Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid
In the current research work, the prepared new ligand 3hydroxy-2-(3-(4-nitro-benzoyl) thiouriedo) propanoic acid (NTP) has undergone synthesis through the reactions of 4-nitrobenzol isothiocyanate with the serine amino acid; its complex has been studied by effects of the temperature ranging wi...
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University of Baghdad
2025-01-01
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| Series: | Ibn Al-Haitham Journal for Pure and Applied Sciences |
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| Online Access: | https://jih.uobaghdad.edu.iq/index.php/j/article/view/3175 |
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| author | Basima M. Sarhan Dr. Taghreed Baqer Alwan Wedyan Mansoor Obaid Abbas M. Abbas Mohamed Abdel-Raheem Ali Abdel-Raheem |
| author_facet | Basima M. Sarhan Dr. Taghreed Baqer Alwan Wedyan Mansoor Obaid Abbas M. Abbas Mohamed Abdel-Raheem Ali Abdel-Raheem |
| author_sort | Basima M. Sarhan |
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In the current research work, the prepared new ligand 3hydroxy-2-(3-(4-nitro-benzoyl) thiouriedo) propanoic acid (NTP) has undergone synthesis through the reactions of 4-nitrobenzol isothiocyanate with the serine amino acid; its complex has been studied by effects of the temperature ranging within (25-45 oC) and various concentrations on molar conductivity values from Arinus' law application, by which decomposition constant and uniform molar conductivity is determined. The thermo0dynamic parameters (i.e., ΔS, ΔG, and ΔH) have been estimated and then discussed. Results have shown that the level of the molar conductivity increases with the degree of temperature and decreases with the increase of the concentration using solvent (DMSO). The dissociation process is exothermic; that ligand's transition metal complex has been synthesized and then characterized through the UV-Vis spectra, FTIR, conductivity measures, and magnetic susceptibility. The general formula [M(NTP)2], M+2= (Cu), is that the molecular form for those complexes is tetrahedral, except that the copper is of a square planer.
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| format | Article |
| id | doaj-art-764b69d4228b409692a4ef890fd6fa01 |
| institution | Kabale University |
| issn | 1609-4042 2521-3407 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | University of Baghdad |
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| series | Ibn Al-Haitham Journal for Pure and Applied Sciences |
| spelling | doaj-art-764b69d4228b409692a4ef890fd6fa012025-01-22T01:21:10ZengUniversity of BaghdadIbn Al-Haitham Journal for Pure and Applied Sciences1609-40422521-34072025-01-0138110.30526/38.1.3175Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic AcidBasima M. Sarhan0https://orcid.org/0000-0003-3813-5982Dr. Taghreed Baqer Alwan1https://orcid.org/0000-0002-1809-4880Wedyan Mansoor Obaid2Abbas M. Abbas3Mohamed Abdel-Raheem Ali Abdel-Raheem4https://orcid.org/0000-0001-9240-064XDepartment of Chemistry, College of Education for Pure Sciences (Ibn-AL- Haitham), University of Baghdad, Baghdad, Iraq.Dept. of Chemistry, College of Education for Pure Sciences (Ibn-AL- Haitham), University of Baghdad, Baghdad, Iraq.General Education in Baghdad Rusafa First, Distinguished High School.Ministry of Education General Directorate for Education in the Provice of MaysanPests & Plant Protection Department, Agricultural and Biological Research Institute, National Research Centre, Egypt. In the current research work, the prepared new ligand 3hydroxy-2-(3-(4-nitro-benzoyl) thiouriedo) propanoic acid (NTP) has undergone synthesis through the reactions of 4-nitrobenzol isothiocyanate with the serine amino acid; its complex has been studied by effects of the temperature ranging within (25-45 oC) and various concentrations on molar conductivity values from Arinus' law application, by which decomposition constant and uniform molar conductivity is determined. The thermo0dynamic parameters (i.e., ΔS, ΔG, and ΔH) have been estimated and then discussed. Results have shown that the level of the molar conductivity increases with the degree of temperature and decreases with the increase of the concentration using solvent (DMSO). The dissociation process is exothermic; that ligand's transition metal complex has been synthesized and then characterized through the UV-Vis spectra, FTIR, conductivity measures, and magnetic susceptibility. The general formula [M(NTP)2], M+2= (Cu), is that the molecular form for those complexes is tetrahedral, except that the copper is of a square planer. https://jih.uobaghdad.edu.iq/index.php/j/article/view/3175Isothiocyanate4-nitrobenzoylserinetheromdynamic measurementstransition metals |
| spellingShingle | Basima M. Sarhan Dr. Taghreed Baqer Alwan Wedyan Mansoor Obaid Abbas M. Abbas Mohamed Abdel-Raheem Ali Abdel-Raheem Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid Ibn Al-Haitham Journal for Pure and Applied Sciences Isothiocyanate 4-nitrobenzoyl serine theromdynamic measurements transition metals |
| title | Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid |
| title_full | Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid |
| title_fullStr | Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid |
| title_full_unstemmed | Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid |
| title_short | Thermodynamic Studies of [M+2] Complexes with 3-Hydroxy-2-(3-(4-Nitrobenzoyl) Thiouriedo) Propanoic Acid |
| title_sort | thermodynamic studies of m 2 complexes with 3 hydroxy 2 3 4 nitrobenzoyl thiouriedo propanoic acid |
| topic | Isothiocyanate 4-nitrobenzoyl serine theromdynamic measurements transition metals |
| url | https://jih.uobaghdad.edu.iq/index.php/j/article/view/3175 |
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