Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator

This work studied the performance effect and regeneration mechanism of the organic–inorganic composite rejuvenator (COWRGO) composed of waste cooking oil, waste rubber powder, and modified graphene oxide on aged asphalt. The findings demonstrate that the rejuvenator retained its storage stability fo...

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Main Authors: Benan Shu, Guodong Zeng, Leifeng Li, Maocong Zhu, Yunlong Ma
Format: Article
Language:English
Published: AIP Publishing LLC 2025-01-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/5.0247743
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author Benan Shu
Guodong Zeng
Leifeng Li
Maocong Zhu
Yunlong Ma
author_facet Benan Shu
Guodong Zeng
Leifeng Li
Maocong Zhu
Yunlong Ma
author_sort Benan Shu
collection DOAJ
description This work studied the performance effect and regeneration mechanism of the organic–inorganic composite rejuvenator (COWRGO) composed of waste cooking oil, waste rubber powder, and modified graphene oxide on aged asphalt. The findings demonstrate that the rejuvenator retained its storage stability for one year following its restoration. The rutting factor of COWRGO regenerated asphalt was 43% higher than that of the base asphalt at 64 °C. A reduction in stiffness of 33% was observed, accompanied by an increase in m of 15% at a temperature of −18 °C. The unrecoverable creep compliance was decreased by 58% under shear stresses of 0.3 kPa. The optimal content of modified graphene oxide was identified as 0.1%. In this instance, the residual penetration rate was increased by 29%, and the viscosity aging index was reduced by 23%. The fatigue life of the regenerated asphalt was increased by 22%, reaching a total of 1610 cycles. Regenerated mechanism tests revealed that the COWRGO process resulted in a reduction in the molecular weight of aged asphalt, with an 11% decrease in the relative content of large molecules and an increase in medium and small molecules. The activation of waste rubber powder results in the formation of a loose and porous structure, accompanied by an increase in oxygen content of 3.79%. The decreased peak intensity of –CH2– and increased peak intensity of C–O and –OH mean that the aged asphalt molecular chains are effectively broken down, and the unsaturated and oxygen-containing functional groups are significantly increased.
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issn 2158-3226
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publishDate 2025-01-01
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spelling doaj-art-6cdf9d63e7d749ada46ff4891acba79f2025-02-03T16:40:42ZengAIP Publishing LLCAIP Advances2158-32262025-01-01151015026015026-1110.1063/5.0247743Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenatorBenan Shu0Guodong Zeng1Leifeng Li2Maocong Zhu3Yunlong Ma4Foshan Transportation Science and Technology Co., Ltd., 528000 Foshan, ChinaFoshan Transportation Science and Technology Co., Ltd., 528000 Foshan, ChinaFoshan Jianying Development Co., Ltd., 528000 Foshan, ChinaFoshan Transportation Science and Technology Co., Ltd., 528000 Foshan, ChinaFojiaoke Tiannuo (Guangdong) Materials Co., Ltd., 528000 Foshan, ChinaThis work studied the performance effect and regeneration mechanism of the organic–inorganic composite rejuvenator (COWRGO) composed of waste cooking oil, waste rubber powder, and modified graphene oxide on aged asphalt. The findings demonstrate that the rejuvenator retained its storage stability for one year following its restoration. The rutting factor of COWRGO regenerated asphalt was 43% higher than that of the base asphalt at 64 °C. A reduction in stiffness of 33% was observed, accompanied by an increase in m of 15% at a temperature of −18 °C. The unrecoverable creep compliance was decreased by 58% under shear stresses of 0.3 kPa. The optimal content of modified graphene oxide was identified as 0.1%. In this instance, the residual penetration rate was increased by 29%, and the viscosity aging index was reduced by 23%. The fatigue life of the regenerated asphalt was increased by 22%, reaching a total of 1610 cycles. Regenerated mechanism tests revealed that the COWRGO process resulted in a reduction in the molecular weight of aged asphalt, with an 11% decrease in the relative content of large molecules and an increase in medium and small molecules. The activation of waste rubber powder results in the formation of a loose and porous structure, accompanied by an increase in oxygen content of 3.79%. The decreased peak intensity of –CH2– and increased peak intensity of C–O and –OH mean that the aged asphalt molecular chains are effectively broken down, and the unsaturated and oxygen-containing functional groups are significantly increased.http://dx.doi.org/10.1063/5.0247743
spellingShingle Benan Shu
Guodong Zeng
Leifeng Li
Maocong Zhu
Yunlong Ma
Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator
AIP Advances
title Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator
title_full Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator
title_fullStr Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator
title_full_unstemmed Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator
title_short Study on the performance and mechanism of aging asphalt with organic–inorganic composite rejuvenator
title_sort study on the performance and mechanism of aging asphalt with organic inorganic composite rejuvenator
url http://dx.doi.org/10.1063/5.0247743
work_keys_str_mv AT benanshu studyontheperformanceandmechanismofagingasphaltwithorganicinorganiccompositerejuvenator
AT guodongzeng studyontheperformanceandmechanismofagingasphaltwithorganicinorganiccompositerejuvenator
AT leifengli studyontheperformanceandmechanismofagingasphaltwithorganicinorganiccompositerejuvenator
AT maocongzhu studyontheperformanceandmechanismofagingasphaltwithorganicinorganiccompositerejuvenator
AT yunlongma studyontheperformanceandmechanismofagingasphaltwithorganicinorganiccompositerejuvenator