Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one

Cyclization of 6-alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one, derivatives (2) in the presence of Keggin heteropoly acids, H3PW1212O40, H3PMo12O40, H4SiW12O40 and lacunary Keggin structure (K7PMo2W9O40) afforded 3 (3a = 6-dimethyl-7H-thiazolo[2,3-b][1,2,4]-triazin-7-one and 3b=6-ethyl-3-methyl...

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Main Authors: Fatemeh Hakim, Masoumeh Tabatabaee, Majid M. Hheravi, Mina Roshani, Fatemeh F. Bamoharam
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2011/103913
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author Fatemeh Hakim
Masoumeh Tabatabaee
Majid M. Hheravi
Mina Roshani
Fatemeh F. Bamoharam
author_facet Fatemeh Hakim
Masoumeh Tabatabaee
Majid M. Hheravi
Mina Roshani
Fatemeh F. Bamoharam
author_sort Fatemeh Hakim
collection DOAJ
description Cyclization of 6-alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one, derivatives (2) in the presence of Keggin heteropoly acids, H3PW1212O40, H3PMo12O40, H4SiW12O40 and lacunary Keggin structure (K7PMo2W9O40) afforded 3 (3a = 6-dimethyl-7H-thiazolo[2,3-b][1,2,4]-triazin-7-one and 3b=6-ethyl-3-methyl-7H-thiazolo[2,3-b][1,2,4]-triazin-7-one) in high yields and short reaction times
format Article
id doaj-art-73bb3860f69c4e468d5efaf290ac1302
institution Kabale University
issn 0973-4945
2090-9810
language English
publishDate 2011-01-01
publisher Wiley
record_format Article
series E-Journal of Chemistry
spelling doaj-art-73bb3860f69c4e468d5efaf290ac13022025-02-03T01:28:36ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018279880210.1155/2011/103913Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-oneFatemeh Hakim0Masoumeh Tabatabaee1Majid M. Hheravi2Mina Roshani3Fatemeh F. Bamoharam4Department of Chemistry, Islamic Azad University Mashhad Branch, Mashhad, IranDepartment of Chemistry, Islamic Azad University Yazd Branch, Yazd, IranDepartment of Chemistry, School of Sciences, Azzahra University, Tehran, IranDepartment of Chemistry, Islamic Azad University Mashhad Branch, Mashhad, IranDepartment of Chemistry, Islamic Azad University Mashhad Branch, Mashhad, IranCyclization of 6-alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one, derivatives (2) in the presence of Keggin heteropoly acids, H3PW1212O40, H3PMo12O40, H4SiW12O40 and lacunary Keggin structure (K7PMo2W9O40) afforded 3 (3a = 6-dimethyl-7H-thiazolo[2,3-b][1,2,4]-triazin-7-one and 3b=6-ethyl-3-methyl-7H-thiazolo[2,3-b][1,2,4]-triazin-7-one) in high yields and short reaction timeshttp://dx.doi.org/10.1155/2011/103913
spellingShingle Fatemeh Hakim
Masoumeh Tabatabaee
Majid M. Hheravi
Mina Roshani
Fatemeh F. Bamoharam
Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one
E-Journal of Chemistry
title Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one
title_full Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one
title_fullStr Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one
title_full_unstemmed Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one
title_short Heteropoly Acid Catalyzed Selective Cyclization of 6-Alkyl-3-propargylmercapto-1,2,4-triazin-5(2H)-one
title_sort heteropoly acid catalyzed selective cyclization of 6 alkyl 3 propargylmercapto 1 2 4 triazin 5 2h one
url http://dx.doi.org/10.1155/2011/103913
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