molbank
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Online Access:https://www.mdpi.com/1422-8599/2025/2/M1995
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Summary:Usnetic acid is a dibenzofuran-2-ylacetic acid that can be obtained by alkaline degradation of a secondary lichen metabolite—usnic acid. In the present paper, the product of the reaction of usnetic acid with a mild fluorinating agent, Selectfluor<sup>®</sup>, was obtained. The structure of the product was proved by a set of physical methods, including <sup>1</sup>H, <sup>13</sup>C, <sup>19</sup>F NMR, HMBC, HSQC, HRMS and IR spectroscopy.
ISSN:1422-8599