Covalent organic framework-based cathodes for beyond lithium-ion batteries

Abstract Covalent organic frameworks (COFs) are revolutionizing cathode materials for beyond-lithium-ion batteries, leveraging their tunable porosity, modular architecture, and redox-active sites to overcome challenges in the storing alkali metal ions (Na+ and K+) and high-valent metal ions (Zn2+, C...

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Bibliographic Details
Main Authors: Suleman Suleman, Xiaolong Cheng, Muhua Gu, Yoonseob Kim
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Communications Materials
Online Access:https://doi.org/10.1038/s43246-025-00801-7
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Summary:Abstract Covalent organic frameworks (COFs) are revolutionizing cathode materials for beyond-lithium-ion batteries, leveraging their tunable porosity, modular architecture, and redox-active sites to overcome challenges in the storing alkali metal ions (Na+ and K+) and high-valent metal ions (Zn2+, Ca2+, Al3+, Mg2+, etc.) for electrochemical energy storage. Their unique crystal structure, molecular designability, and storage mechanism enable high specific capacity, low diffusion energy barrier, and structural stability when storing large-radius charge carriers. This review highlights recent advancements in COFs for applications beyond lithium-ion batteries, emphasizing performance optimization methodologies for next-generation cathode materials.
ISSN:2662-4443