Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films
The aim of this paper is to investigate the properties and photocatalytic activity of nanostructured TiO2 layers. The glancing angle deposition method with DC sputtering at low temperature was applied for deposition of the layers with various columnar structures. The thin-film structure and surface...
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Format: | Article |
Language: | English |
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Wiley
2012-01-01
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Series: | International Journal of Photoenergy |
Online Access: | http://dx.doi.org/10.1155/2012/689154 |
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author | Zdenek Michalcik Marta Horakova Petr Spatenka Sarka Klementova Martin Zlamal Nicolas Martin |
author_facet | Zdenek Michalcik Marta Horakova Petr Spatenka Sarka Klementova Martin Zlamal Nicolas Martin |
author_sort | Zdenek Michalcik |
collection | DOAJ |
description | The aim of this paper is to investigate the properties and photocatalytic activity of nanostructured TiO2 layers. The glancing angle deposition method with DC sputtering at low temperature was applied for deposition of the layers with various columnar structures. The thin-film structure and surface morphology were analyzed by XRD, SEM, and AFM analyses. The photocatalytic activity of the films was determined by the rate constant of the decomposition of the Acid Orange 7. In dependence on the glancing angle deposition parameters, three types of columnar structures were obtained. The films feature anatase/rutile and/or amorphous structures depending on the film architecture and deposition method. All the films give the evidence of the photocatalytic activity, even those without proved anatase or rutile structure presence. The impact of columnar boundary in perspective of the photocatalytic activity of nanostructured TiO2 layers was discussed as the possible factor supporting the photocatalytic activity. |
format | Article |
id | doaj-art-700044106473466ab6e1d8b1ad96ffd9 |
institution | Kabale University |
issn | 1110-662X 1687-529X |
language | English |
publishDate | 2012-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Photoenergy |
spelling | doaj-art-700044106473466ab6e1d8b1ad96ffd92025-02-03T01:06:44ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/689154689154Photocatalytic Activity of Nanostructured Titanium Dioxide Thin FilmsZdenek Michalcik0Marta Horakova1Petr Spatenka2Sarka Klementova3Martin Zlamal4Nicolas Martin5Department of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 46117 Liberec, Czech RepublicDepartment of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 46117 Liberec, Czech RepublicDepartment of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 46117 Liberec, Czech RepublicFaculty of Science, University of South Bohemia, Branisovska 31, 370 05 Ceske Budejovice, Czech RepublicDepartment of Inorganic Technology, VSCHT, Technická 5, Prague 6, 166 28, Dejvice, Czech RepublicDépartement MN2S, Institut FEMTO-ST (UMR 6174) CNRS, UFC ENSMM UTBM, 26 Chemin de l'Épitaphe, 25030 Besançon Cedex, FranceThe aim of this paper is to investigate the properties and photocatalytic activity of nanostructured TiO2 layers. The glancing angle deposition method with DC sputtering at low temperature was applied for deposition of the layers with various columnar structures. The thin-film structure and surface morphology were analyzed by XRD, SEM, and AFM analyses. The photocatalytic activity of the films was determined by the rate constant of the decomposition of the Acid Orange 7. In dependence on the glancing angle deposition parameters, three types of columnar structures were obtained. The films feature anatase/rutile and/or amorphous structures depending on the film architecture and deposition method. All the films give the evidence of the photocatalytic activity, even those without proved anatase or rutile structure presence. The impact of columnar boundary in perspective of the photocatalytic activity of nanostructured TiO2 layers was discussed as the possible factor supporting the photocatalytic activity.http://dx.doi.org/10.1155/2012/689154 |
spellingShingle | Zdenek Michalcik Marta Horakova Petr Spatenka Sarka Klementova Martin Zlamal Nicolas Martin Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films International Journal of Photoenergy |
title | Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films |
title_full | Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films |
title_fullStr | Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films |
title_full_unstemmed | Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films |
title_short | Photocatalytic Activity of Nanostructured Titanium Dioxide Thin Films |
title_sort | photocatalytic activity of nanostructured titanium dioxide thin films |
url | http://dx.doi.org/10.1155/2012/689154 |
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