Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite

The electrochemical properties of silver nanoparticle (d∼ 5 nm) synthesized within aminosilica film from spontaneous reduction reaction were examined using cyclic voltammetry and the results show that the nanocomposite film exhibits similar redox property as solution-synthesized silver nanoparticles...

Full description

Saved in:
Bibliographic Details
Main Authors: Yong-Jae Choi, Tzy-Jiun M. Luo
Format: Article
Language:English
Published: Wiley 2011-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.4061/2011/404937
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832549098233790464
author Yong-Jae Choi
Tzy-Jiun M. Luo
author_facet Yong-Jae Choi
Tzy-Jiun M. Luo
author_sort Yong-Jae Choi
collection DOAJ
description The electrochemical properties of silver nanoparticle (d∼ 5 nm) synthesized within aminosilica film from spontaneous reduction reaction were examined using cyclic voltammetry and the results show that the nanocomposite film exhibits similar redox property as solution-synthesized silver nanoparticles when measuring in phosphate buffer solution and its redox potentials were found to be sensitive to the presence of chloride ions. It also shows that silver nanoparticles and hydrolyzed aminosilica increase the electron diffusivity of the aminosilica film. Both results confirm that an accurate reference electrode suitable for microfluidic devices can be created simply by treating an aminosilica-coated electrode with a silver nitrate solution. Furthermore, a humidity sensor based on silver-silica nanocomposite film has also been demonstrated.
format Article
id doaj-art-6dca769825bc48eabe23e196c0cda66d
institution Kabale University
issn 2090-3537
language English
publishDate 2011-01-01
publisher Wiley
record_format Article
series International Journal of Electrochemistry
spelling doaj-art-6dca769825bc48eabe23e196c0cda66d2025-02-03T06:12:15ZengWileyInternational Journal of Electrochemistry2090-35372011-01-01201110.4061/2011/404937404937Electrochemical Properties of Silver Nanoparticle Doped Aminosilica NanocompositeYong-Jae Choi0Tzy-Jiun M. Luo1Department of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695, USADepartment of Materials Science and Engineering, North Carolina State University, Raleigh, NC 27695, USAThe electrochemical properties of silver nanoparticle (d∼ 5 nm) synthesized within aminosilica film from spontaneous reduction reaction were examined using cyclic voltammetry and the results show that the nanocomposite film exhibits similar redox property as solution-synthesized silver nanoparticles when measuring in phosphate buffer solution and its redox potentials were found to be sensitive to the presence of chloride ions. It also shows that silver nanoparticles and hydrolyzed aminosilica increase the electron diffusivity of the aminosilica film. Both results confirm that an accurate reference electrode suitable for microfluidic devices can be created simply by treating an aminosilica-coated electrode with a silver nitrate solution. Furthermore, a humidity sensor based on silver-silica nanocomposite film has also been demonstrated.http://dx.doi.org/10.4061/2011/404937
spellingShingle Yong-Jae Choi
Tzy-Jiun M. Luo
Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite
International Journal of Electrochemistry
title Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite
title_full Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite
title_fullStr Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite
title_full_unstemmed Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite
title_short Electrochemical Properties of Silver Nanoparticle Doped Aminosilica Nanocomposite
title_sort electrochemical properties of silver nanoparticle doped aminosilica nanocomposite
url http://dx.doi.org/10.4061/2011/404937
work_keys_str_mv AT yongjaechoi electrochemicalpropertiesofsilvernanoparticledopedaminosilicananocomposite
AT tzyjiunmluo electrochemicalpropertiesofsilvernanoparticledopedaminosilicananocomposite