Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications

Graphdiyne (GDY) is a novel carbon allotrope that has attracted significant attention owing to its unique structural and electronic properties. Comprising sp2- and sp-hybridized carbon atoms, GDY forms a two-dimensional structure via conjugated −C≡C−C≡C− linkages. These linkages result in a highly π...

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Main Authors: Dinh Phuc Do, Eunji Lee, Viet Q. Bui, Hyoyoung Lee
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-04-01
Series:ChemPhysMater
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Online Access:http://www.sciencedirect.com/science/article/pii/S2772571524000585
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author Dinh Phuc Do
Eunji Lee
Viet Q. Bui
Hyoyoung Lee
author_facet Dinh Phuc Do
Eunji Lee
Viet Q. Bui
Hyoyoung Lee
author_sort Dinh Phuc Do
collection DOAJ
description Graphdiyne (GDY) is a novel carbon allotrope that has attracted significant attention owing to its unique structural and electronic properties. Comprising sp2- and sp-hybridized carbon atoms, GDY forms a two-dimensional structure via conjugated −C≡C−C≡C− linkages. These linkages result in a highly π-conjugated system with a natural bandgap that distinguishes GDY from other carbon materials such as graphene. This review systematically provides an overview of GDY, with a focus on its intrinsic properties and synthesis strategies, techniques to characterize its structure, and recent advanced applications. First, we summarize several GDY synthesis strategies, providing a detailed discussion of the advantages and disadvantages associated with each approach. Subsequently, several practical and precise techniques, including solid nuclear magnetic resonance, Raman, Fourier-transform infrared, and X-ray photoelectron spectroscopies, transmission electron microscopy, and selected area electron diffraction, to characterize the GDY structure are discussed. Next, we elucidate the unique structural and electronic properties of GDY using both theoretical frameworks and experimental methodologies. Finally, we comprehensively discuss the recent applications of GDY in various fields, including biomedicine, electronics, optoelectronics, energy storage, and catalysis.
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spelling doaj-art-6c2ee2df10f14c35bb2c12fee003288c2025-08-20T02:17:40ZengKeAi Communications Co., Ltd.ChemPhysMater2772-57152025-04-01429110710.1016/j.chphma.2024.09.005Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applicationsDinh Phuc Do0Eunji Lee1Viet Q. Bui2Hyoyoung Lee3Department of Chemistry, Sungkyunkwan University, Suwon 16419, Republic of KoreaDepartment of Chemistry, Sungkyunkwan University, Suwon 16419, Republic of KoreaAdvanced Institute of Science and Technology, The University of Danang, 41 Le Duan, Danang 92026, VietnamDepartment of Chemistry, Sungkyunkwan University, Suwon 16419, Republic of Korea; Creative Research Institute, Sungkyunkwan University, Suwon 16419, Republic of Korea; Institute of Quantum Biophysics, Sungkyunkwan University, 2066 Seoburo, Suwon 16419, Republic of Korea; Corresponding author.Graphdiyne (GDY) is a novel carbon allotrope that has attracted significant attention owing to its unique structural and electronic properties. Comprising sp2- and sp-hybridized carbon atoms, GDY forms a two-dimensional structure via conjugated −C≡C−C≡C− linkages. These linkages result in a highly π-conjugated system with a natural bandgap that distinguishes GDY from other carbon materials such as graphene. This review systematically provides an overview of GDY, with a focus on its intrinsic properties and synthesis strategies, techniques to characterize its structure, and recent advanced applications. First, we summarize several GDY synthesis strategies, providing a detailed discussion of the advantages and disadvantages associated with each approach. Subsequently, several practical and precise techniques, including solid nuclear magnetic resonance, Raman, Fourier-transform infrared, and X-ray photoelectron spectroscopies, transmission electron microscopy, and selected area electron diffraction, to characterize the GDY structure are discussed. Next, we elucidate the unique structural and electronic properties of GDY using both theoretical frameworks and experimental methodologies. Finally, we comprehensively discuss the recent applications of GDY in various fields, including biomedicine, electronics, optoelectronics, energy storage, and catalysis.http://www.sciencedirect.com/science/article/pii/S2772571524000585Graphdiyne2D materialDirect bandgapHigh mobilityPractical applications
spellingShingle Dinh Phuc Do
Eunji Lee
Viet Q. Bui
Hyoyoung Lee
Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications
ChemPhysMater
Graphdiyne
2D material
Direct bandgap
High mobility
Practical applications
title Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications
title_full Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications
title_fullStr Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications
title_full_unstemmed Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications
title_short Recent progress in two-dimensional graphdiyne: Synthesis, characterization, and applications
title_sort recent progress in two dimensional graphdiyne synthesis characterization and applications
topic Graphdiyne
2D material
Direct bandgap
High mobility
Practical applications
url http://www.sciencedirect.com/science/article/pii/S2772571524000585
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AT vietqbui recentprogressintwodimensionalgraphdiynesynthesischaracterizationandapplications
AT hyoyounglee recentprogressintwodimensionalgraphdiynesynthesischaracterizationandapplications