Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
Bio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepar...
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Format: | Article |
Language: | English |
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Wiley
2023-01-01
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Series: | Advances in Polymer Technology |
Online Access: | http://dx.doi.org/10.1155/2023/3114639 |
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author | Yunsheng Chong Liyan Wang Xiangming Xu Xiao Zhuang Rongrong Zheng Di Cao Yanming Chen |
author_facet | Yunsheng Chong Liyan Wang Xiangming Xu Xiao Zhuang Rongrong Zheng Di Cao Yanming Chen |
author_sort | Yunsheng Chong |
collection | DOAJ |
description | Bio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepared by the melt blending method through twin screw extruder. The structure and property of PA56/POE-g-MAH-GMA/PPO ternary alloys were studied. The results showed that the microscopic morphology of each alloy showed an obvious “sea-island” structure. PA56 is a continuous sea phase, and the island phase assumes the “core–shell structure,” the etched POE-g-MAH-GMA particles are as the nucleus, and PPO are as the shell. When the PPO mass fraction is 30%, the relative crystallinity of the alloy is 11.56%, which is 1.68 times lower compared to the pure PA56, the alloy notch impact strength is 42.1 kJ/m2, and reaches 11.7 times of pure PA56; the water absorption rate of 1.22%, which is 3.22 times lower than pure PA56. |
format | Article |
id | doaj-art-720d900825e641afb73a718239ecacc8 |
institution | Kabale University |
issn | 1098-2329 |
language | English |
publishDate | 2023-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Polymer Technology |
spelling | doaj-art-720d900825e641afb73a718239ecacc82025-02-03T06:47:29ZengWileyAdvances in Polymer Technology1098-23292023-01-01202310.1155/2023/3114639Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary AlloyYunsheng Chong0Liyan Wang1Xiangming Xu2Xiao Zhuang3Rongrong Zheng4Di Cao5Yanming Chen6School of Petrochemical EngineeringSchool of Petrochemical EngineeringLiaoyang Kangda Plastic Resin Co. Ltd.Duke Kunshan UniversitySchool of Petrochemical EngineeringLiaoyang Kangda Plastic Resin Co. Ltd.School of Petrochemical EngineeringBio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepared by the melt blending method through twin screw extruder. The structure and property of PA56/POE-g-MAH-GMA/PPO ternary alloys were studied. The results showed that the microscopic morphology of each alloy showed an obvious “sea-island” structure. PA56 is a continuous sea phase, and the island phase assumes the “core–shell structure,” the etched POE-g-MAH-GMA particles are as the nucleus, and PPO are as the shell. When the PPO mass fraction is 30%, the relative crystallinity of the alloy is 11.56%, which is 1.68 times lower compared to the pure PA56, the alloy notch impact strength is 42.1 kJ/m2, and reaches 11.7 times of pure PA56; the water absorption rate of 1.22%, which is 3.22 times lower than pure PA56.http://dx.doi.org/10.1155/2023/3114639 |
spellingShingle | Yunsheng Chong Liyan Wang Xiangming Xu Xiao Zhuang Rongrong Zheng Di Cao Yanming Chen Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy Advances in Polymer Technology |
title | Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy |
title_full | Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy |
title_fullStr | Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy |
title_full_unstemmed | Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy |
title_short | Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy |
title_sort | preparation and property study of pa56 poe g mah gma ppo ternary alloy |
url | http://dx.doi.org/10.1155/2023/3114639 |
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