Asymmetric Hydrocarboxylation of Olefines by Chiral Palladium Complexes
Asymmetric induction up to 14% have been obtained in the hydrocarboxylation of olefinic hydrocarbons with carbon monoxide and alcohols in the presence of PdCl2 and (–)-DIOP (= 2,3-O-isopropylidene-2,3-dihydroxy-1,4- bis(diphenylphosphino)butane).
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| Main Authors: | , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1973-09-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9100 |
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| Summary: | Asymmetric induction up to 14% have been obtained in the hydrocarboxylation of olefinic hydrocarbons with carbon monoxide and alcohols in the presence of PdCl2 and (–)-DIOP (= 2,3-O-isopropylidene-2,3-dihydroxy-1,4- bis(diphenylphosphino)butane).
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| ISSN: | 0009-4293 2673-2424 |