The Electrochemical Characterization of Functionalized Isoindolinones
This study considers the electrochemical and physical properties of six functionalized isoindolinones, synthesized using a facile, green route. The compounds show redox activity at a highly negative potential with quasireversible redox potentials of ≈−2.8 V versus Fc/Fc+, a potential in the region o...
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| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-06-01
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| Series: | ChemElectroChem |
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| Online Access: | https://doi.org/10.1002/celc.202500044 |
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| author | Daniel. E. Smith Ashley J. Basson Niamh J. Owen Mark Potter Mark G. McLaughlin Kathryn E. Toghill |
| author_facet | Daniel. E. Smith Ashley J. Basson Niamh J. Owen Mark Potter Mark G. McLaughlin Kathryn E. Toghill |
| author_sort | Daniel. E. Smith |
| collection | DOAJ |
| description | This study considers the electrochemical and physical properties of six functionalized isoindolinones, synthesized using a facile, green route. The compounds show redox activity at a highly negative potential with quasireversible redox potentials of ≈−2.8 V versus Fc/Fc+, a potential in the region of alkali metal deposition and intercalation. For those molecules with a specific structural motif, the electrochemical behavior is electrochemically quasireversible, attributed to the formation of a carbanion radical stabilized on the carbonyl group. The electrochemical properties of the reversible compounds are assessed, with the lead‐performing compound extensively characterized galvanostatically to assess its candidacy for nonaqueous, high‐voltage energy storage. |
| format | Article |
| id | doaj-art-6ece78e7c2c647cbb8c7a897e90c89b2 |
| institution | OA Journals |
| issn | 2196-0216 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | ChemElectroChem |
| spelling | doaj-art-6ece78e7c2c647cbb8c7a897e90c89b22025-08-20T02:23:11ZengWiley-VCHChemElectroChem2196-02162025-06-011212n/an/a10.1002/celc.202500044The Electrochemical Characterization of Functionalized IsoindolinonesDaniel. E. Smith0Ashley J. Basson1Niamh J. Owen2Mark Potter3Mark G. McLaughlin4Kathryn E. Toghill5Department of Chemistry Lancaster University Bailrigg, Lancaster LA1 4YB UKDepartment of Chemistry Lancaster University Bailrigg, Lancaster LA1 4YB UKDepartment of Chemistry Lancaster University Bailrigg, Lancaster LA1 4YB UKDepartment of Chemistry Lancaster University Bailrigg, Lancaster LA1 4YB UKSchool of Chemistry Queen's University Belfast David Keir Building, Stranmillis Road Belfast BT9 5AG UKDepartment of Chemistry Lancaster University Bailrigg, Lancaster LA1 4YB UKThis study considers the electrochemical and physical properties of six functionalized isoindolinones, synthesized using a facile, green route. The compounds show redox activity at a highly negative potential with quasireversible redox potentials of ≈−2.8 V versus Fc/Fc+, a potential in the region of alkali metal deposition and intercalation. For those molecules with a specific structural motif, the electrochemical behavior is electrochemically quasireversible, attributed to the formation of a carbanion radical stabilized on the carbonyl group. The electrochemical properties of the reversible compounds are assessed, with the lead‐performing compound extensively characterized galvanostatically to assess its candidacy for nonaqueous, high‐voltage energy storage.https://doi.org/10.1002/celc.202500044energy storagemolecular electrochemistryreactive intermediatesredoxmersvoltammetry |
| spellingShingle | Daniel. E. Smith Ashley J. Basson Niamh J. Owen Mark Potter Mark G. McLaughlin Kathryn E. Toghill The Electrochemical Characterization of Functionalized Isoindolinones ChemElectroChem energy storage molecular electrochemistry reactive intermediates redoxmers voltammetry |
| title | The Electrochemical Characterization of Functionalized Isoindolinones |
| title_full | The Electrochemical Characterization of Functionalized Isoindolinones |
| title_fullStr | The Electrochemical Characterization of Functionalized Isoindolinones |
| title_full_unstemmed | The Electrochemical Characterization of Functionalized Isoindolinones |
| title_short | The Electrochemical Characterization of Functionalized Isoindolinones |
| title_sort | electrochemical characterization of functionalized isoindolinones |
| topic | energy storage molecular electrochemistry reactive intermediates redoxmers voltammetry |
| url | https://doi.org/10.1002/celc.202500044 |
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