Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer

Although liquid electrolyte based dye-sensitized solar cells (DSCs) have shown higher photovoltaic performance in their class, they still suffer from some practical limitations such as solvent evaporation, leakage, and sealing imperfections. These problems can be circumvented to a certain extent by...

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Main Authors: W. M. N. M. B. Wanninayake, K. Premaratne, R. M. G. R. Rajapakse
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2016/9087478
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author W. M. N. M. B. Wanninayake
K. Premaratne
R. M. G. R. Rajapakse
author_facet W. M. N. M. B. Wanninayake
K. Premaratne
R. M. G. R. Rajapakse
author_sort W. M. N. M. B. Wanninayake
collection DOAJ
description Although liquid electrolyte based dye-sensitized solar cells (DSCs) have shown higher photovoltaic performance in their class, they still suffer from some practical limitations such as solvent evaporation, leakage, and sealing imperfections. These problems can be circumvented to a certain extent by replacing the liquid electrolytes with quasi-solid-state electrolytes. Even though SnO2 shows high election mobility when compared to the semiconductor material commonly used in DSCs, the cell performance of SnO2-based DSCs is considerably low due to high electron recombination. This recombination effect can be reduced through the use of ultrathin coating layer of ZnO on SnO2 nanoparticles surface. ZnO-based DSCs also showed lower performance due to its amphoteric nature which help dissolve in slightly acidic dye solution. In this study, the effect of the composite SnO2/ZnO system was investigated. SnO2/ZnO composite DSCs showed 100% and 38% increase of efficiency compared to the pure SnO2-based and ZnO-based devices, respectively, with the gel electrolyte consisting of LiI salt.
format Article
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institution Kabale University
issn 1110-662X
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language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-705c04e621e94d1b9a9d43b3a6725bba2025-02-03T05:54:40ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2016-01-01201610.1155/2016/90874789087478Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation LayerW. M. N. M. B. Wanninayake0K. Premaratne1R. M. G. R. Rajapakse2Department of Civil Engineering, Faculty of Engineering, University of Peradeniya, 20400 Peradeniya, Sri LankaPostgraduate Institute of Science, University of Peradeniya, 20400 Peradeniya, Sri LankaPostgraduate Institute of Science, University of Peradeniya, 20400 Peradeniya, Sri LankaAlthough liquid electrolyte based dye-sensitized solar cells (DSCs) have shown higher photovoltaic performance in their class, they still suffer from some practical limitations such as solvent evaporation, leakage, and sealing imperfections. These problems can be circumvented to a certain extent by replacing the liquid electrolytes with quasi-solid-state electrolytes. Even though SnO2 shows high election mobility when compared to the semiconductor material commonly used in DSCs, the cell performance of SnO2-based DSCs is considerably low due to high electron recombination. This recombination effect can be reduced through the use of ultrathin coating layer of ZnO on SnO2 nanoparticles surface. ZnO-based DSCs also showed lower performance due to its amphoteric nature which help dissolve in slightly acidic dye solution. In this study, the effect of the composite SnO2/ZnO system was investigated. SnO2/ZnO composite DSCs showed 100% and 38% increase of efficiency compared to the pure SnO2-based and ZnO-based devices, respectively, with the gel electrolyte consisting of LiI salt.http://dx.doi.org/10.1155/2016/9087478
spellingShingle W. M. N. M. B. Wanninayake
K. Premaratne
R. M. G. R. Rajapakse
Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer
International Journal of Photoenergy
title Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer
title_full Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer
title_fullStr Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer
title_full_unstemmed Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer
title_short Enhancing Performance of SnO2-Based Dye-Sensitized Solar Cells Using ZnO Passivation Layer
title_sort enhancing performance of sno2 based dye sensitized solar cells using zno passivation layer
url http://dx.doi.org/10.1155/2016/9087478
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