Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review

Steel reinforcement corrosion is the main reason for the decrease in the durability of concrete structures, and concrete structures serving in the coupled environment of chloride and sulfate are prone to steel reinforcement corrosion. Therefore, it is necessary to explore the coupled effect of chlor...

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Main Authors: Ye Tian, Yu Liu, Yu-Meng Xie, Guo-Yi Zhang, Hai-Long Ye, Dong-Ming Yan, Yun-Jian Li, Bei Li, Hong-Jing Xue, Qing Cai
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Case Studies in Construction Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2214509525000622
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author Ye Tian
Yu Liu
Yu-Meng Xie
Guo-Yi Zhang
Hai-Long Ye
Dong-Ming Yan
Yun-Jian Li
Bei Li
Hong-Jing Xue
Qing Cai
author_facet Ye Tian
Yu Liu
Yu-Meng Xie
Guo-Yi Zhang
Hai-Long Ye
Dong-Ming Yan
Yun-Jian Li
Bei Li
Hong-Jing Xue
Qing Cai
author_sort Ye Tian
collection DOAJ
description Steel reinforcement corrosion is the main reason for the decrease in the durability of concrete structures, and concrete structures serving in the coupled environment of chloride and sulfate are prone to steel reinforcement corrosion. Therefore, it is necessary to explore the coupled effect of chloride and sulfate on concrete degradation and steel corrosion. This paper provides a comprehensive review of the corrosion of steel reinforcement in concrete structures exposed to coupled invasion of chlorides and sulfates. The natural exposure stations and tests of concrete under chloride and sulfate attack around the world are discussed. The complex interactions and coupled transport models involved in the erosion process of chloride and sulfate ions are explained. From the perspectives of the direct effect of chloride ions on steel corrosion and the influence of sulfate ions on chloride-induced steel corrosion, the mechanism of steel corrosion in a coupled environment of chlorides and sulfates is represented. The paper also summarizes relevant experimental research and numerical simulation research. It emphasizes the importance of further research to clarify the direct mechanism of sulfate ions on the passive film on the steel surface and their reactions in the electrochemical corrosion process. Comprehensive consideration and accurate simulation of the factors influencing steel corrosion are crucial for advancing the prediction of the durability of reinforced concrete structures.
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institution Kabale University
issn 2214-5095
language English
publishDate 2025-07-01
publisher Elsevier
record_format Article
series Case Studies in Construction Materials
spelling doaj-art-6df456bf577c4088a1af63621590e4372025-01-22T05:41:55ZengElsevierCase Studies in Construction Materials2214-50952025-07-0122e04263Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive reviewYe Tian0Yu Liu1Yu-Meng Xie2Guo-Yi Zhang3Hai-Long Ye4Dong-Ming Yan5Yun-Jian Li6Bei Li7Hong-Jing Xue8Qing Cai9Department of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, PR ChinaDepartment of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, PR ChinaDepartment of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, PR ChinaCollege of Landscape Architecture, Zhejiang Agriculture and Forestry University, Hangzhou 310058, PR China; Corresponding authors.Department of Civil Engineering, The University of Hong Kong, Hong Kong, PR China; Corresponding authors.Department of Civil Engineering and Architecture, Zhejiang University, Hangzhou 310058, PR ChinaFaculty of Innovation Engineering, Macau University of Science and Technology, Macao, 999078, PR ChinaCollege of Civil Engineering and Architecture, Zhejiang University of Water Resources and Electric Power, Hangzhou 310018, PR ChinaBeijing Institute of Architectural Design Co., Ltd., Beijing 100037, PR ChinaBeijing Institute of Architectural Design Co., Ltd., Beijing 100037, PR ChinaSteel reinforcement corrosion is the main reason for the decrease in the durability of concrete structures, and concrete structures serving in the coupled environment of chloride and sulfate are prone to steel reinforcement corrosion. Therefore, it is necessary to explore the coupled effect of chloride and sulfate on concrete degradation and steel corrosion. This paper provides a comprehensive review of the corrosion of steel reinforcement in concrete structures exposed to coupled invasion of chlorides and sulfates. The natural exposure stations and tests of concrete under chloride and sulfate attack around the world are discussed. The complex interactions and coupled transport models involved in the erosion process of chloride and sulfate ions are explained. From the perspectives of the direct effect of chloride ions on steel corrosion and the influence of sulfate ions on chloride-induced steel corrosion, the mechanism of steel corrosion in a coupled environment of chlorides and sulfates is represented. The paper also summarizes relevant experimental research and numerical simulation research. It emphasizes the importance of further research to clarify the direct mechanism of sulfate ions on the passive film on the steel surface and their reactions in the electrochemical corrosion process. Comprehensive consideration and accurate simulation of the factors influencing steel corrosion are crucial for advancing the prediction of the durability of reinforced concrete structures.http://www.sciencedirect.com/science/article/pii/S2214509525000622ReviewSteel corrosionChloride-sulfateCoupled attackConcrete durability
spellingShingle Ye Tian
Yu Liu
Yu-Meng Xie
Guo-Yi Zhang
Hai-Long Ye
Dong-Ming Yan
Yun-Jian Li
Bei Li
Hong-Jing Xue
Qing Cai
Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review
Case Studies in Construction Materials
Review
Steel corrosion
Chloride-sulfate
Coupled attack
Concrete durability
title Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review
title_full Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review
title_fullStr Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review
title_full_unstemmed Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review
title_short Coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures: A comprehensive review
title_sort coupled effects of chlorides and sulfates on steel reinforcement corrosion in concrete structures a comprehensive review
topic Review
Steel corrosion
Chloride-sulfate
Coupled attack
Concrete durability
url http://www.sciencedirect.com/science/article/pii/S2214509525000622
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