Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy

Bio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepar...

Full description

Saved in:
Bibliographic Details
Main Authors: Yunsheng Chong, Liyan Wang, Xiangming Xu, Xiao Zhuang, Rongrong Zheng, Di Cao, Yanming Chen
Format: Article
Language:English
Published: Wiley 2023-01-01
Series:Advances in Polymer Technology
Online Access:http://dx.doi.org/10.1155/2023/3114639
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832546668585680896
author Yunsheng Chong
Liyan Wang
Xiangming Xu
Xiao Zhuang
Rongrong Zheng
Di Cao
Yanming Chen
author_facet Yunsheng Chong
Liyan Wang
Xiangming Xu
Xiao Zhuang
Rongrong Zheng
Di Cao
Yanming Chen
author_sort Yunsheng Chong
collection DOAJ
description Bio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepared by the melt blending method through twin screw extruder. The structure and property of PA56/POE-g-MAH-GMA/PPO ternary alloys were studied. The results showed that the microscopic morphology of each alloy showed an obvious “sea-island” structure. PA56 is a continuous sea phase, and the island phase assumes the “core–shell structure,” the etched POE-g-MAH-GMA particles are as the nucleus, and PPO are as the shell. When the PPO mass fraction is 30%, the relative crystallinity of the alloy is 11.56%, which is 1.68 times lower compared to the pure PA56, the alloy notch impact strength is 42.1 kJ/m2, and reaches 11.7 times of pure PA56; the water absorption rate of 1.22%, which is 3.22 times lower than pure PA56.
format Article
id doaj-art-720d900825e641afb73a718239ecacc8
institution Kabale University
issn 1098-2329
language English
publishDate 2023-01-01
publisher Wiley
record_format Article
series Advances in Polymer Technology
spelling doaj-art-720d900825e641afb73a718239ecacc82025-02-03T06:47:29ZengWileyAdvances in Polymer Technology1098-23292023-01-01202310.1155/2023/3114639Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary AlloyYunsheng Chong0Liyan Wang1Xiangming Xu2Xiao Zhuang3Rongrong Zheng4Di Cao5Yanming Chen6School of Petrochemical EngineeringSchool of Petrochemical EngineeringLiaoyang Kangda Plastic Resin Co. Ltd.Duke Kunshan UniversitySchool of Petrochemical EngineeringLiaoyang Kangda Plastic Resin Co. Ltd.School of Petrochemical EngineeringBio-based PA56 is as matrix resin, maleic anhydride (MAH), and glycidyl methacrylate (GMA) dual monomer grafted POE (POE-g-MAH/GMA) polyphenyl ether(PPO) are simultaneous as toughening agents. The PA56/POE-g-MAH-GMA/PPO ternary alloys containing 10 wt% POE-g-MAH-GMA with different PPO content prepared by the melt blending method through twin screw extruder. The structure and property of PA56/POE-g-MAH-GMA/PPO ternary alloys were studied. The results showed that the microscopic morphology of each alloy showed an obvious “sea-island” structure. PA56 is a continuous sea phase, and the island phase assumes the “core–shell structure,” the etched POE-g-MAH-GMA particles are as the nucleus, and PPO are as the shell. When the PPO mass fraction is 30%, the relative crystallinity of the alloy is 11.56%, which is 1.68 times lower compared to the pure PA56, the alloy notch impact strength is 42.1 kJ/m2, and reaches 11.7 times of pure PA56; the water absorption rate of 1.22%, which is 3.22 times lower than pure PA56.http://dx.doi.org/10.1155/2023/3114639
spellingShingle Yunsheng Chong
Liyan Wang
Xiangming Xu
Xiao Zhuang
Rongrong Zheng
Di Cao
Yanming Chen
Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
Advances in Polymer Technology
title Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
title_full Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
title_fullStr Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
title_full_unstemmed Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
title_short Preparation and Property Study of PA56/POE-g-MAH-GMA/PPO Ternary Alloy
title_sort preparation and property study of pa56 poe g mah gma ppo ternary alloy
url http://dx.doi.org/10.1155/2023/3114639
work_keys_str_mv AT yunshengchong preparationandpropertystudyofpa56poegmahgmappoternaryalloy
AT liyanwang preparationandpropertystudyofpa56poegmahgmappoternaryalloy
AT xiangmingxu preparationandpropertystudyofpa56poegmahgmappoternaryalloy
AT xiaozhuang preparationandpropertystudyofpa56poegmahgmappoternaryalloy
AT rongrongzheng preparationandpropertystudyofpa56poegmahgmappoternaryalloy
AT dicao preparationandpropertystudyofpa56poegmahgmappoternaryalloy
AT yanmingchen preparationandpropertystudyofpa56poegmahgmappoternaryalloy