Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films

The aim of this paper is to investigate the properties and photocatalytic activity of nanostructured TiO2 layers. The glancing angle deposition method with DC sputtering at low temperature was applied for deposition of the layers with various columnar structures. The thin-film structure and surface...

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Main Authors: Zdenek Michalcik, Marta Horakova, Petr Spatenka, Sarka Klementova, Martin Zlamal, Nicolas Martin
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/689154
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author Zdenek Michalcik
Marta Horakova
Petr Spatenka
Sarka Klementova
Martin Zlamal
Nicolas Martin
author_facet Zdenek Michalcik
Marta Horakova
Petr Spatenka
Sarka Klementova
Martin Zlamal
Nicolas Martin
author_sort Zdenek Michalcik
collection DOAJ
description The aim of this paper is to investigate the properties and photocatalytic activity of nanostructured TiO2 layers. The glancing angle deposition method with DC sputtering at low temperature was applied for deposition of the layers with various columnar structures. The thin-film structure and surface morphology were analyzed by XRD, SEM, and AFM analyses. The photocatalytic activity of the films was determined by the rate constant of the decomposition of the Acid Orange 7. In dependence on the glancing angle deposition parameters, three types of columnar structures were obtained. The films feature anatase/rutile and/or amorphous structures depending on the film architecture and deposition method. All the films give the evidence of the photocatalytic activity, even those without proved anatase or rutile structure presence. The impact of columnar boundary in perspective of the photocatalytic activity of nanostructured TiO2 layers was discussed as the possible factor supporting the photocatalytic activity.
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institution Kabale University
issn 1110-662X
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language English
publishDate 2012-01-01
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series International Journal of Photoenergy
spelling doaj-art-700044106473466ab6e1d8b1ad96ffd92025-02-03T01:06:44ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/689154689154Photocatalytic Activity of Nanostructured Titanium Dioxide Thin FilmsZdenek Michalcik0Marta Horakova1Petr Spatenka2Sarka Klementova3Martin Zlamal4Nicolas Martin5Department of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 46117 Liberec, Czech RepublicDepartment of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 46117 Liberec, Czech RepublicDepartment of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 46117 Liberec, Czech RepublicFaculty of Science, University of South Bohemia, Branisovska 31, 370 05 Ceske Budejovice, Czech RepublicDepartment of Inorganic Technology, VSCHT, Technická 5, Prague 6, 166 28, Dejvice, Czech RepublicDépartement MN2S, Institut FEMTO-ST (UMR 6174) CNRS, UFC ENSMM UTBM, 26 Chemin de l'Épitaphe, 25030 Besançon Cedex, FranceThe aim of this paper is to investigate the properties and photocatalytic activity of nanostructured TiO2 layers. The glancing angle deposition method with DC sputtering at low temperature was applied for deposition of the layers with various columnar structures. The thin-film structure and surface morphology were analyzed by XRD, SEM, and AFM analyses. The photocatalytic activity of the films was determined by the rate constant of the decomposition of the Acid Orange 7. In dependence on the glancing angle deposition parameters, three types of columnar structures were obtained. The films feature anatase/rutile and/or amorphous structures depending on the film architecture and deposition method. All the films give the evidence of the photocatalytic activity, even those without proved anatase or rutile structure presence. The impact of columnar boundary in perspective of the photocatalytic activity of nanostructured TiO2 layers was discussed as the possible factor supporting the photocatalytic activity.http://dx.doi.org/10.1155/2012/689154
spellingShingle Zdenek Michalcik
Marta Horakova
Petr Spatenka
Sarka Klementova
Martin Zlamal
Nicolas Martin
Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
International Journal of Photoenergy
title Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
title_full Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
title_fullStr Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
title_full_unstemmed Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
title_short Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
title_sort photocatalytic activity of nanostructured titanium dioxide thin films
url http://dx.doi.org/10.1155/2012/689154
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AT petrspatenka photocatalyticactivityofnanostructuredtitaniumdioxidethinfilms
AT sarkaklementova photocatalyticactivityofnanostructuredtitaniumdioxidethinfilms
AT martinzlamal photocatalyticactivityofnanostructuredtitaniumdioxidethinfilms
AT nicolasmartin photocatalyticactivityofnanostructuredtitaniumdioxidethinfilms