Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts
Ethanol conversion to C3+ olefins, especially propylene, using Zr-modified H-ZSM-5 catalysts was investigated. Zr-modification to H-ZSM-5 zeolite could improve the initial yield of C3+ olefins and propylene and could reduce the initial yield of ethylene. In general, catalysts exhibiting the higher i...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | Advances in Materials Science and Engineering |
| Online Access: | http://dx.doi.org/10.1155/2012/293485 |
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| author | Megumu Inaba Kazuhisa Murata Isao Takahara Ken-ichiro Inoue |
| author_facet | Megumu Inaba Kazuhisa Murata Isao Takahara Ken-ichiro Inoue |
| author_sort | Megumu Inaba |
| collection | DOAJ |
| description | Ethanol conversion to C3+ olefins, especially propylene, using Zr-modified H-ZSM-5 catalysts was investigated. Zr-modification to H-ZSM-5 zeolite could improve the initial yield of C3+ olefins and propylene and could reduce the initial yield of ethylene. In general, catalysts exhibiting the higher initial yield of propylene showed the steeper decrease in propylene yield as the reaction proceeded. However, Zr-modification to H-ZSM-5 could depress the decrease in propylene yield for aqueous ethanol. As cause of catalytic deactivation, carbon deposition on catalyst and framework collapse of zeolite support can be considered. The addition of water to Zr-modified H-ZSM-5 catalyst could depress carbon deposition in some degree, and, as a result, the decrease in propylene yield could be depressed. |
| format | Article |
| id | doaj-art-7b1525a03860416c91f27931dd115c48 |
| institution | Kabale University |
| issn | 1687-8434 1687-8442 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advances in Materials Science and Engineering |
| spelling | doaj-art-7b1525a03860416c91f27931dd115c482025-02-03T01:30:37ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422012-01-01201210.1155/2012/293485293485Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite CatalystsMegumu Inaba0Kazuhisa Murata1Isao Takahara2Ken-ichiro Inoue3BTL Catalyst Group, Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Ibaraki, Tsukuba 305-8565, JapanBTL Catalyst Group, Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Ibaraki, Tsukuba 305-8565, JapanBTL Catalyst Group, Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Ibaraki, Tsukuba 305-8565, JapanBTL Catalyst Group, Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba Central 5, 1-1-1 Higashi, Ibaraki, Tsukuba 305-8565, JapanEthanol conversion to C3+ olefins, especially propylene, using Zr-modified H-ZSM-5 catalysts was investigated. Zr-modification to H-ZSM-5 zeolite could improve the initial yield of C3+ olefins and propylene and could reduce the initial yield of ethylene. In general, catalysts exhibiting the higher initial yield of propylene showed the steeper decrease in propylene yield as the reaction proceeded. However, Zr-modification to H-ZSM-5 could depress the decrease in propylene yield for aqueous ethanol. As cause of catalytic deactivation, carbon deposition on catalyst and framework collapse of zeolite support can be considered. The addition of water to Zr-modified H-ZSM-5 catalyst could depress carbon deposition in some degree, and, as a result, the decrease in propylene yield could be depressed.http://dx.doi.org/10.1155/2012/293485 |
| spellingShingle | Megumu Inaba Kazuhisa Murata Isao Takahara Ken-ichiro Inoue Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts Advances in Materials Science and Engineering |
| title | Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts |
| title_full | Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts |
| title_fullStr | Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts |
| title_full_unstemmed | Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts |
| title_short | Production of C3+ Olefins and Propylene from Ethanol by Zr-Modified H-ZSM-5 Zeolite Catalysts |
| title_sort | production of c3 olefins and propylene from ethanol by zr modified h zsm 5 zeolite catalysts |
| url | http://dx.doi.org/10.1155/2012/293485 |
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