The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam

Polyurethane (PU) foam is known as the popular material for the applications in many fields of industry and life. To improve the mechanical and thermal properties of this material, in this research, PU foam was reinforced with aniline-modified multiwalled carbon nanotubes (MWCNTs). Fourier transform...

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Main Authors: Huynh Mai Duc, Dat Nguyen Huu, Trung Tran Huu, Lu Le Trong, Hai Luong Nhu, Hong Phan Ngoc, Thao Nguyen Van, Quynh Hoa Kieu Thi, Giang Nguyen Vu
Format: Article
Language:English
Published: Wiley 2021-01-01
Series:Advances in Polymer Technology
Online Access:http://dx.doi.org/10.1155/2021/6634545
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author Huynh Mai Duc
Dat Nguyen Huu
Trung Tran Huu
Lu Le Trong
Hai Luong Nhu
Hong Phan Ngoc
Thao Nguyen Van
Quynh Hoa Kieu Thi
Giang Nguyen Vu
author_facet Huynh Mai Duc
Dat Nguyen Huu
Trung Tran Huu
Lu Le Trong
Hai Luong Nhu
Hong Phan Ngoc
Thao Nguyen Van
Quynh Hoa Kieu Thi
Giang Nguyen Vu
author_sort Huynh Mai Duc
collection DOAJ
description Polyurethane (PU) foam is known as the popular material for the applications in many fields of industry and life. To improve the mechanical and thermal properties of this material, in this research, PU foam was reinforced with aniline-modified multiwalled carbon nanotubes (MWCNTs). Fourier transform infrared FTIR spectrum of modified MWCNTs showed the aniline was grafted on the surface of MWCNTs through the appearance of –NH2 stretches. The effect of MWCNTs with and without modification on the density, porosity, compressive strength, and heat conductivity of PU/MWCNT foam nanocomposites was investigated. The dispersibility of MWCNTs in the PU matrix was enhanced after modification with aniline. Compressive strength of PU nanocomposite reached the highest value after adding 3 wt.% of modified MWCNTs into PU foam. Besides, the water uptake of PU nanocomposites using 3 wt.% of MWCNTs was decreased to 13.4% as compared to that using unmodified MWCNTs. The improvement in thermal conductivity of PU/aniline-modified MWCNT nanocomposite was observed due to the change in the cellular size of PU foam in the presence of MWCNTs as shown by SEM images.
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issn 0730-6679
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publishDate 2021-01-01
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series Advances in Polymer Technology
spelling doaj-art-747755d6f1214f3ca974b4918e7adfaa2025-02-03T05:51:11ZengWileyAdvances in Polymer Technology0730-66791098-23292021-01-01202110.1155/2021/66345456634545The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane FoamHuynh Mai Duc0Dat Nguyen Huu1Trung Tran Huu2Lu Le Trong3Hai Luong Nhu4Hong Phan Ngoc5Thao Nguyen Van6Quynh Hoa Kieu Thi7Giang Nguyen Vu8Institute for Tropical Technology, Vietnam Academy of Science and Technology, VietnamInstitute for Tropical Technology, Vietnam Academy of Science and Technology, VietnamInstitute for Tropical Technology, Vietnam Academy of Science and Technology, VietnamInstitute for Tropical Technology, Vietnam Academy of Science and Technology, VietnamCentre for High Technology Development, Vietnam Academy of Science and Technology, VietnamCentre for High Technology Development, Vietnam Academy of Science and Technology, VietnamCentre for High Technology Development, Vietnam Academy of Science and Technology, VietnamInstitute of Biotechnology, Vietnam Academy of Science and Technology, VietnamInstitute for Tropical Technology, Vietnam Academy of Science and Technology, VietnamPolyurethane (PU) foam is known as the popular material for the applications in many fields of industry and life. To improve the mechanical and thermal properties of this material, in this research, PU foam was reinforced with aniline-modified multiwalled carbon nanotubes (MWCNTs). Fourier transform infrared FTIR spectrum of modified MWCNTs showed the aniline was grafted on the surface of MWCNTs through the appearance of –NH2 stretches. The effect of MWCNTs with and without modification on the density, porosity, compressive strength, and heat conductivity of PU/MWCNT foam nanocomposites was investigated. The dispersibility of MWCNTs in the PU matrix was enhanced after modification with aniline. Compressive strength of PU nanocomposite reached the highest value after adding 3 wt.% of modified MWCNTs into PU foam. Besides, the water uptake of PU nanocomposites using 3 wt.% of MWCNTs was decreased to 13.4% as compared to that using unmodified MWCNTs. The improvement in thermal conductivity of PU/aniline-modified MWCNT nanocomposite was observed due to the change in the cellular size of PU foam in the presence of MWCNTs as shown by SEM images.http://dx.doi.org/10.1155/2021/6634545
spellingShingle Huynh Mai Duc
Dat Nguyen Huu
Trung Tran Huu
Lu Le Trong
Hai Luong Nhu
Hong Phan Ngoc
Thao Nguyen Van
Quynh Hoa Kieu Thi
Giang Nguyen Vu
The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam
Advances in Polymer Technology
title The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam
title_full The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam
title_fullStr The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam
title_full_unstemmed The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam
title_short The Effect of Multiwalled Carbon Nanotubes on the Thermal Conductivity and Cellular Size of Polyurethane Foam
title_sort effect of multiwalled carbon nanotubes on the thermal conductivity and cellular size of polyurethane foam
url http://dx.doi.org/10.1155/2021/6634545
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