Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications

In this study we investigate the coupled impacts of poly-Si thickness, dopant activation annealing temperature and hydrogenation on n-TOPCon and p-TOPCon passivated contacts. Their performance is first assessed by Photoconductance Decay (PCD) measurements on symmetrical and asymmetrical cell precur...

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Main Authors: Julci Ditsougou, Thibaut Desrues, Anne Kaminski, Sébastien Dubois
Format: Article
Language:English
Published: TIB Open Publishing 2025-02-01
Series:SiliconPV Conference Proceedings
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Online Access:https://www.tib-op.org/ojs/index.php/siliconpv/article/view/1310
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author Julci Ditsougou
Thibaut Desrues
Anne Kaminski
Sébastien Dubois
author_facet Julci Ditsougou
Thibaut Desrues
Anne Kaminski
Sébastien Dubois
author_sort Julci Ditsougou
collection DOAJ
description In this study we investigate the coupled impacts of poly-Si thickness, dopant activation annealing temperature and hydrogenation on n-TOPCon and p-TOPCon passivated contacts. Their performance is first assessed by Photoconductance Decay (PCD) measurements on symmetrical and asymmetrical cell precursors before being evaluated on cells by I-V characterizations. We show that high-temperature annealing of poly-Si layers is responsible for excessive dopants penetration in the substrate, which can then be limited by the presence of a thicker poly-Si layer. Moreover, these thicker poly-Si layers benefit more from hydrogenation steps, enabling i-Voc of around 720 mV and carrier lifetimes of up to 5 ms on cell precursors. Finally, while increasing the thickness leads to current limitation under AM1.5G (1 Sun) illumination, this limitation is less pronounced under IR illumination. We therefore demonstrate that for tandem applications, the bottom-cell can benefit from a gain in Voc and FF without suffering from a major optical limitation.
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institution Kabale University
issn 2940-2123
language English
publishDate 2025-02-01
publisher TIB Open Publishing
record_format Article
series SiliconPV Conference Proceedings
spelling doaj-art-73eb7fdf56e54730ac9cb5188233179b2025-02-04T09:54:11ZengTIB Open PublishingSiliconPV Conference Proceedings2940-21232025-02-01210.52825/siliconpv.v2i.1310Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells ApplicationsJulci Ditsougou0https://orcid.org/0009-0003-3798-3354Thibaut Desrues1Anne Kaminski2Sébastien Dubois3https://orcid.org/0000-0002-3003-2981CEA LITENCEA LITENGrenoble Institute of TechnologyCEA LITEN In this study we investigate the coupled impacts of poly-Si thickness, dopant activation annealing temperature and hydrogenation on n-TOPCon and p-TOPCon passivated contacts. Their performance is first assessed by Photoconductance Decay (PCD) measurements on symmetrical and asymmetrical cell precursors before being evaluated on cells by I-V characterizations. We show that high-temperature annealing of poly-Si layers is responsible for excessive dopants penetration in the substrate, which can then be limited by the presence of a thicker poly-Si layer. Moreover, these thicker poly-Si layers benefit more from hydrogenation steps, enabling i-Voc of around 720 mV and carrier lifetimes of up to 5 ms on cell precursors. Finally, while increasing the thickness leads to current limitation under AM1.5G (1 Sun) illumination, this limitation is less pronounced under IR illumination. We therefore demonstrate that for tandem applications, the bottom-cell can benefit from a gain in Voc and FF without suffering from a major optical limitation. https://www.tib-op.org/ojs/index.php/siliconpv/article/view/1310TOPconPassivated ContactHydrogenationSolar CellBottom-Cell2T Tandem
spellingShingle Julci Ditsougou
Thibaut Desrues
Anne Kaminski
Sébastien Dubois
Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications
SiliconPV Conference Proceedings
TOPcon
Passivated Contact
Hydrogenation
Solar Cell
Bottom-Cell
2T Tandem
title Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications
title_full Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications
title_fullStr Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications
title_full_unstemmed Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications
title_short Optimization of Poly-Si/SiOx Passivated Contacts for Crystalline Silicon Bottom Cells Applications
title_sort optimization of poly si siox passivated contacts for crystalline silicon bottom cells applications
topic TOPcon
Passivated Contact
Hydrogenation
Solar Cell
Bottom-Cell
2T Tandem
url https://www.tib-op.org/ojs/index.php/siliconpv/article/view/1310
work_keys_str_mv AT julciditsougou optimizationofpolysisioxpassivatedcontactsforcrystallinesiliconbottomcellsapplications
AT thibautdesrues optimizationofpolysisioxpassivatedcontactsforcrystallinesiliconbottomcellsapplications
AT annekaminski optimizationofpolysisioxpassivatedcontactsforcrystallinesiliconbottomcellsapplications
AT sebastiendubois optimizationofpolysisioxpassivatedcontactsforcrystallinesiliconbottomcellsapplications