The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste

Rare earth magnets based upon neodymium-iron-boron (NdFeB) are employed in many high tech applications, including hard disk drives (HDDs). The key elements in manufacturing NdFeB magnets are rare earth elements (REEs) such as neodymium. This element has been subject to significant supply shortfalls...

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Main Authors: Piotrowicz A., Pietrzyk S., Noga P., Myćka Ł.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2020-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2020/1450-53392000032P.pdf
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author Piotrowicz A.
Pietrzyk S.
Noga P.
Myćka Ł.
author_facet Piotrowicz A.
Pietrzyk S.
Noga P.
Myćka Ł.
author_sort Piotrowicz A.
collection DOAJ
description Rare earth magnets based upon neodymium-iron-boron (NdFeB) are employed in many high tech applications, including hard disk drives (HDDs). The key elements in manufacturing NdFeB magnets are rare earth elements (REEs) such as neodymium. This element has been subject to significant supply shortfalls in the recent past. Recycling of NdFeB magnets contained within waste of electrical and electronic equipment (WEEE) could provide a secure and alternative supply of these materials. Various recycling approaches for the recovery of sintered NdFeB magnets have been widely explored. Hydrogen decrepitation (HD) can be used as a direct reuse approach and effective method of recycling process to turn solid sintered magnets into a demagnetised powder for further processing. In this work, sintered Nd-Fe-B magnets were processed without prior removal of the metallic protective layer using the thermal HD process as an alternative recycling method. The gas sorption analyzer was used to determine the quantity of the hydrogen absorbed by a samples of magnets, under controlled pressure (1, 2, 3, and 4 bar) and temperature (room, 100, 300, and 400°C) conditions, using Sieverts’ volumetric method. The composition and morphology of the starting and the extracted/disintegrated materials were examined by ICP, XRD, and SEM-EDS analysis.
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publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-7917f1993e9648e9a93be165348ecc312025-02-02T01:10:20ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752020-01-0156341542410.2298/JMMB200207032P1450-53392000032PThe use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic wastePiotrowicz A.0Pietrzyk S.1Noga P.2Myćka Ł.3AGH University of Science and Technology, Faculty of Non-Ferrous Metals, Cracow, PolandAGH University of Science and Technology, Faculty of Non-Ferrous Metals, Cracow, PolandAGH University of Science and Technology, Faculty of Non-Ferrous Metals, Cracow, PolandŁukasiewicz Research Network, Institute of Non-Ferrous Metals, Gliwice, PolandRare earth magnets based upon neodymium-iron-boron (NdFeB) are employed in many high tech applications, including hard disk drives (HDDs). The key elements in manufacturing NdFeB magnets are rare earth elements (REEs) such as neodymium. This element has been subject to significant supply shortfalls in the recent past. Recycling of NdFeB magnets contained within waste of electrical and electronic equipment (WEEE) could provide a secure and alternative supply of these materials. Various recycling approaches for the recovery of sintered NdFeB magnets have been widely explored. Hydrogen decrepitation (HD) can be used as a direct reuse approach and effective method of recycling process to turn solid sintered magnets into a demagnetised powder for further processing. In this work, sintered Nd-Fe-B magnets were processed without prior removal of the metallic protective layer using the thermal HD process as an alternative recycling method. The gas sorption analyzer was used to determine the quantity of the hydrogen absorbed by a samples of magnets, under controlled pressure (1, 2, 3, and 4 bar) and temperature (room, 100, 300, and 400°C) conditions, using Sieverts’ volumetric method. The composition and morphology of the starting and the extracted/disintegrated materials were examined by ICP, XRD, and SEM-EDS analysis.http://www.doiserbia.nb.rs/img/doi/1450-5339/2020/1450-53392000032P.pdfneodymium magnetsndfeb recyclinghydrogen decrepitation
spellingShingle Piotrowicz A.
Pietrzyk S.
Noga P.
Myćka Ł.
The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste
Journal of Mining and Metallurgy. Section B: Metallurgy
neodymium magnets
ndfeb recycling
hydrogen decrepitation
title The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste
title_full The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste
title_fullStr The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste
title_full_unstemmed The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste
title_short The use of thermal hydrogen decrepitation to recycle Nd-Fe-B magnets from electronic waste
title_sort use of thermal hydrogen decrepitation to recycle nd fe b magnets from electronic waste
topic neodymium magnets
ndfeb recycling
hydrogen decrepitation
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2020/1450-53392000032P.pdf
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