Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process

High quantity of slurries, kerf, are generated during ingot wafering and represent up to 40% of the silicon in weight. The highly pure silicon contained in kerf is contaminated with organics, metal impurities, water and an oxide layer. The recovery of the silicon could be an efficient way to reduce...

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Main Authors: Marion Chevallier, Jean-Baptiste Antoine, Francis Marchitto, Yoann Doré, Yun Luo, Yohan Parsa
Format: Article
Language:English
Published: TIB Open Publishing 2025-02-01
Series:SiliconPV Conference Proceedings
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Online Access:https://www.tib-op.org/ojs/index.php/siliconpv/article/view/1301
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author Marion Chevallier
Jean-Baptiste Antoine
Francis Marchitto
Yoann Doré
Yun Luo
Yohan Parsa
author_facet Marion Chevallier
Jean-Baptiste Antoine
Francis Marchitto
Yoann Doré
Yun Luo
Yohan Parsa
author_sort Marion Chevallier
collection DOAJ
description High quantity of slurries, kerf, are generated during ingot wafering and represent up to 40% of the silicon in weight. The highly pure silicon contained in kerf is contaminated with organics, metal impurities, water and an oxide layer. The recovery of the silicon could be an efficient way to reduce costs in the production of solar panels through material and energy savings. At high temperatures, organic contamination causes the formation of silicon carbide species that are difficult to segregate during kerf remelting into a pure silicon ingot. Also, during the fusion of silicon, temperatures up to 1500°C are reached and the mixture of silicon and water forms oxides and gases that reduce production yields and affect melting conditions. For these reason, purification and drying steps are required to ensure proper silicon raw material for remelting into ingots. So far, approaches using strong acidic or organic solvent are used to reduce contamination by organic compounds. In this study, more environmentally friendly processes were applied on authentic kerf waste to purify and dry silicon, to make it suitable as raw material for silicon ingot preparation. The amount of water and organic compounds were monitored along the process steps. Using aqueous oxidative processes in combination with filtration, kerf was cleaned and a total carbon reduction of at least 30% was observed. The control of humidity enables the convenient conditioning of purified kerf and effective drying reduced the moisture content to less than 5% wt.
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institution Kabale University
issn 2940-2123
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publishDate 2025-02-01
publisher TIB Open Publishing
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series SiliconPV Conference Proceedings
spelling doaj-art-7b0ab78fdedf48759fb1bb872c51b18e2025-02-04T09:54:12ZengTIB Open PublishingSiliconPV Conference Proceedings2940-21232025-02-01210.52825/siliconpv.v2i.1301Recovery of Silicon Kerf Through Oxidative Cleaning and Drying ProcessMarion Chevallier0https://orcid.org/0000-0002-1950-0182Jean-Baptiste Antoine1https://orcid.org/0009-0003-0088-2293Francis Marchitto2Yoann Doré3Yun Luo4Yohan Parsa5ROSIROSIROSIROSIROSIROSI High quantity of slurries, kerf, are generated during ingot wafering and represent up to 40% of the silicon in weight. The highly pure silicon contained in kerf is contaminated with organics, metal impurities, water and an oxide layer. The recovery of the silicon could be an efficient way to reduce costs in the production of solar panels through material and energy savings. At high temperatures, organic contamination causes the formation of silicon carbide species that are difficult to segregate during kerf remelting into a pure silicon ingot. Also, during the fusion of silicon, temperatures up to 1500°C are reached and the mixture of silicon and water forms oxides and gases that reduce production yields and affect melting conditions. For these reason, purification and drying steps are required to ensure proper silicon raw material for remelting into ingots. So far, approaches using strong acidic or organic solvent are used to reduce contamination by organic compounds. In this study, more environmentally friendly processes were applied on authentic kerf waste to purify and dry silicon, to make it suitable as raw material for silicon ingot preparation. The amount of water and organic compounds were monitored along the process steps. Using aqueous oxidative processes in combination with filtration, kerf was cleaned and a total carbon reduction of at least 30% was observed. The control of humidity enables the convenient conditioning of purified kerf and effective drying reduced the moisture content to less than 5% wt. https://www.tib-op.org/ojs/index.php/siliconpv/article/view/1301KerfSiliconRecyclingOxidative ProcessCleaning Process
spellingShingle Marion Chevallier
Jean-Baptiste Antoine
Francis Marchitto
Yoann Doré
Yun Luo
Yohan Parsa
Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process
SiliconPV Conference Proceedings
Kerf
Silicon
Recycling
Oxidative Process
Cleaning Process
title Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process
title_full Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process
title_fullStr Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process
title_full_unstemmed Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process
title_short Recovery of Silicon Kerf Through Oxidative Cleaning and Drying Process
title_sort recovery of silicon kerf through oxidative cleaning and drying process
topic Kerf
Silicon
Recycling
Oxidative Process
Cleaning Process
url https://www.tib-op.org/ojs/index.php/siliconpv/article/view/1301
work_keys_str_mv AT marionchevallier recoveryofsiliconkerfthroughoxidativecleaninganddryingprocess
AT jeanbaptisteantoine recoveryofsiliconkerfthroughoxidativecleaninganddryingprocess
AT francismarchitto recoveryofsiliconkerfthroughoxidativecleaninganddryingprocess
AT yoanndore recoveryofsiliconkerfthroughoxidativecleaninganddryingprocess
AT yunluo recoveryofsiliconkerfthroughoxidativecleaninganddryingprocess
AT yohanparsa recoveryofsiliconkerfthroughoxidativecleaninganddryingprocess